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- Explosophore abstract "Explosophores are functional groups in organic chemistry that give organic compounds explosive properties. The term was first coined by Russian chemist V. Pletz in 1935. and originally mistranslated in some articles as "plosophore". Also of note is an auxoexplose concept(similar to chromophore and auxochrome concept), which is a group that modifies the explosive capability of the molecule. Pletz grouped the explosophores into eight distinct categories. It has been suggested that the current list is insufficient and that several other new categories should be added. I. –NO2, –ON=O and –ONO2 The nitro (in which the nitrogen bonds to the organic molecule), nitrite (in which oxygen is bonded to the organic molecule), and nitrate ester (in which nitrogen is between one oxygen bonded to the organic molecule and the other two oxygen atoms) groups respectively connected to organic molecules (by far the most commercially used explosives are nitrate/nitrite based). (Another functional group that is frequently considered as an explosophore is picrate, the salts or ethers of picric acid (2,4,6-trinitrophenol), which gains its explosive capability from the nitrate groups attached to it.) These nitro-containing groups are particularly strong explosophores because of the fact that in addition to providing oxygen they react to form molecular nitrogen, which is a very stable molecule, so the overall reaction is strongly exothermic (the gas formed also expands, causing the shock wave which is observed). The considerations apply to II and III below, which are also nitrogen-containing. II. –N=N– and –N−=N+=N−– The azo and azide groups respectively, connected to organic/inorganic compounds (e.g. AgN3, Pb(N3)2, NH4N3) III. –RnNXm The Halogenated nitrogen group X:halogen (for example NI3 and RNCl3) IV. –C=N–O– The fulminate group (example HONC and Hg(ONC)2) V. –OClO3 and –OClO4 The chlorate and perchlorate groups respectively, connected to organics/inorganics (e.g. KClO3, FOClO3) VI. –O–O– and –O3– The peroxide and ozonide groups respectively, connected to organics/inorganics (e.g. acetone peroxide, butanone peroxide) VII. –C≡C− M+ The acetylide group with its metal derivatives VIII. A metal atom connected by an unstable bond to the carbon of certain organic radicals (for example, organic compounds of mercury, thallium, and lead).The term explosophore has been used more frequently after its use in books such as Organic Chemistry of Explosives by J. Agrawal and R. Hodgson (2007).".
- Explosophore wikiPageID "21727035".
- Explosophore wikiPageLength "3509".
- Explosophore wikiPageOutDegree "35".
- Explosophore wikiPageRevisionID "634997748".
- Explosophore wikiPageWikiLink Acetone_peroxide.
- Explosophore wikiPageWikiLink Acetylide.
- Explosophore wikiPageWikiLink Ammonium_azide.
- Explosophore wikiPageWikiLink Auxochrome.
- Explosophore wikiPageWikiLink Azide.
- Explosophore wikiPageWikiLink Azo_compound.
- Explosophore wikiPageWikiLink Category:Explosives.
- Explosophore wikiPageWikiLink Category:Organic_compounds.
- Explosophore wikiPageWikiLink Chlorate.
- Explosophore wikiPageWikiLink Chromophore.
- Explosophore wikiPageWikiLink Ether.
- Explosophore wikiPageWikiLink Explosive.
- Explosophore wikiPageWikiLink Explosive_material.
- Explosophore wikiPageWikiLink Fluorine_perchlorate.
- Explosophore wikiPageWikiLink Fulminate.
- Explosophore wikiPageWikiLink Fulminic_acid.
- Explosophore wikiPageWikiLink Functional_group.
- Explosophore wikiPageWikiLink Lead.
- Explosophore wikiPageWikiLink Lead(II)_azide.
- Explosophore wikiPageWikiLink Lead_azide.
- Explosophore wikiPageWikiLink Mercury(II)_fulminate.
- Explosophore wikiPageWikiLink Mercury_(element).
- Explosophore wikiPageWikiLink Mercury_fulminate.
- Explosophore wikiPageWikiLink Methyl_ethyl_ketone_peroxide.
- Explosophore wikiPageWikiLink Nitrite.
- Explosophore wikiPageWikiLink Nitro_compound.
- Explosophore wikiPageWikiLink Nitrogen_trichloride.
- Explosophore wikiPageWikiLink Nitrogen_triiodide.
- Explosophore wikiPageWikiLink Organic_chemistry.
- Explosophore wikiPageWikiLink Ozonide.
- Explosophore wikiPageWikiLink Perchlorate.
- Explosophore wikiPageWikiLink Peroxide.
- Explosophore wikiPageWikiLink Picrate.
- Explosophore wikiPageWikiLink Picric_acid.
- Explosophore wikiPageWikiLink Potassium_chlorate.
- Explosophore wikiPageWikiLink Silver_azide.
- Explosophore wikiPageWikiLink Thallium.
- Explosophore wikiPageWikiLink V._Pletz.
- Explosophore wikiPageWikiLinkText "Explosophore".
- Explosophore wikiPageWikiLinkText "explosophore".
- Explosophore hasPhotoCollection Explosophore.
- Explosophore wikiPageUsesTemplate Template:Citation_needed.
- Explosophore wikiPageUsesTemplate Template:Reflist.
- Explosophore subject Category:Explosives.
- Explosophore subject Category:Organic_compounds.
- Explosophore hypernym Groups.
- Explosophore type Event.
- Explosophore type Source.
- Explosophore comment "Explosophores are functional groups in organic chemistry that give organic compounds explosive properties. The term was first coined by Russian chemist V. Pletz in 1935. and originally mistranslated in some articles as "plosophore". Also of note is an auxoexplose concept(similar to chromophore and auxochrome concept), which is a group that modifies the explosive capability of the molecule. Pletz grouped the explosophores into eight distinct categories.".
- Explosophore label "Explosophore".
- Explosophore sameAs Explosóforo.
- Explosophore sameAs m.05mrv0p.
- Explosophore sameAs Q5421455.
- Explosophore sameAs Q5421455.
- Explosophore wasDerivedFrom Explosophore?oldid=634997748.
- Explosophore isPrimaryTopicOf Explosophore.