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- Deep_eutectic_solvent abstract "A deep eutectic solvent or DES is a type of ionic solvent with special properties composed of a mixture which forms a eutectic with a melting point much lower than either of the individual components. One of the most significant deep eutectic phenomenon was observed for a mixture of choline chloride and urea in a 1:2 mole ratio, respectively. The resulting mixture has a melting point of 12 °C (far less than the melting point of choline, 302 °C and urea, 133 °C), which makes it liquid at room temperature. The first generation eutectic solvents were based on mixtures of quaternary ammonium salts with hydrogen bond donors such as amines and carboxylic acids. There are four types of eutectic solvents:Type I Eutectics therefore also include the wide range of chlorometallate ionic liquids widely studied in the 1980s, such as the ever-popular imidazolium chloroaluminates which are based on mixtures of AlCl3 + 1-Ethyl-3-methylimidazolium chloride.In addition to ionic liquids with discrete anions, the electrodeposition of a range of metals has been previously carried out in deep eutectic solvents (DESs). These are quaternary ammonium salts (e.g. choline chloride, ChCl), metal salts or metal salt hydrates and hydrogen bond donors (e.g. urea) and are commonly divided into four groups (Table 1), and have been particularly successful on a large scale for metal polishing and immersion silver deposition. While most ionic liquids and DESs include a quaternary ammonium ion as the cationic component, it has recently been shown that eutectics can also be formed between a metal salt (hydrate) and a simple amide or alcohol to form a metalcontaining solution composed of cations and anions via disproportionation processes e.g.2AlCl3 + urea ↔ [AlCl2•urea]+ + [AlCl4]−These so-called Type 4 eutectics are useful as they produce cationic metal complexes, ensuring that the double layer close to the electrode surface has a high metal ion concentration.".
- Deep_eutectic_solvent wikiPageID "2777190".
- Deep_eutectic_solvent wikiPageLength "9943".
- Deep_eutectic_solvent wikiPageOutDegree "35".
- Deep_eutectic_solvent wikiPageRevisionID "662799839".
- Deep_eutectic_solvent wikiPageWikiLink Amine.
- Deep_eutectic_solvent wikiPageWikiLink Benzoic_acid.
- Deep_eutectic_solvent wikiPageWikiLink Biodegradation.
- Deep_eutectic_solvent wikiPageWikiLink Bistriflimide.
- Deep_eutectic_solvent wikiPageWikiLink Carboxylic_acid.
- Deep_eutectic_solvent wikiPageWikiLink Category:Solvents.
- Deep_eutectic_solvent wikiPageWikiLink Cellulose.
- Deep_eutectic_solvent wikiPageWikiLink Choline_chloride.
- Deep_eutectic_solvent wikiPageWikiLink Conductive.
- Deep_eutectic_solvent wikiPageWikiLink Copper(II)_oxide.
- Deep_eutectic_solvent wikiPageWikiLink Electrical_conductor.
- Deep_eutectic_solvent wikiPageWikiLink Electroplating.
- Deep_eutectic_solvent wikiPageWikiLink Electropolishing.
- Deep_eutectic_solvent wikiPageWikiLink Eutectic.
- Deep_eutectic_solvent wikiPageWikiLink Eutectic_system.
- Deep_eutectic_solvent wikiPageWikiLink Glycerol.
- Deep_eutectic_solvent wikiPageWikiLink Hydrogen_bond.
- Deep_eutectic_solvent wikiPageWikiLink Ion.
- Deep_eutectic_solvent wikiPageWikiLink Ionic_liquid.
- Deep_eutectic_solvent wikiPageWikiLink J._Am._Chem._Soc..
- Deep_eutectic_solvent wikiPageWikiLink J._Chem._&_Eng._Data.
- Deep_eutectic_solvent wikiPageWikiLink Journal_of_the_American_Chemical_Society.
- Deep_eutectic_solvent wikiPageWikiLink Lithium_chloride.
- Deep_eutectic_solvent wikiPageWikiLink Malonic_acid.
- Deep_eutectic_solvent wikiPageWikiLink Melting_point.
- Deep_eutectic_solvent wikiPageWikiLink Metal.
- Deep_eutectic_solvent wikiPageWikiLink Mole_(chemistry).
- Deep_eutectic_solvent wikiPageWikiLink Mole_(unit).
- Deep_eutectic_solvent wikiPageWikiLink Organic_compound.
- Deep_eutectic_solvent wikiPageWikiLink Phenol.
- Deep_eutectic_solvent wikiPageWikiLink Quaternary_ammonium.
- Deep_eutectic_solvent wikiPageWikiLink Quaternary_ammonium_cation.
- Deep_eutectic_solvent wikiPageWikiLink Salt.
- Deep_eutectic_solvent wikiPageWikiLink Salt_(chemistry).
- Deep_eutectic_solvent wikiPageWikiLink Salts.
- Deep_eutectic_solvent wikiPageWikiLink Solubility.
- Deep_eutectic_solvent wikiPageWikiLink Solvent.
- Deep_eutectic_solvent wikiPageWikiLink Toxic.
- Deep_eutectic_solvent wikiPageWikiLink Toxicity.
- Deep_eutectic_solvent wikiPageWikiLink Urea.
- Deep_eutectic_solvent wikiPageWikiLink Volatile_organic_compound.
- Deep_eutectic_solvent wikiPageWikiLinkText "Deep eutectic solvent".
- Deep_eutectic_solvent wikiPageWikiLinkText "deep eutectic solvent".
- Deep_eutectic_solvent hasPhotoCollection Deep_eutectic_solvent.
- Deep_eutectic_solvent wikiPageUsesTemplate Template:Cite_journal.
- Deep_eutectic_solvent subject Category:Solvents.
- Deep_eutectic_solvent hypernym Type.
- Deep_eutectic_solvent comment "A deep eutectic solvent or DES is a type of ionic solvent with special properties composed of a mixture which forms a eutectic with a melting point much lower than either of the individual components. One of the most significant deep eutectic phenomenon was observed for a mixture of choline chloride and urea in a 1:2 mole ratio, respectively.".
- Deep_eutectic_solvent label "Deep eutectic solvent".
- Deep_eutectic_solvent sameAs Stark_eutektisches_Lösungsmittel.
- Deep_eutectic_solvent sameAs m.0822kd.
- Deep_eutectic_solvent sameAs Q168033.
- Deep_eutectic_solvent sameAs Q168033.
- Deep_eutectic_solvent wasDerivedFrom Deep_eutectic_solvent?oldid=662799839.
- Deep_eutectic_solvent isPrimaryTopicOf Deep_eutectic_solvent.