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- Edwards_equation abstract "The Edwards equation in organic chemistry is a two-parameter equation for correlating nucleophilic reactivity, as defined by relative rate constants, with the basicity of the nucleophile (relative to protons) and its polarizability. This equation was first developed by John O. Edwards in 1954 and later revised based on additional work in 1956. The general idea is that most nucleophiles are also good bases because the concentration of negatively charged electron density that defines a nucleophile will strongly attract positively charged protons, which is the definition of a base according to Brønsted-Lowry acid-base theory. Additionally, highly polarizable nucleophiles will have greater nucleophilic character than suggested by their basicity because their electron density can be shifted with relative ease to concentrate in one area.".
- Edwards_equation wikiPageID "39302352".
- Edwards_equation wikiPageLength "9914".
- Edwards_equation wikiPageOutDegree "15".
- Edwards_equation wikiPageRevisionID "662943570".
- Edwards_equation wikiPageWikiLink Alpha_effect.
- Edwards_equation wikiPageWikiLink Base_(chemistry).
- Edwards_equation wikiPageWikiLink Bell–Evans–Polanyi_principle.
- Edwards_equation wikiPageWikiLink Bromomethane.
- Edwards_equation wikiPageWikiLink Brønsted_catalysis_equation.
- Edwards_equation wikiPageWikiLink Brønsted–Lowry_acid–base_theory.
- Edwards_equation wikiPageWikiLink Category:Equations.
- Edwards_equation wikiPageWikiLink Category:Physical_organic_chemistry.
- Edwards_equation wikiPageWikiLink Free-energy_relationship.
- Edwards_equation wikiPageWikiLink HSAB_theory.
- Edwards_equation wikiPageWikiLink Hammett_equation.
- Edwards_equation wikiPageWikiLink Molar_refractivity.
- Edwards_equation wikiPageWikiLink Nucleophile.
- Edwards_equation wikiPageWikiLink Polarizability.
- Edwards_equation wikiPageWikiLinkText "Edwards equation".
- Edwards_equation wikiPageUsesTemplate Template:Reflist.
- Edwards_equation subject Category:Equations.
- Edwards_equation subject Category:Physical_organic_chemistry.
- Edwards_equation hypernym Equation.
- Edwards_equation comment "The Edwards equation in organic chemistry is a two-parameter equation for correlating nucleophilic reactivity, as defined by relative rate constants, with the basicity of the nucleophile (relative to protons) and its polarizability. This equation was first developed by John O. Edwards in 1954 and later revised based on additional work in 1956.".
- Edwards_equation label "Edwards equation".
- Edwards_equation sameAs m.01295zld.
- Edwards_equation wasDerivedFrom Edwards_equation?oldid=662943570.
- Edwards_equation isPrimaryTopicOf Edwards_equation.