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- Butterfly_cluster_compound abstract "In the area of metal cluster chemistry, a butterfly cluster compound usually describes tetrametallic clusters containing five M-M bonds. A prototype of this motif is [Re4(CO)12]2-. Most butterfly clusters have additional bridging ligands. One inexample is the tetraphosphide [[Rh4(CO)5(PPh2)5]]-. A carbide-containing butterfly cluster is [Fe4C(CO)12]2-.Bonding in such clusters is often discussed in the context of polyhedral skeletal electron pair theory. This theory predicts that tetrametallic clusters with 60 valence electrons will adopt tetrahedral geometry with six M-M bonds. Tetrahedral clusters is classified as nido clusterrs. By addition of 2e, the 60e cluster opens one edge, as manifested in the butterfly motif.".
- Butterfly_cluster_compound thumbnail Re4CO122-.svg?width=300.
- Butterfly_cluster_compound wikiPageID "46456176".
- Butterfly_cluster_compound wikiPageLength "1263".
- Butterfly_cluster_compound wikiPageOutDegree "8".
- Butterfly_cluster_compound wikiPageRevisionID "657295181".
- Butterfly_cluster_compound wikiPageWikiLink Bridging_ligand.
- Butterfly_cluster_compound wikiPageWikiLink Category:Cluster_chemistry.
- Butterfly_cluster_compound wikiPageWikiLink Chemical_bond.
- Butterfly_cluster_compound wikiPageWikiLink Cluster_chemistry.
- Butterfly_cluster_compound wikiPageWikiLink Phosphide.
- Butterfly_cluster_compound wikiPageWikiLink Polyhedral_skeletal_electron_pair_theory.
- Butterfly_cluster_compound wikiPageWikiLink File:Re4CO122-.svg.
- Butterfly_cluster_compound wikiPageWikiLink sub%3E.
- Butterfly_cluster_compound wikiPageWikiLinkText "Butterfly cluster compound".
- Butterfly_cluster_compound subject Category:Cluster_chemistry.
- Butterfly_cluster_compound comment "In the area of metal cluster chemistry, a butterfly cluster compound usually describes tetrametallic clusters containing five M-M bonds. A prototype of this motif is [Re4(CO)12]2-. Most butterfly clusters have additional bridging ligands. One inexample is the tetraphosphide [[Rh4(CO)5(PPh2)5]]-. A carbide-containing butterfly cluster is [Fe4C(CO)12]2-.Bonding in such clusters is often discussed in the context of polyhedral skeletal electron pair theory.".
- Butterfly_cluster_compound label "Butterfly cluster compound".
- Butterfly_cluster_compound sameAs m.0134jg2p.
- Butterfly_cluster_compound wasDerivedFrom Butterfly_cluster_compound?oldid=657295181.
- Butterfly_cluster_compound depiction Re4CO122-.svg.
- Butterfly_cluster_compound isPrimaryTopicOf Butterfly_cluster_compound.