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- Indium-mediated_allylation abstract "Indium-Mediated Allylations (IMAs) are important chemical reactions for the formation of carbon–carbon bonds. This reaction has two steps: first, indium inserts itself between the carbon–halogen bond of an allyl halide, becoming the organoindium intermediate; second, this allyl indide intermediate reacts with an electrophile to synthesize one of a wide range of compounds, such as carbohydrates and antihelminthic drugs. This reaction is depicted in the scheme below:Two steps of the IMA reaction mechanism Although this reaction occurs in two steps, it is commonly done as a Barbier reaction where the indium, allyl halide, and electrophile are all mixed together in a one-pot process.IMA illustrated as a Barbier reactionIndium reacts more readily than other metals, such as Mg, Pb, Bi, or Zn and does not require a promoter or flammable organic solvent to drive the reaction. IMAs have advantages over other carbon bond forming reactions because of their ability to be carried out in water, which is cheap and environmentally friendly. Therefore, these reactions represent Green chemistry, providing a safer alternative to the very common Grignard reaction, performed with Mg. Reactions yield high stereo- and regio-selectivity with few by-products making it easy to purify the desired product.".
- Indium-mediated_allylation thumbnail IMA_in_two_steps_as_scalable_vg_file.svg?width=300.
- Indium-mediated_allylation wikiPageID "36624325".
- Indium-mediated_allylation wikiPageLength "10249".
- Indium-mediated_allylation wikiPageOutDegree "44".
- Indium-mediated_allylation wikiPageRevisionID "673106486".
- Indium-mediated_allylation wikiPageWikiLink Allyl.
- Indium-mediated_allylation wikiPageWikiLink Barbier_reaction.
- Indium-mediated_allylation wikiPageWikiLink Carbohydrate.
- Indium-mediated_allylation wikiPageWikiLink Carbonyl.
- Indium-mediated_allylation wikiPageWikiLink Carbon–carbon_bond.
- Indium-mediated_allylation wikiPageWikiLink Category:Chemical_reactions.
- Indium-mediated_allylation wikiPageWikiLink Category:Indium.
- Indium-mediated_allylation wikiPageWikiLink Chemical_reaction.
- Indium-mediated_allylation wikiPageWikiLink Chemoselectivity.
- Indium-mediated_allylation wikiPageWikiLink Dimethylformamide.
- Indium-mediated_allylation wikiPageWikiLink Electrophile.
- Indium-mediated_allylation wikiPageWikiLink Enthalpy.
- Indium-mediated_allylation wikiPageWikiLink Environmentally_friendly.
- Indium-mediated_allylation wikiPageWikiLink Exothermic_process.
- Indium-mediated_allylation wikiPageWikiLink File:A_wide_variety_of_IMA_reactions.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Another_example_of_enantioselective_IMA.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Balanced_chemical_reactions_for_mix_of_In_and_allyl_halide.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Corrected_example_of_enantioselective_IMA.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Example_of_ima_showing_alpha_vs_gamma.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Explanation_of_diastereoselectivity_of_IMA.svg.
- Indium-mediated_allylation wikiPageWikiLink File:IMA_in_two_steps_as_scalable_vg_file.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Ima_example_showing_diastereoselectivity.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Ima_illustrated_as_a_Barbier_reaction.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Propargylation_of_a_ketone.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Three_chiral_additives_for_ima.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Two_intermediates_formed_during_IMA.svg.
- Indium-mediated_allylation wikiPageWikiLink File:Updated_chemoselective_propargylation_of_aldehyde.svg.
- Indium-mediated_allylation wikiPageWikiLink Green_chemistry.
- Indium-mediated_allylation wikiPageWikiLink Grignard_reaction.
- Indium-mediated_allylation wikiPageWikiLink Haloalkane.
- Indium-mediated_allylation wikiPageWikiLink Indium.
- Indium-mediated_allylation wikiPageWikiLink Magnesium.
- Indium-mediated_allylation wikiPageWikiLink Magnesium_oxide.
- Indium-mediated_allylation wikiPageWikiLink N-Methylformamide.
- Indium-mediated_allylation wikiPageWikiLink Organogallium_chemistry.
- Indium-mediated_allylation wikiPageWikiLink Propargyl.
- Indium-mediated_allylation wikiPageWikiLink Regioselectivity.
- Indium-mediated_allylation wikiPageWikiLink Solvent.
- Indium-mediated_allylation wikiPageWikiLink Sonication.
- Indium-mediated_allylation wikiPageWikiLink Steric_effects.
- Indium-mediated_allylation wikiPageWikiLink Tetrahydrofuran.
- Indium-mediated_allylation wikiPageWikiLinkText "Indium-mediated allylation".
- Indium-mediated_allylation wikiPageWikiLinkText "indium-mediated allylation".
- Indium-mediated_allylation wikiPageUsesTemplate Template:Cn.
- Indium-mediated_allylation wikiPageUsesTemplate Template:Primary_sources.
- Indium-mediated_allylation wikiPageUsesTemplate Template:Reflist.
- Indium-mediated_allylation wikiPageUsesTemplate Template:Technical.
- Indium-mediated_allylation subject Category:Chemical_reactions.
- Indium-mediated_allylation subject Category:Indium.
- Indium-mediated_allylation hypernym Reactions.
- Indium-mediated_allylation type Disease.
- Indium-mediated_allylation type Process.
- Indium-mediated_allylation type Reaction.
- Indium-mediated_allylation comment "Indium-Mediated Allylations (IMAs) are important chemical reactions for the formation of carbon–carbon bonds. This reaction has two steps: first, indium inserts itself between the carbon–halogen bond of an allyl halide, becoming the organoindium intermediate; second, this allyl indide intermediate reacts with an electrophile to synthesize one of a wide range of compounds, such as carbohydrates and antihelminthic drugs.".
- Indium-mediated_allylation label "Indium-mediated allylation".
- Indium-mediated_allylation sameAs Q6025195.
- Indium-mediated_allylation sameAs m.0km2ggn.
- Indium-mediated_allylation sameAs Q6025195.
- Indium-mediated_allylation wasDerivedFrom Indium-mediated_allylation?oldid=673106486.
- Indium-mediated_allylation depiction IMA_in_two_steps_as_scalable_vg_file.svg.
- Indium-mediated_allylation isPrimaryTopicOf Indium-mediated_allylation.