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- Upjohn_dihydroxylation abstract "Upjohn dihydroxylation is an organic reaction converting an alkene to a cis vicinal diol, and was developed by V. VanRheenen, R. C. Kelly and D. Y. Cha of the Upjohn Company, USA in 1976. It is a catalytic system using N-methylmorpholine N-oxide (NMO) as stoichiometric re-oxidant for the Osmium tetroxide, and is superior to previous catalytic methods. Prior to this method, use of stoichiometric amounts of the toxic and expensive osmium tetroxide was often necessary. The Upjohn dihydroxylation is still often used for the formation of cis-vicinal diols, however it can be slow and is prone to over-oxidation of the substrate to the vicinal di-ketone. One of the peculiarities of the dihydroxylation of olefins is that the standard \"racemic\" method (the Upjohn dihydroxyation) is slower and often lower yielding than the asymmetric method (the Sharpless asymmetric dihydroxylation).".
- Upjohn_dihydroxylation thumbnail Upjohn_dihydroxylation.svg?width=300.
- Upjohn_dihydroxylation wikiPageID "9429153".
- Upjohn_dihydroxylation wikiPageLength "2198".
- Upjohn_dihydroxylation wikiPageOutDegree "16".
- Upjohn_dihydroxylation wikiPageRevisionID "642772054".
- Upjohn_dihydroxylation wikiPageWikiLink Alkene.
- Upjohn_dihydroxylation wikiPageWikiLink Category:Name_reactions.
- Upjohn_dihydroxylation wikiPageWikiLink Category:Organic_redox_reactions.
- Upjohn_dihydroxylation wikiPageWikiLink Diol.
- Upjohn_dihydroxylation wikiPageWikiLink Karl_Barry_Sharpless.
- Upjohn_dihydroxylation wikiPageWikiLink Milas_hydroxylation.
- Upjohn_dihydroxylation wikiPageWikiLink N-Methylmorpholine_N-oxide.
- Upjohn_dihydroxylation wikiPageWikiLink Organic_reaction.
- Upjohn_dihydroxylation wikiPageWikiLink Osmium_tetroxide.
- Upjohn_dihydroxylation wikiPageWikiLink Quinuclidine.
- Upjohn_dihydroxylation wikiPageWikiLink Sharpless_asymmetric_dihydroxylation.
- Upjohn_dihydroxylation wikiPageWikiLink Upjohn.
- Upjohn_dihydroxylation wikiPageWikiLink Vicinal_(chemistry).
- Upjohn_dihydroxylation wikiPageWikiLink File:Upjohn_dihydroxylation.svg.
- Upjohn_dihydroxylation wikiPageWikiLinkText "Upjohn Reaction".
- Upjohn_dihydroxylation wikiPageWikiLinkText "Upjohn dihydroxylation".
- Upjohn_dihydroxylation wikiPageUsesTemplate Template:Reflist.
- Upjohn_dihydroxylation subject Category:Name_reactions.
- Upjohn_dihydroxylation subject Category:Organic_redox_reactions.
- Upjohn_dihydroxylation hypernym Reaction.
- Upjohn_dihydroxylation type Disease.
- Upjohn_dihydroxylation type Eponym.
- Upjohn_dihydroxylation type Reaction.
- Upjohn_dihydroxylation comment "Upjohn dihydroxylation is an organic reaction converting an alkene to a cis vicinal diol, and was developed by V. VanRheenen, R. C. Kelly and D. Y. Cha of the Upjohn Company, USA in 1976. It is a catalytic system using N-methylmorpholine N-oxide (NMO) as stoichiometric re-oxidant for the Osmium tetroxide, and is superior to previous catalytic methods. Prior to this method, use of stoichiometric amounts of the toxic and expensive osmium tetroxide was often necessary.".
- Upjohn_dihydroxylation label "Upjohn dihydroxylation".
- Upjohn_dihydroxylation sameAs Q3240610.
- Upjohn_dihydroxylation sameAs Hidroxilación_de_Upjohn.
- Upjohn_dihydroxylation sameAs Upjohn-dihydroxylering.
- Upjohn_dihydroxylation sameAs Di-hidrogenação_de_Upjohn.
- Upjohn_dihydroxylation sameAs m.0288lwb.
- Upjohn_dihydroxylation sameAs Q3240610.
- Upjohn_dihydroxylation sameAs Upjohn双羟基化反应.
- Upjohn_dihydroxylation wasDerivedFrom Upjohn_dihydroxylation?oldid=642772054.
- Upjohn_dihydroxylation depiction Upjohn_dihydroxylation.svg.
- Upjohn_dihydroxylation isPrimaryTopicOf Upjohn_dihydroxylation.