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- Wharton_reaction abstract "The Wharton olefin synthesis is a chemical reaction that involves the reduction of α,β-epoxy ketones using hydrazine to give allylic alcohols. This reaction, introduced in 1961 by P. S. Wharton, is an extension of the Wolff–Kishner reduction. The general features of this synthesis are: 1) the epoxidation of α,β-unsaturated ketones is achieved usually in basic conditions using hydrogen peroxide solution in high yield; 2) the epoxy ketone is treated with 2–3 equivalents of a hydrazine hydrate in presence of substoichiometric amounts of acetic acid. This reaction occurs rapidly at room temperature with the evolution of nitrogen and the formation of an allylic alcohol. It can be used to synthesize carenol compounds. The Wharton reaction is the chemical reaction of α,β-epoxy-ketones with hydrazine to give allylic alcohols. Wharton's procedure has been improved.".
- Wharton_reaction thumbnail Wharton_Reaction_Scheme.png?width=300.
- Wharton_reaction wikiPageID "3588960".
- Wharton_reaction wikiPageLength "5008".
- Wharton_reaction wikiPageOutDegree "33".
- Wharton_reaction wikiPageRevisionID "666481044".
- Wharton_reaction wikiPageWikiLink Acetic_acid.
- Wharton_reaction wikiPageWikiLink Alcohol.
- Wharton_reaction wikiPageWikiLink Allyl.
- Wharton_reaction wikiPageWikiLink Allyl_alcohol.
- Wharton_reaction wikiPageWikiLink Anhydrous.
- Wharton_reaction wikiPageWikiLink Anticarcinogen.
- Wharton_reaction wikiPageWikiLink Category:Name_reactions.
- Wharton_reaction wikiPageWikiLink Category:Organic_redox_reactions.
- Wharton_reaction wikiPageWikiLink Chemical_reaction.
- Wharton_reaction wikiPageWikiLink Cis–trans_isomerism.
- Wharton_reaction wikiPageWikiLink Diol.
- Wharton_reaction wikiPageWikiLink Epoxide.
- Wharton_reaction wikiPageWikiLink Eschenmoser_fragmentation.
- Wharton_reaction wikiPageWikiLink Grob_fragmentation.
- Wharton_reaction wikiPageWikiLink Hydrazine.
- Wharton_reaction wikiPageWikiLink Hydrazone.
- Wharton_reaction wikiPageWikiLink Hydrogen_peroxide.
- Wharton_reaction wikiPageWikiLink Ketone.
- Wharton_reaction wikiPageWikiLink Natural_product.
- Wharton_reaction wikiPageWikiLink Nitrogen.
- Wharton_reaction wikiPageWikiLink Open-chain_compound.
- Wharton_reaction wikiPageWikiLink Reaction_mechanism.
- Wharton_reaction wikiPageWikiLink Stoichiometry.
- Wharton_reaction wikiPageWikiLink Wolff–Kishner_reduction.
- Wharton_reaction wikiPageWikiLink File:Drimanes_Wharton_reaction.png.
- Wharton_reaction wikiPageWikiLink File:Wharton_Reaction_Mechanism.png.
- Wharton_reaction wikiPageWikiLink File:Wharton_Reaction_Scheme.png.
- Wharton_reaction wikiPageWikiLinkText "Wharton reaction".
- Wharton_reaction subject Category:Name_reactions.
- Wharton_reaction subject Category:Organic_redox_reactions.
- Wharton_reaction hypernym Reaction.
- Wharton_reaction type Disease.
- Wharton_reaction type Eponym.
- Wharton_reaction type Process.
- Wharton_reaction type Reaction.
- Wharton_reaction type Redirect.
- Wharton_reaction comment "The Wharton olefin synthesis is a chemical reaction that involves the reduction of α,β-epoxy ketones using hydrazine to give allylic alcohols. This reaction, introduced in 1961 by P. S. Wharton, is an extension of the Wolff–Kishner reduction.".
- Wharton_reaction label "Wharton reaction".
- Wharton_reaction sameAs Q7990731.
- Wharton_reaction sameAs Wharton-Olefinsynthese.
- Wharton_reaction sameAs Reacción_de_Wharton.
- Wharton_reaction sameAs m.09ncm1.
- Wharton_reaction sameAs Q7990731.
- Wharton_reaction sameAs 沃顿反应.
- Wharton_reaction wasDerivedFrom Wharton_reaction?oldid=666481044.
- Wharton_reaction depiction Wharton_Reaction_Scheme.png.
- Wharton_reaction isPrimaryTopicOf Wharton_reaction.