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- Thiol-yne_reaction abstract "The Thiol-yne reaction (also alkyne hydrothiolation) is an organic reaction between a thiol and an alkyne. The reaction product is an alkenyl sulfide. The reaction was first reported in 1949 with thioacetic acid as reagent and rediscovered in 2009 It is used in click chemistry and in polymerization, especially with dendrimers. This addition reaction is typically facilitated by a radical initiator or UV irradiation and proceeds through a sulfanyl radical species.With monoaddition a mixture of E/Z alkenes form. The mode of addition is anti-Markovnikov. The radical intermediate can engage in secondary reactions such as cyclisation. With diaddition the 1,2-disulfide or the 1,1- dithioacetal forms. Reported catalysts for radical additions are triethylborane, indium(III) bromide and AIBN. The reaction is also reported to be catalysed by cationic rhodium and iridium complexes, by thorium and uranium complexes, by rhodium complexes, by caesium carbonate and by gold.Diphenyl disulphide reacts with alkynes to a 1,2-bis(phenylthio)ethylene. Reported alkynes are ynamides".
- Thiol-yne_reaction thumbnail Thiol-yne-reaction.svg?width=300.
- Thiol-yne_reaction wikiPageID "27144045".
- Thiol-yne_reaction wikiPageLength "15246".
- Thiol-yne_reaction wikiPageOutDegree "38".
- Thiol-yne_reaction wikiPageRevisionID "707937937".
- Thiol-yne_reaction wikiPageWikiLink Addition_reaction.
- Thiol-yne_reaction wikiPageWikiLink Alkyne.
- Thiol-yne_reaction wikiPageWikiLink Azobisisobutyronitrile.
- Thiol-yne_reaction wikiPageWikiLink Branching_(polymer_chemistry).
- Thiol-yne_reaction wikiPageWikiLink Caesium_carbonate.
- Thiol-yne_reaction wikiPageWikiLink Category:Organic_reactions.
- Thiol-yne_reaction wikiPageWikiLink Chain-growth_polymerization.
- Thiol-yne_reaction wikiPageWikiLink Click_chemistry.
- Thiol-yne_reaction wikiPageWikiLink Copolymer.
- Thiol-yne_reaction wikiPageWikiLink Dendrimer.
- Thiol-yne_reaction wikiPageWikiLink Diphenyl_disulfide.
- Thiol-yne_reaction wikiPageWikiLink E-Z_notation.
- Thiol-yne_reaction wikiPageWikiLink Free-radical_addition.
- Thiol-yne_reaction wikiPageWikiLink Gold.
- Thiol-yne_reaction wikiPageWikiLink Indium(III)_bromide.
- Thiol-yne_reaction wikiPageWikiLink Iridium.
- Thiol-yne_reaction wikiPageWikiLink Markovnikovs_rule.
- Thiol-yne_reaction wikiPageWikiLink Michael_reaction.
- Thiol-yne_reaction wikiPageWikiLink Organic_reaction.
- Thiol-yne_reaction wikiPageWikiLink Polymer_chemistry.
- Thiol-yne_reaction wikiPageWikiLink Polymerization.
- Thiol-yne_reaction wikiPageWikiLink Radical_initiator.
- Thiol-yne_reaction wikiPageWikiLink Rhodium.
- Thiol-yne_reaction wikiPageWikiLink Star-shaped_polymer.
- Thiol-yne_reaction wikiPageWikiLink Thioacetal.
- Thiol-yne_reaction wikiPageWikiLink Thioacetic_acid.
- Thiol-yne_reaction wikiPageWikiLink Thiol.
- Thiol-yne_reaction wikiPageWikiLink Thiol-ene_reaction.
- Thiol-yne_reaction wikiPageWikiLink Thorium.
- Thiol-yne_reaction wikiPageWikiLink Triethylborane.
- Thiol-yne_reaction wikiPageWikiLink Ultraviolet_germicidal_irradiation.
- Thiol-yne_reaction wikiPageWikiLink Uranium.
- Thiol-yne_reaction wikiPageWikiLink File:Ichinose_thiol-yne_1987.svg.
- Thiol-yne_reaction wikiPageWikiLink File:Thiol-yne-reaction.svg.
- Thiol-yne_reaction wikiPageWikiLinkText "Thiol-yne reaction".
- Thiol-yne_reaction wikiPageWikiLinkText "thiol-yne reaction".
- Thiol-yne_reaction colwidth "30".
- Thiol-yne_reaction wikiPageUsesTemplate Template:Reflist.
- Thiol-yne_reaction subject Category:Organic_reactions.
- Thiol-yne_reaction hypernym Reaction.
- Thiol-yne_reaction type Disease.
- Thiol-yne_reaction type Reaction.
- Thiol-yne_reaction comment "The Thiol-yne reaction (also alkyne hydrothiolation) is an organic reaction between a thiol and an alkyne. The reaction product is an alkenyl sulfide. The reaction was first reported in 1949 with thioacetic acid as reagent and rediscovered in 2009 It is used in click chemistry and in polymerization, especially with dendrimers.".
- Thiol-yne_reaction label "Thiol-yne reaction".
- Thiol-yne_reaction sameAs Q7784672.
- Thiol-yne_reaction sameAs Thiol-yn-reactie.
- Thiol-yne_reaction sameAs m.0bwlx2j.
- Thiol-yne_reaction sameAs Q7784672.
- Thiol-yne_reaction wasDerivedFrom Thiol-yne_reaction?oldid=707937937.
- Thiol-yne_reaction depiction Thiol-yne-reaction.svg.
- Thiol-yne_reaction isPrimaryTopicOf Thiol-yne_reaction.
