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- J-aggregate abstract "A J-aggregate is a type of dye with an absorption band that shifts to a longer wavelength (bathochromic shift) of increasing sharpness (higher absorption coefficient) when it aggregates under the influence of a solvent or additive or concentration as a result of supramolecular self-organisation. The dye can be characterized further by a small Stokes shift with a narrow band. The J in J-aggregate refers to E.E. Jelley who discovered the phenomenon in 1936. The dye is also called a Scheibe aggregate after G. Scheibe who also independently published on this topic in 1937.Scheibe and Jelley independently observed that in ethanol the dye PIC chloride has two broad absorption maxima at around 19,000 cm−1 and 20,500 cm−1 (526 and 488 nm respectively) and that in water a third sharp absorption maximum appears at 17,500 cm−1 (571 nm). The intensity of this band further increases on increasing concentration and on adding sodium chloride. In the oldest aggregation model for PIC chloride the individual molecules are stacked like a roll of coins forming a supramolecular polymer but the true nature of this aggregation phenomenon is still under investigation. Analysis is complicated because PIC chloride is not a planar molecule. The molecular axis can tilt in the stack creating a helix pattern. In other models the dye molecules orient themselves in a brickwork, ladder, or staircase fashion. In various experiments the J-band was found to split as a function of temperature, liquid crystal phases were found with concentrated solutions and CryoTEM revealed aggregeate rods 350 nm long and 2.3 nm in diameter.J-aggregate dyes are found with polymethine dyes in general, with cyanines, merocyanines, squaraine and perylene bisimides.In H-aggregates a hypsochromic shift is observed with low or no fluorescence.".
- J-aggregate thumbnail Diethyl-cyanine.svg?width=300.
- J-aggregate wikiPageID "31508894".
- J-aggregate wikiPageLength "3327".
- J-aggregate wikiPageOutDegree "25".
- J-aggregate wikiPageRevisionID "688097718".
- J-aggregate wikiPageWikiLink Absorption_band.
- J-aggregate wikiPageWikiLink Absorption_spectroscopy.
- J-aggregate wikiPageWikiLink Attenuation_coefficient.
- J-aggregate wikiPageWikiLink Bathochromic_shift.
- J-aggregate wikiPageWikiLink Category:Dyes.
- J-aggregate wikiPageWikiLink Category:Supramolecular_chemistry.
- J-aggregate wikiPageWikiLink Concentration.
- J-aggregate wikiPageWikiLink Cyanine.
- J-aggregate wikiPageWikiLink Dye.
- J-aggregate wikiPageWikiLink Ethanol.
- J-aggregate wikiPageWikiLink Fluorescence.
- J-aggregate wikiPageWikiLink Hypsochromic_shift.
- J-aggregate wikiPageWikiLink Liquid_crystal.
- J-aggregate wikiPageWikiLink Merocyanine.
- J-aggregate wikiPageWikiLink Polymethine.
- J-aggregate wikiPageWikiLink Rylene_dye.
- J-aggregate wikiPageWikiLink Sodium_chloride.
- J-aggregate wikiPageWikiLink Squaraine_dye.
- J-aggregate wikiPageWikiLink Stokes_shift.
- J-aggregate wikiPageWikiLink Supramolecular_chemistry.
- J-aggregate wikiPageWikiLink Supramolecular_polymers.
- J-aggregate wikiPageWikiLink Transmission_electron_microscopy.
- J-aggregate wikiPageWikiLink Wavelength.
- J-aggregate wikiPageWikiLink File:Diethyl-cyanine.svg.
- J-aggregate wikiPageWikiLink File:Fiber_to_crystalite_transformation.jpg.
- J-aggregate wikiPageWikiLinkText "J-aggregate".
- J-aggregate wikiPageUsesTemplate Template:Reflist.
- J-aggregate subject Category:Dyes.
- J-aggregate subject Category:Supramolecular_chemistry.
- J-aggregate hypernym Dye.
- J-aggregate type ChemicalCompound.
- J-aggregate type Textile.
- J-aggregate comment "A J-aggregate is a type of dye with an absorption band that shifts to a longer wavelength (bathochromic shift) of increasing sharpness (higher absorption coefficient) when it aggregates under the influence of a solvent or additive or concentration as a result of supramolecular self-organisation. The dye can be characterized further by a small Stokes shift with a narrow band. The J in J-aggregate refers to E.E. Jelley who discovered the phenomenon in 1936.".
- J-aggregate label "J-aggregate".
- J-aggregate sameAs Q6103812.
- J-aggregate sameAs m.0glpncj.
- J-aggregate sameAs Q6103812.
- J-aggregate wasDerivedFrom J-aggregate?oldid=688097718.
- J-aggregate depiction Diethyl-cyanine.svg.
- J-aggregate isPrimaryTopicOf J-aggregate.