Matches in DBpedia 2015-10 for { <http://dbpedia.org/resource/Rosenmund_reduction> ?p ?o }
Showing triples 1 to 61 of
61
with 100 triples per page.
- Rosenmund_reduction abstract "The Rosenmund reduction is a hydrogenation process in which an acyl chloride is selectively reduced to an aldehyde. The reaction was named after Karl Wilhelm Rosenmund who first reported it in 1918.The reaction is catalysed by palladium on barium sulfate, which is sometimes called the Rosenmund catalyst. Barium sulfate has a low surface area which reduces the activity of the palladium, preventing over-reduction. However for certain reactive acyl chlorides the activity must be reduced further, by the addition of a poison. Originally this was thioquinanthrene although thiourea has also been used. Deactivation is required because the system must reduce the acyl chloride but not the subsequent aldehyde. If further reduction does take place it will create a primary alcohol which would then react with the remaining acyl chloride to form an ester.".
- Rosenmund_reduction thumbnail Rosenmund_Reduction_Scheme.png?width=300.
- Rosenmund_reduction wikiPageID "3252738".
- Rosenmund_reduction wikiPageLength "3565".
- Rosenmund_reduction wikiPageOutDegree "19".
- Rosenmund_reduction wikiPageRevisionID "673524223".
- Rosenmund_reduction wikiPageWikiLink Acyl_chloride.
- Rosenmund_reduction wikiPageWikiLink Aldehyde.
- Rosenmund_reduction wikiPageWikiLink Barium_sulfate.
- Rosenmund_reduction wikiPageWikiLink Catalyst_poisoning.
- Rosenmund_reduction wikiPageWikiLink Category:Name_reactions.
- Rosenmund_reduction wikiPageWikiLink Category:Organic_redox_reactions.
- Rosenmund_reduction wikiPageWikiLink Diisobutylaluminium_hydride.
- Rosenmund_reduction wikiPageWikiLink Ester.
- Rosenmund_reduction wikiPageWikiLink Gattermann_reaction.
- Rosenmund_reduction wikiPageWikiLink Gattermann–Koch_reaction.
- Rosenmund_reduction wikiPageWikiLink Grundmann_aldehyde_synthesis.
- Rosenmund_reduction wikiPageWikiLink Hydrogenation.
- Rosenmund_reduction wikiPageWikiLink Karl_Wilhelm_Rosenmund.
- Rosenmund_reduction wikiPageWikiLink Lindlar_catalyst.
- Rosenmund_reduction wikiPageWikiLink Palladium.
- Rosenmund_reduction wikiPageWikiLink Redox.
- Rosenmund_reduction wikiPageWikiLink Rosenmund–von_Braun_reaction.
- Rosenmund_reduction wikiPageWikiLink Thioquinanthrene.
- Rosenmund_reduction wikiPageWikiLink Thiourea.
- Rosenmund_reduction wikiPageWikiLink File:Rosenmund_Reduction_Scheme.png.
- Rosenmund_reduction wikiPageWikiLinkText "Rosenmund reduction".
- Rosenmund_reduction author "A. I. Rachlin, H. Gurien, and D. P. Wagner".
- Rosenmund_reduction collvol "6".
- Rosenmund_reduction collvolpages "1007".
- Rosenmund_reduction hasPhotoCollection Rosenmund_reduction.
- Rosenmund_reduction prep "cv6p1007".
- Rosenmund_reduction title "Aldehydes from Acid Chlorides by modified Rosenmund Reduction: 3,4,5-Trimethoxybenzaldehyde".
- Rosenmund_reduction wikiPageUsesTemplate Template:Cite_journal.
- Rosenmund_reduction wikiPageUsesTemplate Template:OrgSynth.
- Rosenmund_reduction year "1988".
- Rosenmund_reduction subject Category:Name_reactions.
- Rosenmund_reduction subject Category:Organic_redox_reactions.
- Rosenmund_reduction hypernym Process.
- Rosenmund_reduction type Election.
- Rosenmund_reduction type Eponym.
- Rosenmund_reduction type Reaction.
- Rosenmund_reduction comment "The Rosenmund reduction is a hydrogenation process in which an acyl chloride is selectively reduced to an aldehyde. The reaction was named after Karl Wilhelm Rosenmund who first reported it in 1918.The reaction is catalysed by palladium on barium sulfate, which is sometimes called the Rosenmund catalyst. Barium sulfate has a low surface area which reduces the activity of the palladium, preventing over-reduction.".
- Rosenmund_reduction label "Rosenmund reduction".
- Rosenmund_reduction sameAs اختزال_روزينموند.
- Rosenmund_reduction sameAs Reacció_de_Rosenmund.
- Rosenmund_reduction sameAs Rosenmund-Reduktion.
- Rosenmund_reduction sameAs واکنش_رزنموند.
- Rosenmund_reduction sameAs Réduction_de_Rosenmund.
- Rosenmund_reduction sameAs Rosenmund-redukció.
- Rosenmund_reduction sameAs ローゼンムント還元.
- Rosenmund_reduction sameAs Rosenmund-reductie.
- Rosenmund_reduction sameAs m.091cwp.
- Rosenmund_reduction sameAs Реакция_Розенмунда.
- Rosenmund_reduction sameAs ரோசன்மண்ட்_குறைத்தல்_விளைவு.
- Rosenmund_reduction sameAs Q905524.
- Rosenmund_reduction sameAs Q905524.
- Rosenmund_reduction sameAs 罗森蒙德还原反应.
- Rosenmund_reduction wasDerivedFrom Rosenmund_reduction?oldid=673524223.
- Rosenmund_reduction depiction Rosenmund_Reduction_Scheme.png.
- Rosenmund_reduction isPrimaryTopicOf Rosenmund_reduction.