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- Free-energy_relationship abstract "In physical organic chemistry, a free-energy relationship or Gibbs energy relation relates the logarithm of a reaction rate constant or equilibrium constant for one series of reactions with the logarithm of the rate or equilibrium constant for a related series of reactions. Establishing free-energy relationships helps in the understanding of the reaction mechanism for a chemical reaction and allows the prediction of reaction rates and equilibrium constants.The most common form of free-energy relationships are Linear Free-Energy Relationships (LFER). The Brønsted catalysis equation describes the relationship between the ionization constant of a series of catalysts and the reaction rate constant for a reaction on which the catalyst operates. The Hammett equation predicts the equilibrium constant or reaction rate of a reaction from a substituent constant and a reaction type constant. The Edwards equation relates the nucleophilic power to polarisability and basicity. The Marcus equation is an example of a Quadratic Free-Energy Relationship (QFER).IUPAC has suggested that this name should be replaced by linear Gibbs energy relation, but at present there is little sign of acceptance of this change.The area of physical organic chemistry which deals with such relations is commonly referred to as 'Linear Free-Energy Relationships'.".
- Free-energy_relationship wikiPageExternalLink goldbook.iupac.org.
- Free-energy_relationship wikiPageExternalLink L03551.html.
- Free-energy_relationship wikiPageID "2057973".
- Free-energy_relationship wikiPageLength "5227".
- Free-energy_relationship wikiPageOutDegree "42".
- Free-energy_relationship wikiPageRevisionID "678330049".
- Free-energy_relationship wikiPageWikiLink Acid.
- Free-energy_relationship wikiPageWikiLink Acid_dissociation_constant.
- Free-energy_relationship wikiPageWikiLink Acidity.
- Free-energy_relationship wikiPageWikiLink Adsorption.
- Free-energy_relationship wikiPageWikiLink Aerosol.
- Free-energy_relationship wikiPageWikiLink Base_(chemistry).
- Free-energy_relationship wikiPageWikiLink Basicity.
- Free-energy_relationship wikiPageWikiLink Bell–Evans–Polanyi_principle.
- Free-energy_relationship wikiPageWikiLink Brønsted_catalysis_equation.
- Free-energy_relationship wikiPageWikiLink Catalysis.
- Free-energy_relationship wikiPageWikiLink Catalyst.
- Free-energy_relationship wikiPageWikiLink Category:Physical_organic_chemistry.
- Free-energy_relationship wikiPageWikiLink Category:Solutions.
- Free-energy_relationship wikiPageWikiLink Chemical_reaction.
- Free-energy_relationship wikiPageWikiLink Dipole.
- Free-energy_relationship wikiPageWikiLink Edwards_equation.
- Free-energy_relationship wikiPageWikiLink Equilibrium_constant.
- Free-energy_relationship wikiPageWikiLink Gibbs_free_energy.
- Free-energy_relationship wikiPageWikiLink Grunwald-Winstein_equation.
- Free-energy_relationship wikiPageWikiLink Grunwald–Winstein_equation.
- Free-energy_relationship wikiPageWikiLink Hammett_equation.
- Free-energy_relationship wikiPageWikiLink Hexadecane.
- Free-energy_relationship wikiPageWikiLink Hydrogen_bond.
- Free-energy_relationship wikiPageWikiLink Ionization_constant.
- Free-energy_relationship wikiPageWikiLink Letter_case.
- Free-energy_relationship wikiPageWikiLink Logarithm.
- Free-energy_relationship wikiPageWikiLink Lone_pair.
- Free-energy_relationship wikiPageWikiLink Lower_case.
- Free-energy_relationship wikiPageWikiLink Marcus_equation.
- Free-energy_relationship wikiPageWikiLink Marcus_theory.
- Free-energy_relationship wikiPageWikiLink McGowans_characteristic_molecular_volume.
- Free-energy_relationship wikiPageWikiLink Michael_Abraham_(chemist).
- Free-energy_relationship wikiPageWikiLink Molar_refractivity.
- Free-energy_relationship wikiPageWikiLink N-hexadecane.
- Free-energy_relationship wikiPageWikiLink Physical_organic_chemistry.
- Free-energy_relationship wikiPageWikiLink Pi_bond.
- Free-energy_relationship wikiPageWikiLink Pi_electron.
- Free-energy_relationship wikiPageWikiLink Quantitative_structure-activity_relationship.
- Free-energy_relationship wikiPageWikiLink Quantitative_structure–activity_relationship.
- Free-energy_relationship wikiPageWikiLink Reaction_mechanism.
- Free-energy_relationship wikiPageWikiLink Reaction_rate_constant.
- Free-energy_relationship wikiPageWikiLink Solution.
- Free-energy_relationship wikiPageWikiLink Sorbent.
- Free-energy_relationship wikiPageWikiLink Sorption.
- Free-energy_relationship wikiPageWikiLink Swain-Lupton_equation.
- Free-energy_relationship wikiPageWikiLink Swain–Lupton_equation.
- Free-energy_relationship wikiPageWikiLink Taft_equation.
- Free-energy_relationship wikiPageWikiLink Yukawa-Tsuno_equation.
- Free-energy_relationship wikiPageWikiLink Yukawa–Tsuno_equation.
- Free-energy_relationship wikiPageWikiLinkText "Free-energy relationship ".
- Free-energy_relationship wikiPageWikiLinkText "Free-energy relationship".
- Free-energy_relationship wikiPageWikiLinkText "Linear free energy relationships".
- Free-energy_relationship wikiPageWikiLinkText "free-energy relationship".
- Free-energy_relationship wikiPageWikiLinkText "linear energy relationship".
- Free-energy_relationship wikiPageWikiLinkText "linear free energy relationship".
- Free-energy_relationship wikiPageWikiLinkText "linear free energy relationships".
- Free-energy_relationship hasPhotoCollection Free-energy_relationship.
- Free-energy_relationship wikiPageUsesTemplate Template:Doi.
- Free-energy_relationship wikiPageUsesTemplate Template:Main.
- Free-energy_relationship subject Category:Physical_organic_chemistry.
- Free-energy_relationship subject Category:Solutions.
- Free-energy_relationship type Article.
- Free-energy_relationship type Article.
- Free-energy_relationship comment "In physical organic chemistry, a free-energy relationship or Gibbs energy relation relates the logarithm of a reaction rate constant or equilibrium constant for one series of reactions with the logarithm of the rate or equilibrium constant for a related series of reactions.".
- Free-energy_relationship label "Free-energy relationship".
- Free-energy_relationship sameAs علاقة_خطية_للطاقة_الحرة.
- Free-energy_relationship sameAs Correlação_linear_de_energia_livre.
- Free-energy_relationship sameAs m.06j40d.
- Free-energy_relationship sameAs Q4119007.
- Free-energy_relationship sameAs Q4119007.
- Free-energy_relationship wasDerivedFrom Free-energy_relationship?oldid=678330049.
- Free-energy_relationship isPrimaryTopicOf Free-energy_relationship.