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- Epoxidation_with_dioxiranes abstract "Epoxidation with dioxiranes refers to the synthesis of epoxides from alkenes using three-membered cyclic peroxides, also known as dioxiranes.Dioxiranes are three-membered cyclic peroxides containing a weak oxygen-oxygen bond. Although they are able to effect oxidations of heteroatom functionality and even carbon-hydrogen bonds, they are most widely used as epoxidizing agents of alkenes. Dioxiranes are electrophilic oxidants that react more quickly with electron-rich than electron-poor double bonds; however, both classes of substrates can be epoxidized within a reasonable time frame. Dioxiranes may be prepared and isolated or generated in situ from ketones and potassium peroxymonosulfate (Oxone). In situ preparations may be catalytic in ketone, and if the ketone is chiral, enantioselective epoxidation takes place. The functional group compatibility of dioxiranes is limited somewhat, as side oxidations of amines and sulfides are rapid. Nonetheless, protocols for dioxirane oxidations are entirely metal free. The most common dioxiranes employed for synthesis are dimethyl dioxirane (DMD) and methyl(trifluoromethyl)dioxirane (TFD).(1)File:DOEpoxGen.png".
- Epoxidation_with_dioxiranes thumbnail DOEpoxGen.png?width=300.
- Epoxidation_with_dioxiranes wikiPageID "27673072".
- Epoxidation_with_dioxiranes wikiPageLength "11398".
- Epoxidation_with_dioxiranes wikiPageOutDegree "24".
- Epoxidation_with_dioxiranes wikiPageRevisionID "598198232".
- Epoxidation_with_dioxiranes wikiPageWikiLink Acetonitrile.
- Epoxidation_with_dioxiranes wikiPageWikiLink Air-free_technique.
- Epoxidation_with_dioxiranes wikiPageWikiLink Alkene.
- Epoxidation_with_dioxiranes wikiPageWikiLink Baeyer-Villiger_oxidation.
- Epoxidation_with_dioxiranes wikiPageWikiLink Baeyer–Villiger_oxidation.
- Epoxidation_with_dioxiranes wikiPageWikiLink Category:Organic_reactions.
- Epoxidation_with_dioxiranes wikiPageWikiLink Dioxirane.
- Epoxidation_with_dioxiranes wikiPageWikiLink Epoxide.
- Epoxidation_with_dioxiranes wikiPageWikiLink Metal_salen_complexes.
- Epoxidation_with_dioxiranes wikiPageWikiLink Oxaziridine.
- Epoxidation_with_dioxiranes wikiPageWikiLink Oxone.
- Epoxidation_with_dioxiranes wikiPageWikiLink Potassium_peroxymonosulfate.
- Epoxidation_with_dioxiranes wikiPageWikiLink Salen_complexes.
- Epoxidation_with_dioxiranes wikiPageWikiLink Spiro_compound.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxGen.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxMech.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxScope1.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxScope2.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxScope3.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxScope4.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxScope5.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxStereo1.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxStereo2.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxStereo4.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxStereoSeq.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DOEpoxSynth.png.
- Epoxidation_with_dioxiranes wikiPageWikiLink File:DioxEpoxStereoEx.png.
- Epoxidation_with_dioxiranes wikiPageWikiLinkText "oxidation of alkenes to epoxide".
- Epoxidation_with_dioxiranes hasPhotoCollection Epoxidation_with_dioxiranes.
- Epoxidation_with_dioxiranes wikiPageUsesTemplate Template:Reflist.
- Epoxidation_with_dioxiranes subject Category:Organic_reactions.
- Epoxidation_with_dioxiranes hypernym Peroxides.
- Epoxidation_with_dioxiranes type ChemicalCompound.
- Epoxidation_with_dioxiranes type Reaction.
- Epoxidation_with_dioxiranes comment "Epoxidation with dioxiranes refers to the synthesis of epoxides from alkenes using three-membered cyclic peroxides, also known as dioxiranes.Dioxiranes are three-membered cyclic peroxides containing a weak oxygen-oxygen bond. Although they are able to effect oxidations of heteroatom functionality and even carbon-hydrogen bonds, they are most widely used as epoxidizing agents of alkenes.".
- Epoxidation_with_dioxiranes label "Epoxidation with dioxiranes".
- Epoxidation_with_dioxiranes sameAs m.0dlmynl.
- Epoxidation_with_dioxiranes sameAs Q5383822.
- Epoxidation_with_dioxiranes sameAs Q5383822.
- Epoxidation_with_dioxiranes wasDerivedFrom Epoxidation_with_dioxiranes?oldid=598198232.
- Epoxidation_with_dioxiranes depiction DOEpoxGen.png.
- Epoxidation_with_dioxiranes isPrimaryTopicOf Epoxidation_with_dioxiranes.