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- Biomimetic_synthesis abstract "Biomimetic synthesis is an area of organic chemical synthesis that is specifically biologically inspired, so-named in 1917 by the English organic chemist and Nobel laureate Sir Robert Robinson. The term encompasses both the testing of a \"biogenetic hypothesis\" (conjectured course of a biosynthesis in nature) through execution of a series of reactions designed to parallel the proposed biosynthesis, as well as programs of study where a synthetic reaction or reactions aimed at a desired synthetic goal are designed to mimic a one or more known enzymic transformations of an established biosynthetic pathway. The earliest generally cited example of a biomimetic synthesis is Robinson's organic synthesis of the alkaloid tropinone.500pxA more recent example is E.J. Corey's carbenium-mediated cyclization of an engineered linear polyene to provide a tetracyclic steroid ring system, which built upon studies of cationic cyclizations of linear polyenes by the Albert Eschenmoser and Gilbert Stork, and the extensive studies of the W.S. Johnson to define the requirements to initiate and terminate the cyclization, and to stabilize the cationic carbenium group during the cyclization (as nature accomplishes via enzymes during biosynthesis of steroids such as cholesterol). In relation to the second definition, synthetic organic or inorganic catalysts applied to accomplish a chemical transformation accomplished in nature by a biocatalyst (e.g., a purely proteinaceous catalyst, a metal or other cofactor bound to an enzyme, or a ribozyme) can be said to be accomplishing a biomimetic synthesis, where design and characterization of such catalytic systems has been termed biomimetic chemistry.".
- Biomimetic_synthesis thumbnail Robinson_tropinone_synthesis.png?width=300.
- Biomimetic_synthesis wikiPageExternalLink 2004_Ashley.pdf.
- Biomimetic_synthesis wikiPageExternalLink 192320090788112.
- Biomimetic_synthesis wikiPageID "41175952".
- Biomimetic_synthesis wikiPageLength "9657".
- Biomimetic_synthesis wikiPageOutDegree "47".
- Biomimetic_synthesis wikiPageRevisionID "692646119".
- Biomimetic_synthesis wikiPageWikiLink Acetic_acid.
- Biomimetic_synthesis wikiPageWikiLink Albert_Eschenmoser.
- Biomimetic_synthesis wikiPageWikiLink Alkaloid.
- Biomimetic_synthesis wikiPageWikiLink Ammonia.
- Biomimetic_synthesis wikiPageWikiLink Biosynthesis.
- Biomimetic_synthesis wikiPageWikiLink Carpanone.
- Biomimetic_synthesis wikiPageWikiLink Catalysis.
- Biomimetic_synthesis wikiPageWikiLink Category:Chemical_synthesis.
- Biomimetic_synthesis wikiPageWikiLink Chemical_synthesis.
- Biomimetic_synthesis wikiPageWikiLink Cholesterol.
- Biomimetic_synthesis wikiPageWikiLink Clayton_Heathcock.
- Biomimetic_synthesis wikiPageWikiLink Cofactor_(biochemistry).
- Biomimetic_synthesis wikiPageWikiLink Daphniphyllum.
- Biomimetic_synthesis wikiPageWikiLink Daphniphyllum_macropodum.
- Biomimetic_synthesis wikiPageWikiLink Diels–Alder_reaction.
- Biomimetic_synthesis wikiPageWikiLink Elias_James_Corey.
- Biomimetic_synthesis wikiPageWikiLink Endiandric_acid_C.
- Biomimetic_synthesis wikiPageWikiLink Enzyme.
- Biomimetic_synthesis wikiPageWikiLink Gilbert_Stork.
- Biomimetic_synthesis wikiPageWikiLink Inorganic_compound.
- Biomimetic_synthesis wikiPageWikiLink Metabolism.
- Biomimetic_synthesis wikiPageWikiLink Metalloprotein.
- Biomimetic_synthesis wikiPageWikiLink Molecule.
- Biomimetic_synthesis wikiPageWikiLink Natural_product.
- Biomimetic_synthesis wikiPageWikiLink Organic_synthesis.
- Biomimetic_synthesis wikiPageWikiLink Organocatalysis.
- Biomimetic_synthesis wikiPageWikiLink Polyene.
- Biomimetic_synthesis wikiPageWikiLink Potassium_hydroxide.
- Biomimetic_synthesis wikiPageWikiLink Ribozyme.
- Biomimetic_synthesis wikiPageWikiLink Robert_Robinson_(organic_chemist).
- Biomimetic_synthesis wikiPageWikiLink Spirotryprostatin_B.
- Biomimetic_synthesis wikiPageWikiLink Squalene.
- Biomimetic_synthesis wikiPageWikiLink Steroid.
- Biomimetic_synthesis wikiPageWikiLink Tropinone.
- Biomimetic_synthesis wikiPageWikiLink William_Summer_Johnson.
- Biomimetic_synthesis wikiPageWikiLink File:(a)_Key_precursors_A_and_B_for_the_synthesis_of_proto-daphniphylline._(b)_Mechanisms_for_converting_dialdehyde_A_to_proto-daphniphylline..png.
- Biomimetic_synthesis wikiPageWikiLink File:Proto-Daphniphylline_is_biosynthesized_from_squalene.png.
- Biomimetic_synthesis wikiPageWikiLink File:Robinson_tropinone_synthesis.png.
- Biomimetic_synthesis wikiPageWikiLinkText "Biomimetic synthesis".
- Biomimetic_synthesis wikiPageWikiLinkText "biomimetic chemical synthesis".
- Biomimetic_synthesis wikiPageWikiLinkText "biomimetic strategy".
- Biomimetic_synthesis wikiPageWikiLinkText "biomimetic synthesis".
- Biomimetic_synthesis wikiPageWikiLinkText "biomimetic".
- Biomimetic_synthesis wikiPageWikiLinkText "biomimetically".
- Biomimetic_synthesis wikiPageWikiLinkText "mimic".
- Biomimetic_synthesis wikiPageWikiLinkText "mimicking".
- Biomimetic_synthesis wikiPageUsesTemplate Template:Chemical_synthesis.
- Biomimetic_synthesis wikiPageUsesTemplate Template:Chemistry-stub.
- Biomimetic_synthesis wikiPageUsesTemplate Template:Cite_book.
- Biomimetic_synthesis wikiPageUsesTemplate Template:Cite_web.
- Biomimetic_synthesis wikiPageUsesTemplate Template:Reflist.
- Biomimetic_synthesis subject Category:Chemical_synthesis.
- Biomimetic_synthesis hypernym Area.
- Biomimetic_synthesis type Place.
- Biomimetic_synthesis comment "Biomimetic synthesis is an area of organic chemical synthesis that is specifically biologically inspired, so-named in 1917 by the English organic chemist and Nobel laureate Sir Robert Robinson.".
- Biomimetic_synthesis label "Biomimetic synthesis".
- Biomimetic_synthesis sameAs Q16842168.
- Biomimetic_synthesis sameAs m.0zg9dd8.
- Biomimetic_synthesis sameAs Q16842168.
- Biomimetic_synthesis wasDerivedFrom Biomimetic_synthesis?oldid=692646119.
- Biomimetic_synthesis depiction Robinson_tropinone_synthesis.png.
- Biomimetic_synthesis isPrimaryTopicOf Biomimetic_synthesis.