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- LIESST abstract "In chemistry and physics, LIESST (Light-Induced Excited Spin-State Trapping) is a method of changing the electronic spin state of a compound by means of irradiation with light.Many transition metal complexes with electronic configuration d4-d7 are capable of spin crossover (and d8 when molecular symmetry is lower than Oh). Spin crossover refers to where a transition from the high spin (HS) state to the low spin (LS) state or vice versa occurs. Alternatives to LIESST include using thermal changes and pressure to induce spin crossover. The metal most commonly exhibiting spin crossover is iron, with the first known example, an iron(III) tris(dithiocarbamato) complex, reported by Cambi et al. in 1931.For iron complexes, LIESST involves excitation of the low spin complex with green light to a triplet state. Two successive steps of intersystem crossing result in the high spin complex. Movement from the high spin complex to the low spin complex requires excitation with red light.".
- LIESST thumbnail Electron_distribution_in_the_two_different_spin_states_in_LIESST_for_a_d6_metal.PNG?width=300.
- LIESST wikiPageID "9430536".
- LIESST wikiPageLength "1933".
- LIESST wikiPageOutDegree "7".
- LIESST wikiPageRevisionID "544683999".
- LIESST wikiPageWikiLink Category:Coordination_chemistry.
- LIESST wikiPageWikiLink Category:Laboratory_techniques.
- LIESST wikiPageWikiLink Electron_configuration.
- LIESST wikiPageWikiLink File:Electron_distribution_in_the_two_different_spin_states_in_LIESST_for_a_d6_metal.PNG.
- LIESST wikiPageWikiLink Intersystem_crossing.
- LIESST wikiPageWikiLink Spin_crossover.
- LIESST wikiPageWikiLink Transition_metal.
- LIESST wikiPageWikiLinkText "LIESST".
- LIESST wikiPageWikiLinkText "light induced excited state spin trapping (LIESST)".
- LIESST wikiPageUsesTemplate Template:Chem-stub.
- LIESST subject Category:Coordination_chemistry.
- LIESST subject Category:Laboratory_techniques.
- LIESST hypernym Method.
- LIESST type Software.
- LIESST type Laboratory.
- LIESST type Technique.
- LIESST comment "In chemistry and physics, LIESST (Light-Induced Excited Spin-State Trapping) is a method of changing the electronic spin state of a compound by means of irradiation with light.Many transition metal complexes with electronic configuration d4-d7 are capable of spin crossover (and d8 when molecular symmetry is lower than Oh). Spin crossover refers to where a transition from the high spin (HS) state to the low spin (LS) state or vice versa occurs.".
- LIESST label "LIESST".
- LIESST sameAs Q906680.
- LIESST sameAs LIESST.
- LIESST sameAs Efecto_LIESST.
- LIESST sameAs m.0288ny3.
- LIESST sameAs Q906680.
- LIESST wasDerivedFrom LIESST?oldid=544683999.
- LIESST depiction Electron_distribution_in_the_two_different_spin_states_in_LIESST_for_a_d6_metal.PNG.
- LIESST isPrimaryTopicOf LIESST.