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- Tebbes_reagent abstract "The Tebbe reagent is the organometallic compound with the formula (C5H5)2TiCH2ClAl(CH3)2. It is used in the methylenation of carbonyl compounds, that is it converts organic compounds containing the R2C=O group into the related R2C=CH2 derivative. It is a red solid that is pyrophoric in the air, and thus is typically handled with air-free techniques. It was originally synthesized by Fred Tebbe at DuPont Central Research.Tebbe's reagent contains two tetrahedral metal centers linked by a pair of bridging ligands. The titanium has two cyclopentadienyl ([C5H5]−, or Cp) rings and aluminium has two methyl groups. The titanium and aluminium atoms are linked together by both a methylene bridge (-CH2-) and a chloride atom in a nearly square-planar (Ti–CH2–Al–Cl) geometry. The Tebbe reagent was the first reported compound where a methylene bridge connects a transition metal (Ti) and a main group metal (Al).".
- Tebbes_reagent iupacName "μ-Chloro[di(cyclopenta-2,4-dien-1-yl)]dimethyl(μ-methylene)titaniumaluminum".
- Tebbes_reagent thumbnail TebbeRgt.png?width=300.
- Tebbes_reagent wikiPageID "4218036".
- Tebbes_reagent wikiPageLength "9122".
- Tebbes_reagent wikiPageOutDegree "48".
- Tebbes_reagent wikiPageRevisionID "670198049".
- Tebbes_reagent wikiPageWikiLink Acyl_chloride.
- Tebbes_reagent wikiPageWikiLink Air-free_technique.
- Tebbes_reagent wikiPageWikiLink Aldehyde.
- Tebbes_reagent wikiPageWikiLink Alkene.
- Tebbes_reagent wikiPageWikiLink Amide.
- Tebbes_reagent wikiPageWikiLink Bridging_ligand.
- Tebbes_reagent wikiPageWikiLink Carbonyl.
- Tebbes_reagent wikiPageWikiLink Category:Metallocenes.
- Tebbes_reagent wikiPageWikiLink Category:Organoaluminium_compounds.
- Tebbes_reagent wikiPageWikiLink Category:Organotitanium_compounds.
- Tebbes_reagent wikiPageWikiLink Category:Reagents_for_organic_chemistry.
- Tebbes_reagent wikiPageWikiLink Chirality_(chemistry).
- Tebbes_reagent wikiPageWikiLink Cyclopentadienyl_complex.
- Tebbes_reagent wikiPageWikiLink Cyclopropanation.
- Tebbes_reagent wikiPageWikiLink DuPont_Central_Research.
- Tebbes_reagent wikiPageWikiLink Ester.
- Tebbes_reagent wikiPageWikiLink Frederick_N._Tebbe.
- Tebbes_reagent wikiPageWikiLink Kauffmann_olefination.
- Tebbes_reagent wikiPageWikiLink Lactone.
- Tebbes_reagent wikiPageWikiLink Lewis_acids_and_bases.
- Tebbes_reagent wikiPageWikiLink Methylene_bridge.
- Tebbes_reagent wikiPageWikiLink Nysted_reagent.
- Tebbes_reagent wikiPageWikiLink Organic_synthesis.
- Tebbes_reagent wikiPageWikiLink Organometallic_chemistry.
- Tebbes_reagent wikiPageWikiLink Organozinc_compound.
- Tebbes_reagent wikiPageWikiLink Oxophilicity.
- Tebbes_reagent wikiPageWikiLink Petasis_reagent.
- Tebbes_reagent wikiPageWikiLink Peterson_olefination.
- Tebbes_reagent wikiPageWikiLink Pyridine.
- Tebbes_reagent wikiPageWikiLink Pyrophoricity.
- Tebbes_reagent wikiPageWikiLink Reaction_mechanism.
- Tebbes_reagent wikiPageWikiLink Square_planar_molecular_geometry.
- Tebbes_reagent wikiPageWikiLink Stereochemistry.
- Tebbes_reagent wikiPageWikiLink Tetrahedral_molecular_geometry.
- Tebbes_reagent wikiPageWikiLink Titanocene_dichloride.
- Tebbes_reagent wikiPageWikiLink Toluene.
- Tebbes_reagent wikiPageWikiLink Transition_metal_carbene_complex.
