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- Bergmann_azlactone_peptide_synthesis abstract "The Bergmann azlactone peptide synthesis is a classic organic synthesis process for the preparation of dipeptides.In the presence of a base, peptides are formed by aminolysis of N-carboxyanhydrides of amino acids with amino acid esters (Figure 1). This reaction can be looked at in further detail by Bailey.The resulting peptide is then protected by esters of benzylchroroformate in order to keep the amino groups intact (Figure 2).This mechanism serves as a source of protection for the amino group in the amino acid. The ester will block the amino group from binding with other molecules.The last step in this reaction is the cyclization of the N-haloacylamino acids with an acetanhydride. This will result in the expected azlactone (Figure 3). The reaction with a second amino acid allows for the ring to open, later forming an acylated unsaturated dipeptide. The reaction happens in a step-wise function which allows for the amino group to be protected and the azlactone to be produced.Catalytic hydrogenation and hydrolysis then take place in order to produce the dipeptide (Figure 4).".
- Bergmann_azlactone_peptide_synthesis thumbnail First_reaction.png?width=300.
- Bergmann_azlactone_peptide_synthesis wikiPageExternalLink bergmann1.htm.
- Bergmann_azlactone_peptide_synthesis wikiPageID "11310861".
- Bergmann_azlactone_peptide_synthesis wikiPageLength "2638".
- Bergmann_azlactone_peptide_synthesis wikiPageOutDegree "17".
- Bergmann_azlactone_peptide_synthesis wikiPageRevisionID "702841966".
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Acetic_anhydride.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Amino_acid.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Aminolysis.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Category:Chemical_reactions.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Category:Name_reactions.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Cyclic_compound.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Dipeptide.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Ester.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Hydrogenation.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Hydrolysis.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Organic_synthesis.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Oxazolone.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink Peptide.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink File:Azlactone.png.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink File:Cyclizationstep.png.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink File:First_reaction.png.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLink File:Protection_of_amino_group.png.
- Bergmann_azlactone_peptide_synthesis wikiPageWikiLinkText "Bergmann azlactone peptide synthesis".
- Bergmann_azlactone_peptide_synthesis wikiPageUsesTemplate Template:Reflist.
- Bergmann_azlactone_peptide_synthesis subject Category:Chemical_reactions.
- Bergmann_azlactone_peptide_synthesis subject Category:Name_reactions.
- Bergmann_azlactone_peptide_synthesis hypernym Process.
- Bergmann_azlactone_peptide_synthesis type Election.
- Bergmann_azlactone_peptide_synthesis type Eponym.
- Bergmann_azlactone_peptide_synthesis type Reaction.
- Bergmann_azlactone_peptide_synthesis comment "The Bergmann azlactone peptide synthesis is a classic organic synthesis process for the preparation of dipeptides.In the presence of a base, peptides are formed by aminolysis of N-carboxyanhydrides of amino acids with amino acid esters (Figure 1).".
- Bergmann_azlactone_peptide_synthesis label "Bergmann azlactone peptide synthesis".
- Bergmann_azlactone_peptide_synthesis sameAs m.02sh73.
- Bergmann_azlactone_peptide_synthesis wasDerivedFrom Bergmann_azlactone_peptide_synthesis?oldid=702841966.
- Bergmann_azlactone_peptide_synthesis depiction First_reaction.png.
- Bergmann_azlactone_peptide_synthesis isPrimaryTopicOf Bergmann_azlactone_peptide_synthesis.
