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- Aurophilicity abstract "In chemistry, aurophilicity refers to the tendency of gold complexes to aggregate via formation of weak gold-gold bonds.The main evidence for aurophilicity is from the crystallographic analysis of Au(I) complexes. The aurophilic bond is assigned a length of about 3.0 Å and a strength of about 7–12 kcal/mol, which is comparable to the strength of a hydrogen bond. The aurophilic interaction is thought to result from electron correlation of the closed-shell components, which is unusual because closed-shell atoms generally have negligible interaction with one another at distances on the scale of the Au-Au bond. This is somewhat similar to van der Waals interactions, but is unusually strong due to relativistic effects. Observations and theory show that, on average, 28% of the binding energy in aurophilic interaction can be attributed to relativistic expansion of the gold d orbitals.An example of aurophilicity is the propensity of gold centres to aggregate. While both intra- and inter-molecular aurophilic interactions have been observed, only intramolecular aggregation has been observed at such nucleation sites.".
- Aurophilicity thumbnail P-steric.jpg?width=300.
- Aurophilicity wikiPageID "7219559".
- Aurophilicity wikiPageLength "6387".
- Aurophilicity wikiPageOutDegree "19".
- Aurophilicity wikiPageRevisionID "680266123".
- Aurophilicity wikiPageWikiLink Calorie.
- Aurophilicity wikiPageWikiLink Category:Chemical_bonding.
- Aurophilicity wikiPageWikiLink Category:Gold.
- Aurophilicity wikiPageWikiLink Chemistry.
- Aurophilicity wikiPageWikiLink Coordination_complex.
- Aurophilicity wikiPageWikiLink Crystallography.
- Aurophilicity wikiPageWikiLink Electron_configuration.
- Aurophilicity wikiPageWikiLink Electron_shell.
- Aurophilicity wikiPageWikiLink Electronic_correlation.
- Aurophilicity wikiPageWikiLink Gold.
- Aurophilicity wikiPageWikiLink Hydrogen.
- Aurophilicity wikiPageWikiLink Hydrogen_bond.
- Aurophilicity wikiPageWikiLink Polymer.
- Aurophilicity wikiPageWikiLink Relativistic_quantum_chemistry.
- Aurophilicity wikiPageWikiLink Solvent.
- Aurophilicity wikiPageWikiLink Van_der_Waals_force.
- Aurophilicity wikiPageWikiLink Ångström.
- Aurophilicity wikiPageWikiLink File:Au-poly1.jpg.
- Aurophilicity wikiPageWikiLink File:P-steric.jpg.
- Aurophilicity wikiPageWikiLinkText "Aurophilicity".
- Aurophilicity wikiPageWikiLinkText "aurophilic bonding".
- Aurophilicity wikiPageWikiLinkText "aurophilicity".
- Aurophilicity wikiPageUsesTemplate Template:Chemical_bonds.
- Aurophilicity wikiPageUsesTemplate Template:Reflist.
- Aurophilicity subject Category:Chemical_bonding.
- Aurophilicity subject Category:Gold.
- Aurophilicity type Element.
- Aurophilicity comment "In chemistry, aurophilicity refers to the tendency of gold complexes to aggregate via formation of weak gold-gold bonds.The main evidence for aurophilicity is from the crystallographic analysis of Au(I) complexes. The aurophilic bond is assigned a length of about 3.0 Å and a strength of about 7–12 kcal/mol, which is comparable to the strength of a hydrogen bond.".
- Aurophilicity label "Aurophilicity".
- Aurophilicity sameAs Q4822439.
- Aurophilicity sameAs Aurophilie.
- Aurophilicity sameAs Aurofilicidad.
- Aurophilicity sameAs 친금성.
- Aurophilicity sameAs Aurofilicidade.
- Aurophilicity sameAs m.025wj1c.
- Aurophilicity sameAs Zlatofilnost.
- Aurophilicity sameAs Zlatofilnost.
- Aurophilicity sameAs Q4822439.
- Aurophilicity sameAs 亲金作用.
- Aurophilicity wasDerivedFrom Aurophilicity?oldid=680266123.
- Aurophilicity depiction P-steric.jpg.
- Aurophilicity isPrimaryTopicOf Aurophilicity.