Matches in DBpedia 2016-04 for { <http://dbpedia.org/resource/Sharpless_epoxidation> ?p ?o }
- Sharpless_epoxidation abstract "The Sharpless epoxidation reaction is an enantioselective chemical reaction to prepare 2,3-epoxyalcohols from primary and secondary allylic alcohols.The stereochemistry of the resulting epoxide is determined by the diastereomer of the chiral tartrate diester (usually diethyl tartrate or diisopropyl tartrate) employed in the reaction. The oxidizing agent is tert-butyl hydroperoxide. Enantioselectivity is achieved by a catalyst formed from titanium tetra(isopropoxide) and diethyl tartrate. Only 5–10 mol% of the catalyst in the presence of 3Å molecular sieves (3Å MS) is necessary.The Sharpless epoxidation's success is due to five major reasons. First, epoxides can be easily converted into diols, aminoalcohols or ethers, so formation of chiral epoxides is a very important step in the synthesis of natural products. Second, the Sharpless epoxidation reacts with many primary and secondary allylic alcohols. Third, the products of the Sharpless epoxidation frequently have enantiomeric excesses above 90%. Fourth, the products of the Sharpless epoxidation are predictable using the Sharpless Epoxidation model. Finally, the reactants for the Sharpless epoxidation are commercially available and relatively cheap.Several reviews have been published.K. Barry Sharpless shared the 2001 Nobel prize in Chemistry for his work on asymmetric oxidations.The prize was shared with William S. Knowles and Ryōji Noyori.".
- Sharpless_epoxidation thumbnail Sharpless_epoxidation_DE.svg?width=300.
- Sharpless_epoxidation wikiPageExternalLink 16_Sharpless_Asymmetric_E.pdf.
- Sharpless_epoxidation wikiPageID "173356".
- Sharpless_epoxidation wikiPageLength "16715".
- Sharpless_epoxidation wikiPageOutDegree "65".
- Sharpless_epoxidation wikiPageRevisionID "690365391".
- Sharpless_epoxidation wikiPageWikiLink Acetylation.
- Sharpless_epoxidation wikiPageWikiLink Alkene.
- Sharpless_epoxidation wikiPageWikiLink Allyl.
- Sharpless_epoxidation wikiPageWikiLink Allyl_alcohol.
- Sharpless_epoxidation wikiPageWikiLink Allylic_strain.
- Sharpless_epoxidation wikiPageWikiLink Antibiotics.
- Sharpless_epoxidation wikiPageWikiLink Asymmetric_catalytic_oxidation.
- Sharpless_epoxidation wikiPageWikiLink Carbohydrate.
- Sharpless_epoxidation wikiPageWikiLink Carbonyl.
- Sharpless_epoxidation wikiPageWikiLink Category:Catalysis.
- Sharpless_epoxidation wikiPageWikiLink Category:Epoxides.
- Sharpless_epoxidation wikiPageWikiLink Category:Name_reactions.
- Sharpless_epoxidation wikiPageWikiLink Category:Organic_redox_reactions.
- Sharpless_epoxidation wikiPageWikiLink Chemical_reaction.
- Sharpless_epoxidation wikiPageWikiLink Cyclohexane_conformation.
- Sharpless_epoxidation wikiPageWikiLink Diastereomer.
- Sharpless_epoxidation wikiPageWikiLink Diethyl_tartrate.
- Sharpless_epoxidation wikiPageWikiLink Dihedral_angle.
- Sharpless_epoxidation wikiPageWikiLink Diisopropyl_tartrate.
- Sharpless_epoxidation wikiPageWikiLink Diol.
- Sharpless_epoxidation wikiPageWikiLink Enantiomer.
- Sharpless_epoxidation wikiPageWikiLink Enantiomeric_excess.
- Sharpless_epoxidation wikiPageWikiLink Erythromycin.
- Sharpless_epoxidation wikiPageWikiLink Ether.
- Sharpless_epoxidation wikiPageWikiLink Fluorocarbon.
- Sharpless_epoxidation wikiPageWikiLink Functional_group.
- Sharpless_epoxidation wikiPageWikiLink Hydrogen_bond.
- Sharpless_epoxidation wikiPageWikiLink Jacobsen_epoxidation.
- Sharpless_epoxidation wikiPageWikiLink Juliá–Colonna_epoxidation.
- Sharpless_epoxidation wikiPageWikiLink Karl_Barry_Sharpless.
- Sharpless_epoxidation wikiPageWikiLink Kinetic_resolution.
- Sharpless_epoxidation wikiPageWikiLink Leukotriene.
- Sharpless_epoxidation wikiPageWikiLink Mnemonic.
- Sharpless_epoxidation wikiPageWikiLink Molecular_sieve.
- Sharpless_epoxidation wikiPageWikiLink Nobel_Prize_in_Chemistry.
- Sharpless_epoxidation wikiPageWikiLink Pheromone.
