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- Corrole abstract "A corrole is an aromatic organic chemical, the structure of which is similar to the corrin ring, which is also present in cobalamin (vitamin B12). The ring consists of nineteen carbon atoms, with four nitrogen atoms in the core of the molecule. In this sense, corrole is very similar to porphyrin, which is also an organic macrocycle but has twenty carbon atoms and is found in hemoglobin and chlorophyll.Corroles can be prepared through organic synthesis by condensation reaction of a benzaldehyde with pyrrole in a water / methanol / hydrochloric acid mixture to an open-ring bilane (or tetrapyrrane) followed by oxidation and ring closure with p-chloranil:Corrole has several important differences from porphyrin. The first is that it is normally a trianionic ligand with transition metals, while porphyrin is typically a dianionic ligand. As a result, corrole supports metals in higher oxidation states. The second difference from porphyrin is that, because the ring of corrole is smaller, there is slightly less space in the middle of it, which results in many metals sitting slightly out of the plane created by the four nitrogen atoms in the ring.Corroles have been attached to a wide range of transition metals, main group elements, and more recently, lanthanides, actinides. and the diprotonated, neutral corrole radical. Additionally, corroles and their metal complexes have been demonstrated to be useful as imaging agents in tumor detection, for prevention of heart disease, in synthetic chemistry as oxo, imido, and nitrido transfer agents, and as catalysts for the catalytic reduction of oxygen to water, and hydrogen production form water under aerobic conditions.".
- Corrole thumbnail Corrole_revisedII.png?width=300.
- Corrole wikiPageID "2049123".
- Corrole wikiPageLength "5847".
- Corrole wikiPageOutDegree "32".
- Corrole wikiPageRevisionID "696048339".
- Corrole wikiPageWikiLink Actinide.
- Corrole wikiPageWikiLink Aromaticity.
- Corrole wikiPageWikiLink Benzaldehyde.
- Corrole wikiPageWikiLink Bilin_(biochemistry).
- Corrole wikiPageWikiLink Carbon.
- Corrole wikiPageWikiLink Category:Chelating_agents.
- Corrole wikiPageWikiLink Category:Macrocycles.
- Corrole wikiPageWikiLink Category:Tetrapyrroles.
- Corrole wikiPageWikiLink Chloranil.
- Corrole wikiPageWikiLink Chlorophyll.
- Corrole wikiPageWikiLink Cobalamin.
- Corrole wikiPageWikiLink Condensation_reaction.
- Corrole wikiPageWikiLink Corrin.
- Corrole wikiPageWikiLink Hemoglobin.
- Corrole wikiPageWikiLink Hydrochloric_acid.
- Corrole wikiPageWikiLink Ion.
- Corrole wikiPageWikiLink Lanthanide.
- Corrole wikiPageWikiLink Ligand.
- Corrole wikiPageWikiLink Macrocycle.
- Corrole wikiPageWikiLink Main_group_elements.
- Corrole wikiPageWikiLink Methanol.
- Corrole wikiPageWikiLink Nitrogen.
- Corrole wikiPageWikiLink Organic_compound.
- Corrole wikiPageWikiLink Organic_synthesis.
- Corrole wikiPageWikiLink Oxidation_state.
- Corrole wikiPageWikiLink Porphyrin.
- Corrole wikiPageWikiLink Pyrrole.
- Corrole wikiPageWikiLink Radical_(chemistry).
- Corrole wikiPageWikiLink Transition_metal.
- Corrole wikiPageWikiLink Vitamin_B12.
- Corrole wikiPageWikiLink File:Corrole_revisedII.png.
- Corrole wikiPageWikiLinkText "Corrole".
- Corrole wikiPageWikiLinkText "corrole".
- Corrole subject Category:Chelating_agents.
- Corrole subject Category:Macrocycles.
- Corrole subject Category:Tetrapyrroles.
- Corrole hypernym Chemical.
- Corrole type Agent.
- Corrole type ChemicalCompound.
- Corrole type Agent.
- Corrole type Chemical.
- Corrole type Macrocycle.
- Corrole comment "A corrole is an aromatic organic chemical, the structure of which is similar to the corrin ring, which is also present in cobalamin (vitamin B12). The ring consists of nineteen carbon atoms, with four nitrogen atoms in the core of the molecule.".
- Corrole label "Corrole".
- Corrole sameAs Q1752388.
- Corrole sameAs Corrol.
- Corrole sameAs コロール_(化学).
- Corrole sameAs m.06hj03.
- Corrole sameAs Коррол.
- Corrole sameAs Q1752388.
- Corrole wasDerivedFrom Corrole?oldid=696048339.
- Corrole depiction Corrole_revisedII.png.
- Corrole isPrimaryTopicOf Corrole.