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- Cope_reaction abstract "The Cope reaction or Cope elimination, developed by Arthur C. Cope, is an elimination reaction of the N-oxide of a tertiary amine to form an alkene and a hydroxylamine. The reaction mechanism involves an intramolecular 5-membered cyclic transition state, leading to a syn elimination product, an Ei pathway. This organic reaction gives the same result as the Hofmann elimination, but the base is a part of the leaving group. The amine oxide is prepared by oxidation of the corresponding amine with an oxidant such as mCPBA. The actual elimination just requires heat.An application is a synthesis of methylenecyclohexane:synthesis of methylenecyclohexanePiperidines are resistant to an intramolecular Cope reaction but with pyrrolidine and with rings of size 7 and larger, the reaction product is an unsaturated hydroxyl amine. This result is consistent with the 5-membered cyclic transition state. intramolecular Cope reaction↑ ↑ ↑ ↑".
- Cope_reaction thumbnail CopeReaction.png?width=300.
- Cope_reaction wikiPageID "1125476".
- Cope_reaction wikiPageLength "2286".
- Cope_reaction wikiPageOutDegree "27".
- Cope_reaction wikiPageRevisionID "651927355".
- Cope_reaction wikiPageWikiLink Alkene.
- Cope_reaction wikiPageWikiLink Amine.
- Cope_reaction wikiPageWikiLink Amine_oxide.
- Cope_reaction wikiPageWikiLink Arthur_C._Cope.
- Cope_reaction wikiPageWikiLink Base_(chemistry).
- Cope_reaction wikiPageWikiLink Category:Elimination_reactions.
- Cope_reaction wikiPageWikiLink Category:Name_reactions.
- Cope_reaction wikiPageWikiLink Ei_mechanism.
- Cope_reaction wikiPageWikiLink Elimination_reaction.
- Cope_reaction wikiPageWikiLink Hofmann_elimination.
- Cope_reaction wikiPageWikiLink Hydroxylamine.
- Cope_reaction wikiPageWikiLink Intramolecular_reaction.
- Cope_reaction wikiPageWikiLink Leaving_group.
- Cope_reaction wikiPageWikiLink Meta-Chloroperoxybenzoic_acid.
- Cope_reaction wikiPageWikiLink Methylenecyclohexane.
- Cope_reaction wikiPageWikiLink Organic_reaction.
- Cope_reaction wikiPageWikiLink Organic_redox_reaction.
- Cope_reaction wikiPageWikiLink Piperidine.
- Cope_reaction wikiPageWikiLink Pyrrolidine.
- Cope_reaction wikiPageWikiLink Saturation_(chemistry).
- Cope_reaction wikiPageWikiLink Syn_and_anti_addition.
- Cope_reaction wikiPageWikiLink Transition_state.
- Cope_reaction wikiPageWikiLink File:CopeReaction.png.
- Cope_reaction wikiPageWikiLink File:CopeReactionJACS82-4656.svg.
- Cope_reaction wikiPageWikiLink File:MethyleneCyclohexaneByCopeReaction.svg.
- Cope_reaction wikiPageWikiLinkText "Cope elimination".
- Cope_reaction wikiPageWikiLinkText "Cope reaction".
- Cope_reaction wikiPageWikiLinkText "Cope".
- Cope_reaction wikiPageUsesTemplate Template:Clear-left.
- Cope_reaction wikiPageUsesTemplate Template:Distinguish.
- Cope_reaction wikiPageUsesTemplate Template:Ref.
- Cope_reaction wikiPageUsesTemplate Template:Reflist.
- Cope_reaction subject Category:Elimination_reactions.
- Cope_reaction subject Category:Name_reactions.
- Cope_reaction hypernym Reaction.
- Cope_reaction type Disease.
- Cope_reaction type Eponym.
- Cope_reaction type Reaction.
- Cope_reaction type Thing.
- Cope_reaction comment "The Cope reaction or Cope elimination, developed by Arthur C. Cope, is an elimination reaction of the N-oxide of a tertiary amine to form an alkene and a hydroxylamine. The reaction mechanism involves an intramolecular 5-membered cyclic transition state, leading to a syn elimination product, an Ei pathway. This organic reaction gives the same result as the Hofmann elimination, but the base is a part of the leaving group.".
- Cope_reaction label "Cope reaction".
- Cope_reaction differentFrom Cope_rearrangement.
- Cope_reaction sameAs Q900370.
- Cope_reaction sameAs Cope-Eliminierung.
- Cope_reaction sameAs Réaction_de_Cope.
- Cope_reaction sameAs Reazione_di_Cope.
- Cope_reaction sameAs コープ脱離.
- Cope_reaction sameAs Cope-eliminatie.
- Cope_reaction sameAs m.048fm1.
- Cope_reaction sameAs Элиминирование_по_Коупу.
- Cope_reaction sameAs Q900370.
- Cope_reaction sameAs 柯普消除反应.
- Cope_reaction wasDerivedFrom Cope_reaction?oldid=651927355.
- Cope_reaction depiction CopeReaction.png.
- Cope_reaction isPrimaryTopicOf Cope_reaction.