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- Achmatowicz_reaction abstract "The Achmatowicz Reaction is an organic synthesis in which a furan is converted to a dihydropyran. In the original publication by Osman Achmatowicz Jr. in 1971 furfuryl alcohol is reacted with bromine in methanol to 2,5-dimethoxy-2,5-dihydrofuran which rearranges to the dihydropyran with dilute sulfuric acid. Additional reaction steps, alcohol protection with methyl orthoformate and boron trifluoride) and ketone reduction with sodium borohydride produce an intermediate from which many monosaccharides can be synthesised.The Achmatowicz reactionThe Achmatowitz protocol has been used in total synthesis for example that of desoxoprosophylline, Pyrenophorin and Bao Gong Teng A. Very recently it has been used in diversity oriented synthesis Achmatowicz Burke 2006and in enantiomeric scaffolding.Achmatowicz Reaction Coombs 2008↑ ↑ ↑ ↑ ↑ ↑ ↑ ↑".
- Achmatowicz_reaction thumbnail The_Achmatowicz_reaction.svg?width=300.
- Achmatowicz_reaction wikiPageID "16161577".
- Achmatowicz_reaction wikiPageLength "3375".
- Achmatowicz_reaction wikiPageOutDegree "24".
- Achmatowicz_reaction wikiPageRevisionID "646113145".
- Achmatowicz_reaction wikiPageWikiLink Alcohol.
- Achmatowicz_reaction wikiPageWikiLink Boron_trifluoride.
- Achmatowicz_reaction wikiPageWikiLink Bromine.
- Achmatowicz_reaction wikiPageWikiLink Category:Name_reactions.
- Achmatowicz_reaction wikiPageWikiLink Category:Organic_reactions.
- Achmatowicz_reaction wikiPageWikiLink Chiral_pool_synthesis.
- Achmatowicz_reaction wikiPageWikiLink Dihydropyran.
- Achmatowicz_reaction wikiPageWikiLink Divergent_synthesis.
- Achmatowicz_reaction wikiPageWikiLink Furan.
- Achmatowicz_reaction wikiPageWikiLink Furfuryl_alcohol.
- Achmatowicz_reaction wikiPageWikiLink Ketone.
- Achmatowicz_reaction wikiPageWikiLink Methanol.
- Achmatowicz_reaction wikiPageWikiLink Monosaccharide.
- Achmatowicz_reaction wikiPageWikiLink Organic_redox_reaction.
- Achmatowicz_reaction wikiPageWikiLink Organic_synthesis.
- Achmatowicz_reaction wikiPageWikiLink Osman_Achmatowicz_Jr..
- Achmatowicz_reaction wikiPageWikiLink Protecting_group.
- Achmatowicz_reaction wikiPageWikiLink Sodium_borohydride.
- Achmatowicz_reaction wikiPageWikiLink Sulfuric_acid.
- Achmatowicz_reaction wikiPageWikiLink Total_synthesis.
- Achmatowicz_reaction wikiPageWikiLink Trimethyl_orthoformate.
- Achmatowicz_reaction wikiPageWikiLink File:AchmatowiczBurke2006.svg.
- Achmatowicz_reaction wikiPageWikiLink File:AchmatowiczReactionCoombs2008.svg.
- Achmatowicz_reaction wikiPageWikiLink File:The_Achmatowicz_reaction.svg.
- Achmatowicz_reaction wikiPageWikiLinkText "Achmatowicz reaction".
- Achmatowicz_reaction wikiPageUsesTemplate Template:Reflist.
- Achmatowicz_reaction subject Category:Name_reactions.
- Achmatowicz_reaction subject Category:Organic_reactions.
- Achmatowicz_reaction hypernym Synthesis.
- Achmatowicz_reaction type ProgrammingLanguage.
- Achmatowicz_reaction type Eponym.
- Achmatowicz_reaction type Reaction.
- Achmatowicz_reaction type Redirect.
- Achmatowicz_reaction comment "The Achmatowicz Reaction is an organic synthesis in which a furan is converted to a dihydropyran. In the original publication by Osman Achmatowicz Jr. in 1971 furfuryl alcohol is reacted with bromine in methanol to 2,5-dimethoxy-2,5-dihydrofuran which rearranges to the dihydropyran with dilute sulfuric acid.".
- Achmatowicz_reaction label "Achmatowicz reaction".
- Achmatowicz_reaction sameAs Q3493761.
- Achmatowicz_reaction sameAs Reacción_de_Achmatowicz.
- Achmatowicz_reaction sameAs Reaksi_Achmatowicz.
- Achmatowicz_reaction sameAs Reazione_di_Achmatowicz.
- Achmatowicz_reaction sameAs Reakcja_Achmatowicza.
- Achmatowicz_reaction sameAs m.03wbl58.
- Achmatowicz_reaction sameAs Q3493761.
- Achmatowicz_reaction sameAs Achmatowicz反应.
- Achmatowicz_reaction wasDerivedFrom Achmatowicz_reaction?oldid=646113145.
- Achmatowicz_reaction depiction The_Achmatowicz_reaction.svg.
- Achmatowicz_reaction isPrimaryTopicOf Achmatowicz_reaction.