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- Q3616599 subject Q8638073.
- Q3616599 subject Q8826219.
- Q3616599 abstract "Molecular Borromean rings are an example of a mechanically-interlocked molecular architecture in which three macrocycles are interlocked in such a way that breaking any macrocycle allows the others to disassociate. They are the smallest examples of Borromean rings. The synthesis of molecular Borromean rings was reported in 2004 by the group of J. Fraser Stoddart. The so-called Borromeate is made up of three interpenetrated macrocycles formed from the reaction between 2,6-diformylpyridine and diamine compounds, complexed with zinc.This compound was synthesized from two building blocks: 2,6-diformylpyridine (a pyridine with two aldehyde groups) and a diamine containing a 2,2'-bipyridine group. Zinc acetate is added as the template for the reaction, resulting in one zinc atom in each of a total of 6 pentacoordinate complexation sites. Trifluoroacetic acid (TFA) is added to catalyse the imine bond-forming reactions. The preparation of the tri-ring Borromeate involves a total of 18 precursor molecules and is only possible because the building blocks self-assemble through 12 aromatic pi-pi interactions and 30 zinc to nitrogen dative bonds. Because of these interactions, the Borromeate is thermodynamically the most stable reaction product out of potentially many others. As a consequence of all the reactions taking place being equilibria, the Borromeate is the predominant reaction product. Reduction with sodium borohydride in ethanol affords the neutral Borromeand. True to a Borromean system, cleavage of just one imine bond (to an amine and an acetal) in this structure breaks the mechanical bond between the three constituent macrocycles, releasing the other two individual rings.Organic synthesis of this seemingly complex compound is in reality fairly simple; the reason why the Stoddart group has suggested it for a classroom experiment on a gram scale.".
- Q3616599 thumbnail Molecular_Borromean_Ring.png?width=300.
- Q3616599 wikiPageExternalLink 8222notw1.html.
- Q3616599 wikiPageExternalLink chemistry.html.
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- Q3616599 wikiPageWikiLink Q8638073.
- Q3616599 wikiPageWikiLink Q8826219.
- Q3616599 wikiPageWikiLink Q894166.
- Q3616599 comment "Molecular Borromean rings are an example of a mechanically-interlocked molecular architecture in which three macrocycles are interlocked in such a way that breaking any macrocycle allows the others to disassociate. They are the smallest examples of Borromean rings. The synthesis of molecular Borromean rings was reported in 2004 by the group of J. Fraser Stoddart.".
- Q3616599 label "Molecular Borromean rings".
- Q3616599 depiction Molecular_Borromean_Ring.png.
