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- Q7834419 subject Q7158373.
- Q7834419 subject Q8913144.
- Q7834419 abstract "Metal dinitrogen complexes are a coordination compounds that contain the dinitrogen (N2) as a ligand. In the area of coordination chemistry, the atomic and diatomic forms of nitrogen are distinguished, although otherwise "nitrogen" refers to N2.Metal complexes of N2 have been studied since 1965 when the first complex was reported by Allen and Senoff. This complex, [Ru(NH3)5(N2)]2+ was synthesised from hydrazine hydrate and ruthenium trichloride and consists of a 16e− [Ru(NH3)5]2+ centre attached to one end of N2. Interest in such complexes arises because N2 comprises the majority of the atmosphere and because many useful compounds contain nitrogen atoms. Biological nitrogen fixation probably occurs via the binding of N2 to a metal center in the enzyme nitrogenase, followed by a series of steps that involve electron transfer and protonation. The hydrogenation of N2 is only weakly exothermic, hence the industrial hydrogenation of nitrogen via the Haber-Bosch Process employs high pressures and high temperatures.".
- Q7834419 thumbnail RuA5N2.png?width=300.
- Q7834419 wikiPageWikiLink Q133145.
- Q7834419 wikiPageWikiLink Q161453.
- Q7834419 wikiPageWikiLink Q177033.
- Q7834419 wikiPageWikiLink Q193161.
- Q7834419 wikiPageWikiLink Q2025.
- Q7834419 wikiPageWikiLink Q213669.
- Q7834419 wikiPageWikiLink Q238156.
- Q7834419 wikiPageWikiLink Q272467.
- Q7834419 wikiPageWikiLink Q303472.
- Q7834419 wikiPageWikiLink Q410381.
- Q7834419 wikiPageWikiLink Q421607.
- Q7834419 wikiPageWikiLink Q551821.
- Q7834419 wikiPageWikiLink Q58447.
- Q7834419 wikiPageWikiLink Q7158373.
- Q7834419 wikiPageWikiLink Q7164918.
- Q7834419 wikiPageWikiLink Q8913144.
- Q7834419 wikiPageWikiLink Q899488.
- Q7834419 wikiPageWikiLink Q901811.
- Q7834419 wikiPageWikiLink Q902898.
- Q7834419 comment "Metal dinitrogen complexes are a coordination compounds that contain the dinitrogen (N2) as a ligand. In the area of coordination chemistry, the atomic and diatomic forms of nitrogen are distinguished, although otherwise "nitrogen" refers to N2.Metal complexes of N2 have been studied since 1965 when the first complex was reported by Allen and Senoff.".
- Q7834419 label "Transition metal dinitrogen complex".
- Q7834419 depiction RuA5N2.png.