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- Q6725521 subject Q7311092.
- Q6725521 subject Q8297717.
- Q6725521 subject Q8376113.
- Q6725521 subject Q8965786.
- Q6725521 abstract "Macrophomic acid is a fungal metabolite isolated from the fungus Macrophoma commelinae. The enzyme macrophomate synthase converts 5-acetyl-4-methoxy-6-methyl-2-pyrone to 4-acetyl-3-methoxy-5-methyl-benzoic acid (macrophomic acid) through an unusual intermolecular Diels-Alder reaction (Scheme 1). The pathway to formation of macrophomic acid suggests that the enzyme is a natural Diels-Alderase. Formation of this type of aromatic ring compound normally proceeds via the shikimate and polyketide pathways; however, the production of macrophomic acid by macrophomate synthase proceeds totally differently. Learning about the production of macrophomic acid by a possible natural Diels-Alderase enzyme is important in understanding enzyme catalytic mechanisms. This knowledge can then be applied to organic synthesis.File:Scheme 1 macrophomic acid.gif".
- Q6725521 iupacName "4-acetyl-3-methoxy-5-methylbenzoic acid".
- Q6725521 thumbnail Macrophomic_acid.svg?width=300.
- Q6725521 wikiPageWikiLink Q1027170.
- Q6725521 wikiPageWikiLink Q210390.
- Q6725521 wikiPageWikiLink Q375669.
- Q6725521 wikiPageWikiLink Q407595.
- Q6725521 wikiPageWikiLink Q408053.
- Q6725521 wikiPageWikiLink Q410830.
- Q6725521 wikiPageWikiLink Q423026.
- Q6725521 wikiPageWikiLink Q516751.
- Q6725521 wikiPageWikiLink Q642233.
- Q6725521 wikiPageWikiLink Q7311092.
- Q6725521 wikiPageWikiLink Q764.
- Q6725521 wikiPageWikiLink Q8047.
- Q6725521 wikiPageWikiLink Q8297717.
- Q6725521 wikiPageWikiLink Q8376113.
- Q6725521 wikiPageWikiLink Q8965786.
- Q6725521 iupacname "4".
- Q6725521 type ChemicalCompound.
- Q6725521 type ChemicalSubstance.
- Q6725521 type ChemicalObject.
- Q6725521 type Thing.
- Q6725521 type Q11173.
- Q6725521 comment "Macrophomic acid is a fungal metabolite isolated from the fungus Macrophoma commelinae. The enzyme macrophomate synthase converts 5-acetyl-4-methoxy-6-methyl-2-pyrone to 4-acetyl-3-methoxy-5-methyl-benzoic acid (macrophomic acid) through an unusual intermolecular Diels-Alder reaction (Scheme 1). The pathway to formation of macrophomic acid suggests that the enzyme is a natural Diels-Alderase.".
- Q6725521 label "Macrophomic acid".
- Q6725521 depiction Macrophomic_acid.svg.