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- Nitrenium_ion abstract "A nitrenium ion (also called: aminylium ion) in organic chemistry is a reactive intermediate based on nitrogen with both an electron lone pair and a positive charge and with two substituents (R2N+). Nitrenium ions are isoelectronic with carbenes, and can exist in either a singlet or a triplet state. The parent nitrenium ion, NH2+, is a ground state triplet species with a gap of 30 kcal/mol to the lowest energy singlet state. Conversely, most arylnitrenium ions are ground state singlets. Certain substituted arylnitrenium ions can be ground state triplets, however. Currently, nitrenium ions see heavy study in the groups of Matt Platz (Ohio State), Michael Novak (Miami), and Daniel Falvey (University of Maryland).Aryl nitrenium ions are currently investigated because of their involvement in certain DNA damaging processes. These intermediates can have microsecond or longer lifetimes in water. They can also be exploited for useful synthetic processes.Nitrenium ions are also intermediates in organic reactions; for instance, the Bamberger rearrangement. They can also act as electrophiles in electrophilic aromatic substitution.The term imidonium ion with the same meaning, is now obsolete.".
- Nitrenium_ion wikiPageID "10393385".
- Nitrenium_ion wikiPageLength "2185".
- Nitrenium_ion wikiPageOutDegree "14".
- Nitrenium_ion wikiPageRevisionID "646717325".
- Nitrenium_ion wikiPageWikiLink Bamberger_rearrangement.
- Nitrenium_ion wikiPageWikiLink Carbene.
- Nitrenium_ion wikiPageWikiLink Category:Nitrogen_hydrides.
- Nitrenium_ion wikiPageWikiLink Category:Reactive_intermediates.
- Nitrenium_ion wikiPageWikiLink DNA.
- Nitrenium_ion wikiPageWikiLink Electrophile.
- Nitrenium_ion wikiPageWikiLink Electrophilic_aromatic_substitution.
- Nitrenium_ion wikiPageWikiLink Ion.
- Nitrenium_ion wikiPageWikiLink Lone_pair.
- Nitrenium_ion wikiPageWikiLink Nitrene.
- Nitrenium_ion wikiPageWikiLink Nitrogen.
- Nitrenium_ion wikiPageWikiLink Organic_chemistry.
- Nitrenium_ion wikiPageWikiLink Reactive_intermediate.
- Nitrenium_ion wikiPageWikiLink Triplet_state.
- Nitrenium_ion wikiPageWikiLinkText "Nitrenium ion".
- Nitrenium_ion wikiPageWikiLinkText "nitrenium ion".
- Nitrenium_ion wikiPageWikiLinkText "nitrenium".
- Nitrenium_ion wikiPageUsesTemplate Template:Reflist.
- Nitrenium_ion subject Category:Nitrogen_hydrides.
- Nitrenium_ion subject Category:Reactive_intermediates.
- Nitrenium_ion comment "A nitrenium ion (also called: aminylium ion) in organic chemistry is a reactive intermediate based on nitrogen with both an electron lone pair and a positive charge and with two substituents (R2N+). Nitrenium ions are isoelectronic with carbenes, and can exist in either a singlet or a triplet state. The parent nitrenium ion, NH2+, is a ground state triplet species with a gap of 30 kcal/mol to the lowest energy singlet state. Conversely, most arylnitrenium ions are ground state singlets.".
- Nitrenium_ion label "Nitrenium ion".
- Nitrenium_ion sameAs Q3154108.
- Nitrenium_ion sameAs Ion_nitrénium.
- Nitrenium_ion sameAs m.02qbg96.
- Nitrenium_ion sameAs Q3154108.
- Nitrenium_ion wasDerivedFrom Nitrenium_ion?oldid=646717325.
- Nitrenium_ion isPrimaryTopicOf Nitrenium_ion.