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- Arndt–Eistert_reaction abstract "The Arndt–Eistert synthesis is a series of chemical reactions designed to convert a carboxylic acid to a higher carboxylic acid homologue (i.e. contains one additional carbon atom) and is considered a homologation process. Named for the German chemists Fritz Arndt (1885–1969) and Bernd Eistert (1902–1978), Arndt–Eistert synthesis is a popular method of producing β-amino acids from α-amino acids. Acid chlorides react with diazomethane to give diazoketones. In the presence of a nucleophile (water) and a metal catalyst (Ag2O), diazoketones will form the desired acid homologue.Overview of the Arndt–Eistert reactionWhile the classic Arndt–Eistert synthesis uses thionyl chloride to convert the starting acid to an acid chloride, any procedure can be used that will generate an acid chloride.Diazoketones are typically generated as described here, but other methods such as diazo-group transfer can also apply.Since diazomethane is toxic and violently explosive, many safer alternatives have been developed, such as the usage of ynolates (Kowalski ester homologation) or diazo(trimethylsilyl)methane.".
- Arndt–Eistert_reaction thumbnail Arndt-Eistert-Homologisierung_allgemein.svg?width=300.
- Arndt–Eistert_reaction wikiPageID "2950875".
- Arndt–Eistert_reaction wikiPageLength "7467".
- Arndt–Eistert_reaction wikiPageOutDegree "42".
- Arndt–Eistert_reaction wikiPageRevisionID "705009247".
- Arndt–Eistert_reaction wikiPageWikiLink 1,2-rearrangement.
- Arndt–Eistert_reaction wikiPageWikiLink Acyl_chloride.
- Arndt–Eistert_reaction wikiPageWikiLink Amino_acid.
- Arndt–Eistert_reaction wikiPageWikiLink Bernd_Eistert.
- Arndt–Eistert_reaction wikiPageWikiLink Beta-peptide.
- Arndt–Eistert_reaction wikiPageWikiLink Carboxylic_acid.
- Arndt–Eistert_reaction wikiPageWikiLink Catalysis.
- Arndt–Eistert_reaction wikiPageWikiLink Category:Carbon-carbon_bond_forming_reactions.
- Arndt–Eistert_reaction wikiPageWikiLink Category:Chemical_synthesis_of_amino_acids.
- Arndt–Eistert_reaction wikiPageWikiLink Category:Name_reactions.
- Arndt–Eistert_reaction wikiPageWikiLink Category:Rearrangement_reactions.
- Arndt–Eistert_reaction wikiPageWikiLink Chemical_reaction.
- Arndt–Eistert_reaction wikiPageWikiLink Curtius_rearrangement.
- Arndt–Eistert_reaction wikiPageWikiLink Diazo.
- Arndt–Eistert_reaction wikiPageWikiLink Diazoketone.
- Arndt–Eistert_reaction wikiPageWikiLink Diazomethane.
- Arndt–Eistert_reaction wikiPageWikiLink Enantiomeric_excess.
- Arndt–Eistert_reaction wikiPageWikiLink Fritz_Arndt.
- Arndt–Eistert_reaction wikiPageWikiLink Homologation.
- Arndt–Eistert_reaction wikiPageWikiLink Homologation_reaction.
- Arndt–Eistert_reaction wikiPageWikiLink Hydrolysis.
- Arndt–Eistert_reaction wikiPageWikiLink Insertion_reaction.
- Arndt–Eistert_reaction wikiPageWikiLink Ketene.
- Arndt–Eistert_reaction wikiPageWikiLink Kowalski_ester_homologation.
- Arndt–Eistert_reaction wikiPageWikiLink Lossen_rearrangement.
- Arndt–Eistert_reaction wikiPageWikiLink Nierenstein_reaction.
- Arndt–Eistert_reaction wikiPageWikiLink Nucleophile.
- Arndt–Eistert_reaction wikiPageWikiLink Phenylalanine.
- Arndt–Eistert_reaction wikiPageWikiLink Platinum.
- Arndt–Eistert_reaction wikiPageWikiLink Properties_of_water.
- Arndt–Eistert_reaction wikiPageWikiLink Silver_oxide.
- Arndt–Eistert_reaction wikiPageWikiLink Tert-Butyloxycarbonyl_protecting_group.
- Arndt–Eistert_reaction wikiPageWikiLink Thionyl_chloride.
- Arndt–Eistert_reaction wikiPageWikiLink Triethylamine.
- Arndt–Eistert_reaction wikiPageWikiLink Trimethylsilyldiazomethane.
- Arndt–Eistert_reaction wikiPageWikiLink Wolff_rearrangement.
- Arndt–Eistert_reaction wikiPageWikiLink Ynolate.
- Arndt–Eistert_reaction wikiPageWikiLink File:Arndt-Eistert-Homologisierung_allgemein.svg.
- Arndt–Eistert_reaction wikiPageWikiLink File:Homologation_of_N-boc-phenylalanine.png.
- Arndt–Eistert_reaction wikiPageWikiLinkText "Arndt%E2%80%93Eistert reaction".
- Arndt–Eistert_reaction wikiPageWikiLinkText "Arndt–Eistert reaction".
- Arndt–Eistert_reaction wikiPageUsesTemplate Template:Reflist.
- Arndt–Eistert_reaction wikiPageUsesTemplate Template:Use_dmy_dates.
- Arndt–Eistert_reaction subject Category:Carbon-carbon_bond_forming_reactions.
- Arndt–Eistert_reaction subject Category:Chemical_synthesis_of_amino_acids.
- Arndt–Eistert_reaction subject Category:Name_reactions.
- Arndt–Eistert_reaction subject Category:Rearrangement_reactions.
- Arndt–Eistert_reaction hypernym Series.
- Arndt–Eistert_reaction type TelevisionShow.
- Arndt–Eistert_reaction type Eponym.
- Arndt–Eistert_reaction type Reaction.
- Arndt–Eistert_reaction type Redirect.
- Arndt–Eistert_reaction comment "The Arndt–Eistert synthesis is a series of chemical reactions designed to convert a carboxylic acid to a higher carboxylic acid homologue (i.e. contains one additional carbon atom) and is considered a homologation process. Named for the German chemists Fritz Arndt (1885–1969) and Bernd Eistert (1902–1978), Arndt–Eistert synthesis is a popular method of producing β-amino acids from α-amino acids. Acid chlorides react with diazomethane to give diazoketones.".
- Arndt–Eistert_reaction label "Arndt–Eistert reaction".
- Arndt–Eistert_reaction sameAs Q137617.
- Arndt–Eistert_reaction sameAs Arndt-Eistert-Homologisierung.
- Arndt–Eistert_reaction sameAs Reacción_de_Arndt-Eistert.
- Arndt–Eistert_reaction sameAs Rxc3xa9action_dArndt-Eistert.
- Arndt–Eistert_reaction sameAs アーント・アイシュタート合成.
- Arndt–Eistert_reaction sameAs Arndt-Eistert-reactie.
- Arndt–Eistert_reaction sameAs m.08fp6c.
- Arndt–Eistert_reaction sameAs Q137617.
- Arndt–Eistert_reaction sameAs 阿恩特-艾斯特尔特合成.
- Arndt–Eistert_reaction wasDerivedFrom Arndt–Eistert_reaction?oldid=705009247.
- Arndt–Eistert_reaction depiction Arndt-Eistert-Homologisierung_allgemein.svg.
- Arndt–Eistert_reaction isPrimaryTopicOf Arndt–Eistert_reaction.