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- Sulfite_ester abstract "A sulfite ester is a functional group with the structure (RO)(R'O)SO. They adopt a trigonal pyramidal molecular geometry due to the presence of lone pairs on the sulphur atom. When substituents R and R' differ, the compound is chiral owing to the stereogenic sulphur centre; when the R groups are the same the compound will have idealised Cs molecular symmetry. They are commonly prepared by the reaction of thionyl chloride with alcohols. The reaction is typically performed at room temperature to prevent the alcohol being converted into a chloroalkane. Bases such as pyridine can also be used to promote the reaction: 2 ROH + SOCl2 → (RO)2SO + 2 HClThe pesticide endosulfan is a sulfite ester. Some simple members include ethylene sulfite, dimethyl sulfite, and diphenylsulfite. Many examples have been prepared from diols, such as sugars. Sulfite esters can be powerful alkylation and hydroxyalkylation reagents.".
- Sulfite_ester thumbnail Dimethyl-sulfite-GG-conformer-2D.png?width=300.
- Sulfite_ester wikiPageID "31283000".
- Sulfite_ester wikiPageLength "1631".
- Sulfite_ester wikiPageOutDegree "17".
- Sulfite_ester wikiPageRevisionID "619532925".
- Sulfite_ester wikiPageWikiLink Alkylation.
- Sulfite_ester wikiPageWikiLink Category:Esters.
- Sulfite_ester wikiPageWikiLink Category:Functional_groups.
- Sulfite_ester wikiPageWikiLink Category:Organic_compounds.
- Sulfite_ester wikiPageWikiLink Chiral.
- Sulfite_ester wikiPageWikiLink Chirality.
- Sulfite_ester wikiPageWikiLink Chloroalkane.
- Sulfite_ester wikiPageWikiLink Dimethyl_sulfite.
- Sulfite_ester wikiPageWikiLink Endosulfan.
- Sulfite_ester wikiPageWikiLink Functional_group.
- Sulfite_ester wikiPageWikiLink HCl.
- Sulfite_ester wikiPageWikiLink Hydrogen_chloride.
- Sulfite_ester wikiPageWikiLink Lone_pair.
- Sulfite_ester wikiPageWikiLink Lone_pairs.
- Sulfite_ester wikiPageWikiLink Molecular_symmetry.
- Sulfite_ester wikiPageWikiLink Organochloride.
- Sulfite_ester wikiPageWikiLink Pyridine.
- Sulfite_ester wikiPageWikiLink Side_chain.
- Sulfite_ester wikiPageWikiLink Thionyl_chloride.
- Sulfite_ester wikiPageWikiLink Trigonal_pyramidal_molecular_geometry.
- Sulfite_ester wikiPageWikiLink File:Dimethyl-sulfite-GG-conformer-2D.png.
- Sulfite_ester wikiPageWikiLinkText "sulfite ester".
- Sulfite_ester hasPhotoCollection Sulfite_ester.
- Sulfite_ester wikiPageUsesTemplate Template:Functional_Groups.
- Sulfite_ester subject Category:Esters.
- Sulfite_ester subject Category:Functional_groups.
- Sulfite_ester subject Category:Organic_compounds.
- Sulfite_ester hypernym Group.
- Sulfite_ester type Band.
- Sulfite_ester type Group.
- Sulfite_ester type Ester.
- Sulfite_ester type Group.
- Sulfite_ester comment "A sulfite ester is a functional group with the structure (RO)(R'O)SO. They adopt a trigonal pyramidal molecular geometry due to the presence of lone pairs on the sulphur atom. When substituents R and R' differ, the compound is chiral owing to the stereogenic sulphur centre; when the R groups are the same the compound will have idealised Cs molecular symmetry. They are commonly prepared by the reaction of thionyl chloride with alcohols.".
- Sulfite_ester label "Sulfite ester".
- Sulfite_ester sameAs Ester_de_sulfite.
- Sulfite_ester sameAs m.0gjd30r.
- Sulfite_ester sameAs Q3058925.
- Sulfite_ester sameAs Q3058925.
- Sulfite_ester wasDerivedFrom Sulfite_ester?oldid=619532925.
- Sulfite_ester depiction Dimethyl-sulfite-GG-conformer-2D.png.
- Sulfite_ester isPrimaryTopicOf Sulfite_ester.