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- Q4897185 subject Q8913144.
- Q4897185 abstract "Beta-hydride elimination is a reaction in which an alkyl group bonded to a metal centre is converted into the corresponding metal-bonded hydride and an alkene. The alkyl must have hydrogens on the beta carbon. For instance butyl groups can undergo this reaction but methyl groups cannot. The metal complex must have an empty (or vacant) site cis to the alkyl group for this reaction to occur.The beta-hydride elimination can either be a vital step in a reaction or an unproductive side reaction. The Shell higher olefin process relies on beta-hydride elimination to produce alpha-olefins which are used to produce detergents. Illustrative of a sometimes undesirable beta-hydride elimination, beta-hydride elimination in Ziegler-Natta polymerization results in polymers of decreased molecular weight. In the case of nickel- and palladium-catalyzed couplings of aryl halides with alkyl Grignard reagents, the beta-hydride elimination can lower the yield. The production of branched polymers from ethylene relies on chain walking, a key step of which is beta-hydride elimination.In some cases, beta-hydride elimination is the first in a series of steps. For instance in the synthesis of RuHCl(CO)(PPh3)3 from ruthenium trichloride, triphenylphosphine and 2-methoxyethanol, an intermediate alkoxide complex undergoes a beta-hydride elimination to form the hydride ligand and the pi-bonded aldehyde which then is later converted into the carbonyl (carbon monoxide) ligand.".
- Q4897185 thumbnail Beta_hydride_elimination.png?width=300.
- Q4897185 wikiPageWikiLink Q101497.
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- Q4897185 wikiPageWikiLink Q5067968.
- Q4897185 wikiPageWikiLink Q656556.
- Q4897185 wikiPageWikiLink Q674.
- Q4897185 wikiPageWikiLink Q744.
- Q4897185 wikiPageWikiLink Q750312.
- Q4897185 wikiPageWikiLink Q81406.
- Q4897185 wikiPageWikiLink Q8913144.
- Q4897185 wikiPageWikiLink Q898912.
- Q4897185 wikiPageWikiLink Q903362.
- Q4897185 comment "Beta-hydride elimination is a reaction in which an alkyl group bonded to a metal centre is converted into the corresponding metal-bonded hydride and an alkene. The alkyl must have hydrogens on the beta carbon. For instance butyl groups can undergo this reaction but methyl groups cannot. The metal complex must have an empty (or vacant) site cis to the alkyl group for this reaction to occur.The beta-hydride elimination can either be a vital step in a reaction or an unproductive side reaction.".
- Q4897185 label "Beta-Hydride elimination".
- Q4897185 depiction Beta_hydride_elimination.png.