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- Zero-phonon_line_and_phonon_sideband abstract "The zero-phonon line and the phonon sideband jointly constitute the line shape of individual light absorbing and emitting molecules (chromophores) embedded into a transparent solid matrix. When the host matrix contains many chromophores, each will contribute a zero-phonon line and a phonon sideband to the absorption and emission spectra. The spectra originating from a collection of identical chromophores in a matrix is said to be inhomogeneously broadened because each chromophore is surrounded by a somewhat different matrix environment which modifies the energy required for an electronic transition. In an inhomogeneous distribution of chromophores, individual zero-phonon line and phonon sideband positions are therefore shifted and overlapping.Figure 1 shows the typical line shape for electronic transitions of individual chromophores in a solid matrix. The zero-phonon line is located at a frequency ω’ determined by the intrinsic difference in energy levels between ground and excited state as well as by the local environment. The phonon sideband is shifted to a higher frequency in absorption and to a lower frequency in fluorescence. The frequency gap Δ between the zero-phonon line and the peak of the phonon side band is determined by Franck–Condon principles.The distribution of intensity between the zero-phonon line and the phonon side band is strongly dependent on temperature. At room temperature there is enough thermal energy to excite many phonons and the probability of zero-phonon transition is close to zero. For organic chromophores in organic matrices, the probability of a zero-phonon electronic transition only becomes likely below about 40 kelvins, but depends also on the strength of coupling between the chromophore and the host lattice.".
- Zero-phonon_line_and_phonon_sideband thumbnail Line-shape.png?width=300.
- Zero-phonon_line_and_phonon_sideband wikiPageExternalLink c1.
- Zero-phonon_line_and_phonon_sideband wikiPageExternalLink HoleBurning_00.htm.
- Zero-phonon_line_and_phonon_sideband wikiPageID "3649656".
- Zero-phonon_line_and_phonon_sideband wikiPageLength "9451".
- Zero-phonon_line_and_phonon_sideband wikiPageOutDegree "38".
- Zero-phonon_line_and_phonon_sideband wikiPageRevisionID "703665301".
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Absolute_zero.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Category:Condensed_matter_physics.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Category:Optics.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Category:Spectroscopy.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Cauchy_distribution.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Chromophore.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Debye–Waller_factor.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Excited_state.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Franck–Condon_principle.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Frequency.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Gamma_ray.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Ground_state.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Hamiltonian_(quantum_mechanics).
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Kelvin.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Momentum.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Mössbauer_effect.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Normal_distribution.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Normal_mode.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Parabola.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Phonon.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Photon.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Poisson_distribution.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Quantum.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Quantum_harmonic_oscillator.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Shpolskii_matrix.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Spectral_line.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Spectrum.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Stokes_shift.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink Uncertainty_principle.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink File:Lattice-modes.png.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink File:Line-shape.png.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLink File:Phonon-energy-diagram.png.
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLinkText "Zero-phonon line and phonon sideband".
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLinkText "Zero-phonon optical transitions".
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLinkText "phonon sideband".
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLinkText "phononic sideband".
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLinkText "zero phonon lines".
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLinkText "zero-phonon line and phonon sideband".
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLinkText "zero-phonon line".
- Zero-phonon_line_and_phonon_sideband wikiPageWikiLinkText "zero-phonon".
- Zero-phonon_line_and_phonon_sideband wikiPageUsesTemplate Template:Cite_book.
- Zero-phonon_line_and_phonon_sideband wikiPageUsesTemplate Template:Cite_journal.
- Zero-phonon_line_and_phonon_sideband wikiPageUsesTemplate Template:Nofootnotes.
- Zero-phonon_line_and_phonon_sideband subject Category:Condensed_matter_physics.
- Zero-phonon_line_and_phonon_sideband subject Category:Optics.
- Zero-phonon_line_and_phonon_sideband subject Category:Spectroscopy.
- Zero-phonon_line_and_phonon_sideband type Physic.
- Zero-phonon_line_and_phonon_sideband type Science.
- Zero-phonon_line_and_phonon_sideband type Technique.
- Zero-phonon_line_and_phonon_sideband comment "The zero-phonon line and the phonon sideband jointly constitute the line shape of individual light absorbing and emitting molecules (chromophores) embedded into a transparent solid matrix. When the host matrix contains many chromophores, each will contribute a zero-phonon line and a phonon sideband to the absorption and emission spectra.".
- Zero-phonon_line_and_phonon_sideband label "Zero-phonon line and phonon sideband".
- Zero-phonon_line_and_phonon_sideband sameAs Q921604.
- Zero-phonon_line_and_phonon_sideband sameAs Raie_zéro-phonon_et_bande_satellite_phonon.
- Zero-phonon_line_and_phonon_sideband sameAs ゼロフォノン線とフォノンサイドバンド.
- Zero-phonon_line_and_phonon_sideband sameAs m.09s7gm.
- Zero-phonon_line_and_phonon_sideband sameAs Q921604.
- Zero-phonon_line_and_phonon_sideband wasDerivedFrom Zero-phonon_line_and_phonon_sideband?oldid=703665301.
- Zero-phonon_line_and_phonon_sideband depiction Line-shape.png.
- Zero-phonon_line_and_phonon_sideband isPrimaryTopicOf Zero-phonon_line_and_phonon_sideband.