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- Q17074359 subject Q8417818.
- Q17074359 subject Q8913144.
- Q17074359 abstract "In coordination chemistry, a spectator ligand is a ligand that does not participate in chemical reactions of the complex. Instead, spectator ligands (vs "actor ligands") occupy coordination sites. Spectator ligands tend to be of polydentate, such that the M-spectator ensemble is inert kinetically. Although they do not participate in reactions of the metal, spectator ligands influence the reactivity of the metal center to which they are bound.There are several different classes of ligand that can be considered spectator ligands. A few examples of common spectator ligands include trispyrazolylborates (Tp), cyclopentadienyl ligands (Cp), and many chelating diphosphines such as 1,2-bis(diphenylphosphino)ethane ligands (dppe). Varying the substituents on the spectator ligands greatly influences the solubility, stability, electronic and steric properties of the metal complex.".
- Q17074359 thumbnail LnMTp.png?width=300.
- Q17074359 wikiPageWikiLink Q161453.
- Q17074359 wikiPageWikiLink Q193161.
- Q17074359 wikiPageWikiLink Q2209035.
- Q17074359 wikiPageWikiLink Q238156.
- Q17074359 wikiPageWikiLink Q2454098.
- Q17074359 wikiPageWikiLink Q3023362.
- Q17074359 wikiPageWikiLink Q8417818.
- Q17074359 wikiPageWikiLink Q8913144.
- Q17074359 comment "In coordination chemistry, a spectator ligand is a ligand that does not participate in chemical reactions of the complex. Instead, spectator ligands (vs "actor ligands") occupy coordination sites. Spectator ligands tend to be of polydentate, such that the M-spectator ensemble is inert kinetically.".
- Q17074359 label "Spectator ligand".
- Q17074359 depiction LnMTp.png.