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- Q417652 subject Q6522199.
- Q417652 subject Q7158387.
- Q417652 subject Q8529690.
- Q417652 abstract "Hypofluorous acid is the chemical compound with the formula HOF. It is an intermediate in the oxidation of water by fluorine, which produces hydrogen fluoride and oxygen. It is the only hypohalous acid that can be isolated as a solid. HOF is explosive, decomposing to oxygen and HF. It was isolated in the pure form by fluorination of ice.The compound has been characterized in the solid phase by X-ray crystallography as a bent molecule with an angle of 101°. The O–F and O–H bond lengths are 144.2 and 96.4 picometres, respectively. The solid framework consists of chains with O–H---O linkages. The structure has also been analyzed in the gas phase, a state in which the H—O—F bond angle is slightly narrower (97.2°).For fluorine, the only known oxoacid is hypofluorous acid, HOF. It can be made by passing F2gas over ice at −40 °C, collecting the HOF gas, and condensing it:F2 + H2O → HOF + HFIt decomposes explosively at room temperature to form HF and O2:2 HOF → 2 HF + O2Hypofluorous acid in acetonitrile (generated in situ by passing gaseous fluorine through "wet" acetonitrile) serves as a highly electrophilic oxygen-transfer agent. Treating phenanthroline with this reagent yielded the previously elusive 1,10-phenanthroline dioxide, more than 50 years after the first unsuccessful attempt.This molecule is not very symmetric since the atoms are all different. It only has two symmetry operations: identity (E) and a mirror plane that goes through the three atoms. The assigned point group is Cs.".
- Q417652 iupacName "Hypofluorous acid".
- Q417652 thumbnail Hypofluorous-acid-2D-dimensions.png?width=300.
- Q417652 wikiPageWikiLink Q11173.
- Q417652 wikiPageWikiLink Q11438.
- Q417652 wikiPageWikiLink Q192274.
- Q417652 wikiPageWikiLink Q2014867.
- Q417652 wikiPageWikiLink Q2468.
- Q417652 wikiPageWikiLink Q283.
- Q417652 wikiPageWikiLink Q407318.
- Q417652 wikiPageWikiLink Q408047.
- Q417652 wikiPageWikiLink Q416005.
- Q417652 wikiPageWikiLink Q497173.
- Q417652 wikiPageWikiLink Q629.
- Q417652 wikiPageWikiLink Q650.
- Q417652 wikiPageWikiLink Q6522199.
- Q417652 wikiPageWikiLink Q675211.
- Q417652 wikiPageWikiLink Q7158387.
- Q417652 wikiPageWikiLink Q7458208.
- Q417652 wikiPageWikiLink Q7841508.
- Q417652 wikiPageWikiLink Q826582.
- Q417652 wikiPageWikiLink Q82682.
- Q417652 wikiPageWikiLink Q83147.
- Q417652 wikiPageWikiLink Q8529690.
- Q417652 wikiPageWikiLink Q908086.
- Q417652 iupacname "Hypofluorous acid".
- Q417652 name "Hypofluorous acid".
- Q417652 type ChemicalCompound.
- Q417652 type ChemicalSubstance.
- Q417652 type ChemicalObject.
- Q417652 type Thing.
- Q417652 type Q11173.
- Q417652 comment "Hypofluorous acid is the chemical compound with the formula HOF. It is an intermediate in the oxidation of water by fluorine, which produces hydrogen fluoride and oxygen. It is the only hypohalous acid that can be isolated as a solid. HOF is explosive, decomposing to oxygen and HF. It was isolated in the pure form by fluorination of ice.The compound has been characterized in the solid phase by X-ray crystallography as a bent molecule with an angle of 101°.".
- Q417652 label "Hypofluorous acid".
- Q417652 depiction Hypofluorous-acid-2D-dimensions.png.
- Q417652 name "Hypofluorous acid".