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- Aryne abstract "Arynes or benzynes are highly reactive species derived from an aromatic ring by removal of two ortho substituents. Arynes are usually best described as having a strained triple bond; however, they possess some biradical character as well. The term aryne is most closely associated with ortho-aryne, however para- and meta-aryne intermediates have been described.Benzyne was first postulated by Georg Wittig in 1940 and experimentally confirmed by John D. Roberts in 1953.The discovery of benzyne led to rapid developments in synthetic methodologies to make this highly reactive intermediate useful for organic synthesis. To date, a variety of natural products have been prepared using arynes as intermediates. Examples of such natural products are Cryptaustoline, (+)-Liphagal, Dehydroaltenuene B, Herbindole A, Taxodione, Melleine and many others. Perhaps one of the most famous reactions of arynes is Bergman cyclization, which lies in the core of mechanism of action of enediyne cytostatics.".
- Aryne thumbnail Roberts_1953.png?width=300.
- Aryne wikiPageID "1545126".
- Aryne wikiPageLength "20731".
- Aryne wikiPageOutDegree "49".
- Aryne wikiPageRevisionID "679478457".
- Aryne wikiPageWikiLink 1,2,3,4-Tetraphenylnaphthalene.
- Aryne wikiPageWikiLink 1,2,3,4-tetraphenylnaphthalene.
- Aryne wikiPageWikiLink Arene_substitution_pattern.
- Aryne wikiPageWikiLink Aromatic_hydrocarbon.
- Aryne wikiPageWikiLink Aromatic_ring.
- Aryne wikiPageWikiLink Category:Reactive_intermediates.
- Aryne wikiPageWikiLink Dehydrohalogenation.
- Aryne wikiPageWikiLink Diels-Alder_reaction.
- Aryne wikiPageWikiLink Diels–Alder_reaction.
- Aryne wikiPageWikiLink Furan.
- Aryne wikiPageWikiLink Georg_Wittig.
- Aryne wikiPageWikiLink Hexadehydro_Diels-Alder_reaction.
- Aryne wikiPageWikiLink In-Methylcyclophane.
- Aryne wikiPageWikiLink In-methylcyclophane.
- Aryne wikiPageWikiLink In_silico.
- Aryne wikiPageWikiLink John_D._Roberts.
- Aryne wikiPageWikiLink N-Butyllithium.
- Aryne wikiPageWikiLink Ortho-.
- Aryne wikiPageWikiLink Phenyl.
- Aryne wikiPageWikiLink Phenyl_group.
- Aryne wikiPageWikiLink Pyridyne.
- Aryne wikiPageWikiLink Pyrolysis.
- Aryne wikiPageWikiLink Substituent.
- Aryne wikiPageWikiLink Transition_metal_benzyne_complex.
- Aryne wikiPageWikiLink Tricyclobutabenzene.
- Aryne wikiPageWikiLink File:4+2_cycloaddition.tif.
- Aryne wikiPageWikiLink File:Barrette_synthesis.tif.
- Aryne wikiPageWikiLink File:Benzyne_gen1.tif.
- Aryne wikiPageWikiLink File:Benzyne_gen2.tif.
- Aryne wikiPageWikiLink File:Benzyne_gen3.tif.
- Aryne wikiPageWikiLink File:Benzyne_intermediate.tif.
- Aryne wikiPageWikiLink File:Benzyne_o,p,m1.tif.
- Aryne wikiPageWikiLink File:Bergman.tif.
- Aryne wikiPageWikiLink File:Buszek.tif.
- Aryne wikiPageWikiLink File:Cross-coupling_of_arynes.tif.
- Aryne wikiPageWikiLink File:Diaryne_reaction.svg.
- Aryne wikiPageWikiLink File:Geometric_constraint2.tif.
- Aryne wikiPageWikiLink File:Guyot.tif.
- Aryne wikiPageWikiLink File:HDDA_rxn.tif.
- Aryne wikiPageWikiLink File:Homo-lumo_gap.tif.
- Aryne wikiPageWikiLink File:Interconversion.tif.
- Aryne wikiPageWikiLink File:Kametani1.tif.
- Aryne wikiPageWikiLink File:Mori.tif.
- Aryne wikiPageWikiLink File:Nuc_addn_to_benzyne.tif.
- Aryne wikiPageWikiLink File:Regiochemistry2.png.
- Aryne wikiPageWikiLink File:Resonance_contributors1.tif.
- Aryne wikiPageWikiLink File:Roberts_1953.png.
- Aryne wikiPageWikiLink File:Stevens.tif.
- Aryne wikiPageWikiLink File:Stoermer_-_benzyne.tif.
- Aryne wikiPageWikiLink File:Stoltz_Liphagal.tif.
- Aryne wikiPageWikiLink File:Triple_bond_generation1.png.
- Aryne wikiPageWikiLink File:Wittig.tif.
- Aryne wikiPageWikiLink File:Wittig_1955.png.
- Aryne wikiPageWikiLinkText "Aryne".
- Aryne wikiPageWikiLinkText "aryne".
- Aryne wikiPageWikiLinkText "benzyne".
- Aryne wikiPageWikiLinkText "para-benzyne".
- Aryne hasPhotoCollection Aryne.
- Aryne wikiPageUsesTemplate Template:Authority_control.
- Aryne wikiPageUsesTemplate Template:Reflist.
- Aryne subject Category:Reactive_intermediates.
- Aryne type Article.
- Aryne type Article.
- Aryne type Thing.
- Aryne comment "Arynes or benzynes are highly reactive species derived from an aromatic ring by removal of two ortho substituents. Arynes are usually best described as having a strained triple bond; however, they possess some biradical character as well. The term aryne is most closely associated with ortho-aryne, however para- and meta-aryne intermediates have been described.Benzyne was first postulated by Georg Wittig in 1940 and experimentally confirmed by John D.".
- Aryne label "Aryne".
- Aryne sameAs Arine.
- Aryne sameAs Aryne.
- Aryne sameAs ベンザイン.
- Aryne sameAs Aryn.
- Aryne sameAs Arina.
- Aryne sameAs m.0596ng.
- Aryne sameAs Арини.
- Aryne sameAs Q416633.
- Aryne sameAs Q416633.
- Aryne sameAs 苯炔.
- Aryne wasDerivedFrom Aryne?oldid=679478457.
- Aryne depiction Roberts_1953.png.
- Aryne isPrimaryTopicOf Aryne.