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- Q1145478 subject Q8980764.
- Q1145478 subject Q9588261.
- Q1145478 abstract "The Curtin–Hammett principle is a principle in chemical kinetics proposed by David Yarrow Curtin and Louis Plack Hammett. It states that, for a reaction that has a pair of reactive intermediates or reactants that interconvert rapidly (as is usually the case for conformational isomers), each going irreversibly to a different product, the product ratio will depend both on the difference in energy between the two conformers and the free energy of the transition state going to each product. As a result, the product distribution will not necessarily reflect the equilibrium distribution of the two intermediates. The Curtin–Hammett principle has been invoked to explain selectivity in a variety of stereo- and regioselective reactions.".
- Q1145478 thumbnail Curtin-Hammett_Principle_Diagram.png?width=300.
- Q1145478 wikiPageExternalLink smnr_2009_wzorek_joseph.pdf.
- Q1145478 wikiPageExternalLink CurtinHammettreview.pdf.
- Q1145478 wikiPageWikiLink Q1076414.
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- Q1145478 wikiPageWikiLink Q7361732.
- Q1145478 wikiPageWikiLink Q8980764.
- Q1145478 wikiPageWikiLink Q898628.
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- Q1145478 wikiPageWikiLink Q904041.
- Q1145478 wikiPageWikiLink Q906964.
- Q1145478 wikiPageWikiLink Q9588261.
- Q1145478 comment "The Curtin–Hammett principle is a principle in chemical kinetics proposed by David Yarrow Curtin and Louis Plack Hammett. It states that, for a reaction that has a pair of reactive intermediates or reactants that interconvert rapidly (as is usually the case for conformational isomers), each going irreversibly to a different product, the product ratio will depend both on the difference in energy between the two conformers and the free energy of the transition state going to each product.".
- Q1145478 label "Curtin–Hammett principle".
- Q1145478 depiction Curtin-Hammett_Principle_Diagram.png.