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- Q899853 subject Q10798844.
- Q899853 subject Q6394360.
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- Q899853 subject Q7163675.
- Q899853 subject Q8817204.
- Q899853 subject Q8852107.
- Q899853 abstract "In classical statistical mechanics, the H-theorem, introduced by Ludwig Boltzmann in 1872, describes the tendency to increase in the quantity H (defined below) in a nearly-ideal gas of molecules. As this quantity H was meant to represent the entropy of thermodynamics, the H-theorem was an early demonstration of the power of statistical mechanics as it claimed to derive the second law of thermodynamics—a statement about fundamentally irreversible processes—from reversible microscopic mechanics.The H-theorem is a natural consequence of the kinetic equation derived by Boltzmann that has come to be known as Boltzmann's equation. The H-theorem has led to considerable discussion about its actual implications, with major themes being: What is entropy? In what sense does Boltzmann's quantity H correspond to the thermodynamic entropy? Are the assumptions (especially the assumption of molecular chaos) behind Boltzmann's equation too strong? When are these assumptions violated?↑".
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- Q899853 comment "In classical statistical mechanics, the H-theorem, introduced by Ludwig Boltzmann in 1872, describes the tendency to increase in the quantity H (defined below) in a nearly-ideal gas of molecules.".
- Q899853 label "H-theorem".
- Q899853 depiction Translational_motion.gif.