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- Q902347 subject Q7400650.
- Q902347 subject Q7458901.
- Q902347 abstract "A Wagner–Meerwein rearrangement is a class of carbocation 1,2-rearrangement reactions in which a hydrogen, alkyl or aryl group migrates from one carbon to a neighboring carbon.Several reviews have been published.The rearrangement was first discovered in bicyclic terpenes for example the conversion of isoborneol to camphene:The story of the rearrangement reveals that many scientists were puzzled with this and related reactions and its close relationship to the discovery of carbocations as intermediates.In a simple demonstration reaction of 1,4-dimethoxybenzene with either 2-methyl-2-butanol or 3-methyl-2-butanol in sulfuric acid and acetic acid yields the same disubstituted product, the latter via a hydride shift of the cationic intermediate:Carbocation rearrangement Polito 2010Currently, there are works relating to the use of skeletal rearrangement in the synthesis of bridged azaheterocycles. These data are summarized in 950pxPlausible mechanisms of the Wagner–Meerwein rearrangement of diepoxyisoindoles:1000pxThe related Nametkin rearrangement named after Sergey Namyotkin involves the rearrangement of methyl groups in certain terpenes. In some cases the reaction type is also called a retropinacol rearrangement (see Pinacol rearrangement).".
- Q902347 thumbnail Wagner-Meerwein_Camphen_mechanism.svg?width=300.
- Q902347 wikiPageWikiLink Q137587.
- Q902347 wikiPageWikiLink Q209428.
- Q902347 wikiPageWikiLink Q212270.
- Q902347 wikiPageWikiLink Q212364.
- Q902347 wikiPageWikiLink Q225972.
- Q902347 wikiPageWikiLink Q2533305.
- Q902347 wikiPageWikiLink Q335268.
- Q902347 wikiPageWikiLink Q3821249.
- Q902347 wikiPageWikiLink Q4118.
- Q902347 wikiPageWikiLink Q412435.
- Q902347 wikiPageWikiLink Q416775.
- Q902347 wikiPageWikiLink Q4545697.
- Q902347 wikiPageWikiLink Q4634173.
- Q902347 wikiPageWikiLink Q47512.
- Q902347 wikiPageWikiLink Q556.
- Q902347 wikiPageWikiLink Q718074.
- Q902347 wikiPageWikiLink Q7400650.
- Q902347 wikiPageWikiLink Q7458901.
- Q902347 wikiPageWikiLink Q898367.
- Q902347 wikiPageWikiLink Q902209.
- Q902347 comment "A Wagner–Meerwein rearrangement is a class of carbocation 1,2-rearrangement reactions in which a hydrogen, alkyl or aryl group migrates from one carbon to a neighboring carbon.Several reviews have been published.The rearrangement was first discovered in bicyclic terpenes for example the conversion of isoborneol to camphene:The story of the rearrangement reveals that many scientists were puzzled with this and related reactions and its close relationship to the discovery of carbocations as intermediates.In a simple demonstration reaction of 1,4-dimethoxybenzene with either 2-methyl-2-butanol or 3-methyl-2-butanol in sulfuric acid and acetic acid yields the same disubstituted product, the latter via a hydride shift of the cationic intermediate:Carbocation rearrangement Polito 2010Currently, there are works relating to the use of skeletal rearrangement in the synthesis of bridged azaheterocycles. ".
- Q902347 label "Wagner–Meerwein rearrangement".
- Q902347 depiction Wagner-Meerwein_Camphen_mechanism.svg.