- Tebbes_reagent wikiPageWikiLink Trimethylaluminium.
- Tebbes_reagent wikiPageWikiLink Wittig_reaction.
- Tebbes_reagent wikiPageWikiLink File:AmideCyclopropanation.png.
- Tebbes_reagent wikiPageWikiLink File:AmidecyclopropanationMechanism.png.
- Tebbes_reagent wikiPageWikiLink File:TREnolat.png.
- Tebbes_reagent wikiPageWikiLink File:TRmethylenation.png.
- Tebbes_reagent wikiPageWikiLink File:TebbeRgtEquil.png.
- Tebbes_reagent wikiPageWikiLink File:Tebbe_Reagent_Mechanism.png.
- Tebbes_reagent wikiPageWikiLinkText "Tebbe reaction".
- Tebbes_reagent wikiPageWikiLinkText "Tebbe's reagent".
- Tebbes_reagent imagefile "Tebbe's-reagent-3D-balls.png".
- Tebbes_reagent imagefile "TebbeRgt.png".
- Tebbes_reagent imagename "Ball-and-stick model of Tebbe's reagent".
- Tebbes_reagent imagename "Structure of Tebbe's reagent".
- Tebbes_reagent iupacname "μ-Chloro[di]dimethyltitaniumaluminum".
- Tebbes_reagent name "Tebbe's reagent".
- Tebbes_reagent othernames "Tebbe reagent".
- Tebbes_reagent verifiedrevid "401050656".
- Tebbes_reagent wikiPageUsesTemplate Template:Aluminium_compounds.
- Tebbes_reagent wikiPageUsesTemplate Template:Chem.
- Tebbes_reagent wikiPageUsesTemplate Template:Chembox.
- Tebbes_reagent wikiPageUsesTemplate Template:Chembox_Identifiers.
- Tebbes_reagent wikiPageUsesTemplate Template:Chembox_Properties.
- Tebbes_reagent wikiPageUsesTemplate Template:Reflist.
- Tebbes_reagent wikiPageUsesTemplate Template:Titanium_compounds.
- Tebbes_reagent subject Category:Metallocenes.
- Tebbes_reagent subject Category:Organoaluminium_compounds.
- Tebbes_reagent subject Category:Organotitanium_compounds.
- Tebbes_reagent subject Category:Reagents_for_organic_chemistry.
- Tebbes_reagent hypernym Compound.
- Tebbes_reagent type ChemicalCompound.
- Tebbes_reagent type ChemicalSubstance.
- Tebbes_reagent type Drug.
- Tebbes_reagent type Chemical.
- Tebbes_reagent type Cycloalkene.
- Tebbes_reagent type Reagent.
- Tebbes_reagent type ChemicalObject.
- Tebbes_reagent type Thing.
- Tebbes_reagent type Q11173.
- Tebbes_reagent comment "The Tebbe reagent is the organometallic compound with the formula (C5H5)2TiCH2ClAl(CH3)2. It is used in the methylenation of carbonyl compounds, that is it converts organic compounds containing the R2C=O group into the related R2C=CH2 derivative. It is a red solid that is pyrophoric in the air, and thus is typically handled with air-free techniques.".
- Tebbes_reagent label "Tebbe's reagent".
- Tebbes_reagent sameAs Q416243.
- Tebbes_reagent sameAs Tebbe-Reagenz.
- Tebbes_reagent sameAs واکنشگر_تبه.
- Tebbes_reagent sameAs Tebben_reagenssi.
- Tebbes_reagent sameAs Réactif_de_Tebbe.
- Tebbes_reagent sameAs テッベ試薬.
- Tebbes_reagent sameAs Tebbe-reagens.
- Tebbes_reagent sameAs Reagente_de_Tebbe.
- Tebbes_reagent sameAs m.0bqjmf.
- Tebbes_reagent sameAs Реагент_Теббе.
- Tebbes_reagent sameAs Q416243.
- Tebbes_reagent wasDerivedFrom Tebbes_reagent?oldid=670198049.
- Tebbes_reagent depiction TebbeRgt.png.
- Tebbes_reagent isPrimaryTopicOf Tebbes_reagent.
- Tebbes_reagent name "Tebbe's reagent".