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- Spectator_ligand abstract "In coordination chemistry, a spectator ligand is a ligand that does not participate in chemical reactions of the complex. Instead, spectator ligands (vs \"actor ligands\") occupy coordination sites. Spectator ligands tend to be of polydentate, such that the M-spectator ensemble is inert kinetically. Although they do not participate in reactions of the metal, spectator ligands influence the reactivity of the metal center to which they are bound.There are several different classes of ligand that can be considered spectator ligands. A few examples of common spectator ligands include trispyrazolylborates (Tp), cyclopentadienyl ligands (Cp), and many chelating diphosphines such as 1,2-bis(diphenylphosphino)ethane ligands (dppe). Varying the substituents on the spectator ligands greatly influences the solubility, stability, electronic and steric properties of the metal complex.".
- Spectator_ligand thumbnail LnMTp.png?width=300.
- Spectator_ligand wikiPageID "41340447".
- Spectator_ligand wikiPageLength "1549".
- Spectator_ligand wikiPageOutDegree "10".
- Spectator_ligand wikiPageRevisionID "646726591".
- Spectator_ligand wikiPageWikiLink 1,2-Bis(diphenylphosphino)ethane.
- Spectator_ligand wikiPageWikiLink Category:Coordination_chemistry.
- Spectator_ligand wikiPageWikiLink Category:Organometallic_chemistry.
- Spectator_ligand wikiPageWikiLink Coordination_complex.
- Spectator_ligand wikiPageWikiLink Cyclopentadienyl.
- Spectator_ligand wikiPageWikiLink Denticity.
- Spectator_ligand wikiPageWikiLink Ligand.
- Spectator_ligand wikiPageWikiLink Trispyrazolylborate.
- Spectator_ligand wikiPageWikiLink File:LnMTp.png.
- Spectator_ligand wikiPageWikiLink File:PdCl2(dppe)-3D-balls.png.
- Spectator_ligand wikiPageWikiLinkText "spectator ligand".
- Spectator_ligand wikiPageUsesTemplate Template:Reflist.
- Spectator_ligand subject Category:Coordination_chemistry.
- Spectator_ligand subject Category:Organometallic_chemistry.
- Spectator_ligand hypernym Ligand.
- Spectator_ligand type ChemicalSubstance.
- Spectator_ligand comment "In coordination chemistry, a spectator ligand is a ligand that does not participate in chemical reactions of the complex. Instead, spectator ligands (vs \"actor ligands\") occupy coordination sites. Spectator ligands tend to be of polydentate, such that the M-spectator ensemble is inert kinetically.".
- Spectator_ligand label "Spectator ligand".
- Spectator_ligand sameAs Q17074359.
- Spectator_ligand sameAs Legante_spettatore.
- Spectator_ligand sameAs m.0zn0c61.
- Spectator_ligand sameAs Q17074359.
- Spectator_ligand wasDerivedFrom Spectator_ligand?oldid=646726591.
- Spectator_ligand depiction LnMTp.png.
- Spectator_ligand isPrimaryTopicOf Spectator_ligand.