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- Zinc_molybdate abstract "Zinc molybdate (ZnMoO4) is an inorganic material found in nature with two different types of crystalline phases: α-triclinic and β-monoclinic. In the α-ZnMoO4 triclinic structure, all zinc (Zn) atoms are bonded to six oxygen (O) atoms, forming the distorted octahedral [ZnO6] clusters. The molybdenum (Mo) atoms are coordinated to four O atoms, resulting in the tetrahedral [MoO4] clusters [1,2]. On the other hand, the β-ZnMoO4 monoclinic structure has both Zn and Mo atoms bonded to six O atoms, which promote the origin of distorted octahedral [ZnO6]/[MoO6] clusters, respectively [3]. Moreover, ZnMoO4 is an inorganic chemical compound. It is white to light-gray in color, which can be used as a corrosion inhibitor in paints and adhesives. While highly soluble molybdates (e.g. sodium molybdate) are toxic in high doses, zinc molybdate is essentially non-toxic because of its insolubility in water. Molybdates possess a lower toxicity than chromates or lead salts and are therefore seen as an interesting alternative to these salts for corrosion inhibition. One of the most common methods used to synthesize zinc molybdate is by mixing aqueous solutions of sodium molybdate and zinc chloride: the insoluble zinc molybdate will crystallize from this mixture. A less common procedure used is blending solid molybdenum trioxide powder with zinc oxide powder and then heating the mixture to above 600 °C.Fourier-transform Raman/infrared spectroscopies:Theoretical and experimental analyses of β-ZnMoO4 crystalsAccording to the group theory calculations and symmetry [4], β-ZnMoO4 crystals with a wolframite-type monoclinic structure present 3N = 36 degrees of freedom. Therefore, there are N = 12 atoms within the unit monoclinic cell. In case, β-ZnMoO4 crystals have 36 distinct vibrational modes (Raman and infrared) as indicated in Eq. (1) [5]:Γ(Raman + Infrared) = 8Ag + 10Bg + 8Au + 10Bu........................(1)where the Ag and Bg are Raman-active modes, and Au and Bu are active vibrational modes in the infrared spectrum; the A and B modes are nondegenerate. The terms ‘‘g and u’’ subscripts indicate the parity under inversion in centrosymmetric β-ZnMoO4 crystals. Therefore, only 18 active vibrational modes are expected in Ramanspectra of b-ZnMoO4 crystals as represented by Eq. (2) below:Γ(Raman + Infrared) = 8Ag + 10Bg.....................................(2) (ZnMoO4)".
- Zinc_molybdate wikiPageExternalLink improv.html?CFID=32324&CFTOKEN=45092670.
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- Zinc_molybdate wikiPageID "5438079".
- Zinc_molybdate wikiPageLength "4700".
- Zinc_molybdate wikiPageOutDegree "17".
- Zinc_molybdate wikiPageRevisionID "650967659".
- Zinc_molybdate wikiPageWikiLink Category:Molybdates.
- Zinc_molybdate wikiPageWikiLink Category:Zinc_compounds.
- Zinc_molybdate wikiPageWikiLink Chemical_compound.
- Zinc_molybdate wikiPageWikiLink Inorganic.
- Zinc_molybdate wikiPageWikiLink Inorganic_compound.
- Zinc_molybdate wikiPageWikiLink Molybdenum.
- Zinc_molybdate wikiPageWikiLink Molybdenum_trioxide.
- Zinc_molybdate wikiPageWikiLink Monoclinic_crystal_system.
- Zinc_molybdate wikiPageWikiLink Oxygen.
- Zinc_molybdate wikiPageWikiLink Sodium_molybdate.
- Zinc_molybdate wikiPageWikiLink Solubility.
- Zinc_molybdate wikiPageWikiLink Tetragonal.
- Zinc_molybdate wikiPageWikiLink Tetragonal_crystal_system.
- Zinc_molybdate wikiPageWikiLink Triclinic_crystal_system.
- Zinc_molybdate wikiPageWikiLink Wolframite.
- Zinc_molybdate wikiPageWikiLink Zinc.
- Zinc_molybdate wikiPageWikiLink Zinc_chloride.
- Zinc_molybdate wikiPageWikiLink Zinc_oxide.
- Zinc_molybdate wikiPageWikiLinkText "".
- Zinc_molybdate wikiPageWikiLinkText "zinc molybdate".
- Zinc_molybdate hasPhotoCollection Zinc_molybdate.
- Zinc_molybdate name "Zinc molybdate".
- Zinc_molybdate verifiedrevid "385060199".
- Zinc_molybdate watchedfields "changed".
- Zinc_molybdate wikiPageUsesTemplate Template:Chembox.
- Zinc_molybdate wikiPageUsesTemplate Template:Refimprove.
- Zinc_molybdate wikiPageUsesTemplate Template:Reflist.
- Zinc_molybdate wikiPageUsesTemplate Template:Zinc_compounds.
- Zinc_molybdate subject Category:Molybdates.
- Zinc_molybdate subject Category:Zinc_compounds.
- Zinc_molybdate hypernym Material.
- Zinc_molybdate type Article.
- Zinc_molybdate type ChemicalCompound.
- Zinc_molybdate type ChemicalSubstance.
- Zinc_molybdate type Article.
- Zinc_molybdate type Chemical.
- Zinc_molybdate type ChemicalObject.
- Zinc_molybdate type Thing.
- Zinc_molybdate type Q11173.
- Zinc_molybdate comment "Zinc molybdate (ZnMoO4) is an inorganic material found in nature with two different types of crystalline phases: α-triclinic and β-monoclinic. In the α-ZnMoO4 triclinic structure, all zinc (Zn) atoms are bonded to six oxygen (O) atoms, forming the distorted octahedral [ZnO6] clusters. The molybdenum (Mo) atoms are coordinated to four O atoms, resulting in the tetrahedral [MoO4] clusters [1,2].".
- Zinc_molybdate label "Zinc molybdate".
- Zinc_molybdate sameAs مولیبدات_روی.
- Zinc_molybdate sameAs モリブデン酸亜鉛.
- Zinc_molybdate sameAs Molibdato_de_zinco.
- Zinc_molybdate sameAs m.0dlx6h.
- Zinc_molybdate sameAs Cink_molibdat.
- Zinc_molybdate sameAs Cink_molibdat.
- Zinc_molybdate sameAs Q1064971.
- Zinc_molybdate sameAs Q1064971.
- Zinc_molybdate sameAs 钼酸锌.
- Zinc_molybdate wasDerivedFrom Zinc_molybdate?oldid=650967659.
- Zinc_molybdate isPrimaryTopicOf Zinc_molybdate.
- Zinc_molybdate name "Zinc molybdate".