- Sharpless_epoxidation wikiPageWikiLink Regioselectivity.
- Sharpless_epoxidation wikiPageWikiLink Ryōji_Noyori.
- Sharpless_epoxidation wikiPageWikiLink Steric_effects.
- Sharpless_epoxidation wikiPageWikiLink Terpene.
- Sharpless_epoxidation wikiPageWikiLink Tert-Butyl_hydroperoxide.
- Sharpless_epoxidation wikiPageWikiLink Titanium_isopropoxide.
- Sharpless_epoxidation wikiPageWikiLink Vinyl.
- Sharpless_epoxidation wikiPageWikiLink William_Standish_Knowles.
- Sharpless_epoxidation wikiPageWikiLink Ångström.
- Sharpless_epoxidation wikiPageWikiLink File:Conformationally_locked_directing_groups.png.
- Sharpless_epoxidation wikiPageWikiLink File:Fluro_binding_model.png.
- Sharpless_epoxidation wikiPageWikiLink File:Homoallylic_VO.png.
- Sharpless_epoxidation wikiPageWikiLink File:Homoallylic_peracid.png.
- Sharpless_epoxidation wikiPageWikiLink File:Kinetic_resolution.png.
- Sharpless_epoxidation wikiPageWikiLink File:Kinetics_with_allylic_hetero_atoms.png.
- Sharpless_epoxidation wikiPageWikiLink File:Mnemonic.png.
- Sharpless_epoxidation wikiPageWikiLink File:Peracid_H_bonding_model.png.
- Sharpless_epoxidation wikiPageWikiLink File:Ring_size_on_selectivity.png.
- Sharpless_epoxidation wikiPageWikiLink File:Roation_stuff.png.
- Sharpless_epoxidation wikiPageWikiLink File:Sharpless_epoxidation_DE.svg.
- Sharpless_epoxidation wikiPageWikiLink File:Sharpless_model_violation.png.
- Sharpless_epoxidation wikiPageWikiLink File:Transition_state.png.
- Sharpless_epoxidation wikiPageWikiLink File:Utility.png.
- Sharpless_epoxidation wikiPageWikiLink File:VO_selectivity.png.
- Sharpless_epoxidation wikiPageWikiLink File:Vinyl_Bulk.png.
- Sharpless_epoxidation wikiPageWikiLinkText "Sharpless epoxidation".
- Sharpless_epoxidation wikiPageWikiLinkText "Sharpless reagent".
- Sharpless_epoxidation wikiPageUsesTemplate Template:Authority_control.
- Sharpless_epoxidation wikiPageUsesTemplate Template:Reflist.
- Sharpless_epoxidation wikiPageUsesTemplate Template:Use_dmy_dates.
- Sharpless_epoxidation subject Category:Catalysis.
- Sharpless_epoxidation subject Category:Epoxides.
- Sharpless_epoxidation subject Category:Name_reactions.
- Sharpless_epoxidation subject Category:Organic_redox_reactions.
- Sharpless_epoxidation hypernym Reaction.
- Sharpless_epoxidation type Disease.
- Sharpless_epoxidation type Eponym.
- Sharpless_epoxidation type Ether.
- Sharpless_epoxidation type Heterocycle.
- Sharpless_epoxidation type Page.
- Sharpless_epoxidation type Process.
- Sharpless_epoxidation type Reaction.
- Sharpless_epoxidation type Thing.
- Sharpless_epoxidation comment "The Sharpless epoxidation reaction is an enantioselective chemical reaction to prepare 2,3-epoxyalcohols from primary and secondary allylic alcohols.The stereochemistry of the resulting epoxide is determined by the diastereomer of the chiral tartrate diester (usually diethyl tartrate or diisopropyl tartrate) employed in the reaction. The oxidizing agent is tert-butyl hydroperoxide. Enantioselectivity is achieved by a catalyst formed from titanium tetra(isopropoxide) and diethyl tartrate.".
- Sharpless_epoxidation label "Sharpless epoxidation".
- Sharpless_epoxidation sameAs Q902026.
- Sharpless_epoxidation sameAs Sharpless-Epoxidierung.
- Sharpless_epoxidation sameAs Epoxidación_de_Sharpless.
- Sharpless_epoxidation sameAs Sharpless-epoksidointi.
- Sharpless_epoxidation sameAs Époxydation_de_Sharpless.
- Sharpless_epoxidation sameAs Epossidazione_di_Sharpless.
- Sharpless_epoxidation sameAs シャープレス酸化.
- Sharpless_epoxidation sameAs Sharpless-epoxidatie.
- Sharpless_epoxidation sameAs Asymetryczna_epoksydacja_Sharplessa.
- Sharpless_epoxidation sameAs m.017cn6.
- Sharpless_epoxidation sameAs Q902026.
- Sharpless_epoxidation sameAs 夏普莱斯不对称环氧化反应.