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- Template_reaction abstract "In chemistry, a template reaction is any of a class of ligand-based reactions that occur between two or more adjacent coordination sites on a metal center. In the absence of the metal ion, the same organic reactants produce different products. The term is mainly used in coordination chemistry. The template effects emphasizes the pre-organization provided by the coordination sphere, although the coordination modifies the electronic properties (acidity, electrophilicity, etc.) of ligands.An early example is the dialkylation of a nickel dithiolate:The corresponding alkylation in the absence of a metal ion would yield polymers. Crown ethers arise from dialkylations that are templated by alkali metals. Other template reactions include the Mannich and Schiff base condensations. The condensation of formaldehyde, ammonia, and tris(ethylenediamine)cobalt(III) to give a clathrochelate complex is one example. Phthalocyanines are generated by metal-templated condensations of phthalonitriles.".
- Template_reaction thumbnail TemplateAlkylation.png?width=300.
- Template_reaction wikiPageID "24398213".
- Template_reaction wikiPageLength "4510".
- Template_reaction wikiPageOutDegree "24".
- Template_reaction wikiPageRevisionID "687663984".
- Template_reaction wikiPageWikiLink Benzene.
- Template_reaction wikiPageWikiLink Carbonylation.
- Template_reaction wikiPageWikiLink Catalysis.
- Template_reaction wikiPageWikiLink Category:Polymer_chemistry.
- Template_reaction wikiPageWikiLink Chemistry.
- Template_reaction wikiPageWikiLink Clathrochelate.
- Template_reaction wikiPageWikiLink Coordination_complex.
- Template_reaction wikiPageWikiLink Crown_ether.
- Template_reaction wikiPageWikiLink Cyclooctatetraene.
- Template_reaction wikiPageWikiLink Formaldehyde.
- Template_reaction wikiPageWikiLink Homogeneous_catalysis.
- Template_reaction wikiPageWikiLink Ligand.
- Template_reaction wikiPageWikiLink Mannich_reaction.
- Template_reaction wikiPageWikiLink Nickel.
- Template_reaction wikiPageWikiLink Oligomer.
- Template_reaction wikiPageWikiLink Phthalocyanine.
- Template_reaction wikiPageWikiLink Phthalonitrile.
- Template_reaction wikiPageWikiLink Porphyrin.
- Template_reaction wikiPageWikiLink Schiff_base.
- Template_reaction wikiPageWikiLink Triphenylphosphine.
- Template_reaction wikiPageWikiLink Tris(ethylenediamine)cobalt(III)_chloride.
- Template_reaction wikiPageWikiLink File:18-crown-6_was_synthesized_using_potassium_ion_as_the_template_cation.png.
- Template_reaction wikiPageWikiLink File:CurtisMac.png.
- Template_reaction wikiPageWikiLink File:TemplateAlkylation.png.
- Template_reaction wikiPageWikiLinkText "Template reaction".
- Template_reaction wikiPageWikiLinkText "template reaction".
- Template_reaction subject Category:Polymer_chemistry.
- Template_reaction comment "In chemistry, a template reaction is any of a class of ligand-based reactions that occur between two or more adjacent coordination sites on a metal center. In the absence of the metal ion, the same organic reactants produce different products. The term is mainly used in coordination chemistry.".
- Template_reaction label "Template reaction".
- Template_reaction sameAs Q1100227.
- Template_reaction sameAs m.05p7qy9.
- Template_reaction sameAs Темплатный_эффект.
- Template_reaction sameAs Q1100227.
- Template_reaction wasDerivedFrom Template_reaction?oldid=687663984.
- Template_reaction depiction TemplateAlkylation.png.
- Template_reaction isPrimaryTopicOf Template_reaction.