Matches in DBpedia 2016-04 for { <http://dbpedia.org/resource/Dowd–Beckwith_ring-expansion_reaction> ?p ?o }
Showing triples 1 to 63 of
63
with 100 triples per page.
- Dowd–Beckwith_ring-expansion_reaction abstract "The Dowd–Beckwith ring-expansion reaction is an organic reaction in which a cyclic β-keto ester is expanded by up to 4 carbons in a free radical ring expansion reaction through an α-alkylhalo substituent . The radical initiator system is based on AIBN and tributyltin hydride. The cyclic β-keto ester can be obtained through a Dieckmann condensation. The original reaction consisted of a nucleophilic aliphatic substitution of the enolate of ethyl cyclohexanone-2-carboxylate with 1,4-diiodobutane and sodium hydride followed by ring expansion to ethyl cyclodecanone-6-carboxylate. A side-reaction is organic reduction of the iodoalkane.".
- Dowd–Beckwith_ring-expansion_reaction thumbnail DowdBeckwithRingExpansion.png?width=300.
- Dowd–Beckwith_ring-expansion_reaction wikiPageExternalLink f_ja00255a071.pdf.
- Dowd–Beckwith_ring-expansion_reaction wikiPageExternalLink f_ja00216a033.pdf.
- Dowd–Beckwith_ring-expansion_reaction wikiPageExternalLink ja00245a069?journalCode=jacsat&quickLinkVolume=109&quickLinkPage=3493&volume=109.pdf.
- Dowd–Beckwith_ring-expansion_reaction wikiPageExternalLink jo051551g.
- Dowd–Beckwith_ring-expansion_reaction wikiPageID "3227838".
- Dowd–Beckwith_ring-expansion_reaction wikiPageLength "3639".
- Dowd–Beckwith_ring-expansion_reaction wikiPageOutDegree "38".
- Dowd–Beckwith_ring-expansion_reaction wikiPageRevisionID "641060446".
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Activation_energy.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Alkyl.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Azobisisobutyronitrile.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Bicyclic_molecule.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Carbonyl.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Catalytic_cycle.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Category:Name_reactions.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Category:Rearrangement_reactions.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Deuterium.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Dieckmann_condensation.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Enol.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Ester.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Halogen.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Journal_of_Organic_Chemistry.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Journal_of_the_American_Chemical_Society.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Ketone.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Ketyl.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Nucleophilic_substitution.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Organic_reaction.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Organic_redox_reaction.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Radical_(chemistry).
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Reaction_mechanism.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Rearrangement_reaction.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Ring_expansion_and_ring_contraction.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Sodium_hydride.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Substituent.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink Tributyltin_hydride.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink File:Dowd-Beckwith.png.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink File:DowdBeckwithRingExpansion.png.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLink File:DowdBeckwithRingExpansionMechanism.png.
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLinkText "Dowd–Beckwith reaction".
- Dowd–Beckwith_ring-expansion_reaction wikiPageWikiLinkText "Dowd–Beckwith ring-expansion reaction".
- Dowd–Beckwith_ring-expansion_reaction wikiPageUsesTemplate Template:Doi.
- Dowd–Beckwith_ring-expansion_reaction wikiPageUsesTemplate Template:Note.
- Dowd–Beckwith_ring-expansion_reaction wikiPageUsesTemplate Template:Ref.
- Dowd–Beckwith_ring-expansion_reaction wikiPageUsesTemplate Template:Use_dmy_dates.
- Dowd–Beckwith_ring-expansion_reaction subject Category:Name_reactions.
- Dowd–Beckwith_ring-expansion_reaction subject Category:Rearrangement_reactions.
- Dowd–Beckwith_ring-expansion_reaction hypernym Reaction.
- Dowd–Beckwith_ring-expansion_reaction type Disease.
- Dowd–Beckwith_ring-expansion_reaction type Eponym.
- Dowd–Beckwith_ring-expansion_reaction type Reaction.
- Dowd–Beckwith_ring-expansion_reaction type Redirect.
- Dowd–Beckwith_ring-expansion_reaction comment "The Dowd–Beckwith ring-expansion reaction is an organic reaction in which a cyclic β-keto ester is expanded by up to 4 carbons in a free radical ring expansion reaction through an α-alkylhalo substituent . The radical initiator system is based on AIBN and tributyltin hydride. The cyclic β-keto ester can be obtained through a Dieckmann condensation.".
- Dowd–Beckwith_ring-expansion_reaction label "Dowd–Beckwith ring-expansion reaction".
- Dowd–Beckwith_ring-expansion_reaction sameAs Q5302672.
- Dowd–Beckwith_ring-expansion_reaction sameAs Rxc3xa9action_dexpansion_de_cycle_de_Dowd-Beckwith.
- Dowd–Beckwith_ring-expansion_reaction sameAs m.08_scx.
- Dowd–Beckwith_ring-expansion_reaction sameAs Q5302672.
- Dowd–Beckwith_ring-expansion_reaction sameAs Dowd–Beckwith扩环反应.
- Dowd–Beckwith_ring-expansion_reaction wasDerivedFrom Dowd–Beckwith_ring-expansion_reaction?oldid=641060446.
- Dowd–Beckwith_ring-expansion_reaction depiction DowdBeckwithRingExpansion.png.
- Dowd–Beckwith_ring-expansion_reaction isPrimaryTopicOf Dowd–Beckwith_ring-expansion_reaction.