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- Allylic_strain abstract "Allylic strain (also known as A1,3 strain, 1,3-allylic strain, or A-strain) in organic chemistry is a type of strain energy resulting from the interaction between a substituent on one end of an olefin with an allylic substituent on the other end. If the substituents (R and R') are large enough in size, they can sterically interfere with each other such that one conformer is greatly favored over the other. Allyic strain was first recognized in the literature in 1965 by Johnson and Malhotra. The authors were investigating cyclohexane conformations including endocyclic and exocylic double bonds when they noticed certain conformations were disfavored due to the geometry constraints caused by the double bond. Organic chemists capitalize on the rigidity resulting from allylic strain for use in asymmetric reactions.".
- Allylic_strain thumbnail Generic_allylic_strain.png?width=300.
- Allylic_strain wikiPageID "8005697".
- Allylic_strain wikiPageLength "21276".
- Allylic_strain wikiPageOutDegree "35".
- Allylic_strain wikiPageRevisionID "695108724".
- Allylic_strain wikiPageWikiLink A_value.
- Allylic_strain wikiPageWikiLink Alkene.
- Allylic_strain wikiPageWikiLink Carboxylic_acid.
- Allylic_strain wikiPageWikiLink Category:Stereochemistry.
- Allylic_strain wikiPageWikiLink Chemical_polarity.
- Allylic_strain wikiPageWikiLink Cis–trans_isomerism.
- Allylic_strain wikiPageWikiLink Conformational_isomerism.
- Allylic_strain wikiPageWikiLink Conjugated_system.
- Allylic_strain wikiPageWikiLink Cyclohexane_conformation.
- Allylic_strain wikiPageWikiLink Ether.
- Allylic_strain wikiPageWikiLink LUMO.
- Allylic_strain wikiPageWikiLink Hydrogen_bond.
- Allylic_strain wikiPageWikiLink Hydroxyl.
- Allylic_strain wikiPageWikiLink Keto–enol_tautomerism.
- Allylic_strain wikiPageWikiLink Organic_chemistry.
- Allylic_strain wikiPageWikiLink Protonation.
- Allylic_strain wikiPageWikiLink Sigma_bond.
- Allylic_strain wikiPageWikiLink Strain_energy.
- Allylic_strain wikiPageWikiLink Van_der_Waals_force.
- Allylic_strain wikiPageWikiLink File:1-butene_allylic_strain.png.
- Allylic_strain wikiPageWikiLink File:Aldol6.png.
- Allylic_strain wikiPageWikiLink File:Aldol7.png.
- Allylic_strain wikiPageWikiLink File:Allylic_strain_acid_catalysis.png.
- Allylic_strain wikiPageWikiLink File:Allylic_strain_and_conjugation.png.
- Allylic_strain wikiPageWikiLink File:Allylic_strain_and_hydrogen_bonding.png.
- Allylic_strain wikiPageWikiLink File:DielsAlder.png.
- Allylic_strain wikiPageWikiLink File:DielsAlder3.png.
- Allylic_strain wikiPageWikiLink File:Generic_allylic_strain.png.
- Allylic_strain wikiPageWikiLink File:Hydroboration_2.png.
- Allylic_strain wikiPageWikiLink File:Methylenecyclohexane_strain.png.
- Allylic_strain wikiPageWikiLink File:Monensin.png.
- Allylic_strain wikiPageWikiLink File:Napthalene_phenanthraene_methyl-methyl_strain.png.
- Allylic_strain wikiPageWikiLink File:Origin.png.
- Allylic_strain wikiPageWikiLink File:Substituent_size_and_allylic_strain.png.
- Allylic_strain wikiPageWikiLinkText "A(1,3) strain".
- Allylic_strain wikiPageWikiLinkText "Allylic strain".
- Allylic_strain wikiPageWikiLinkText "allylic 1,3-strain".
- Allylic_strain wikiPageWikiLinkText "allylic strain".
- Allylic_strain wikiPageUsesTemplate Template:Reflist.
- Allylic_strain wikiPageUsesTemplate Template:Verify_source.
- Allylic_strain subject Category:Stereochemistry.
- Allylic_strain hypernym Energy.
- Allylic_strain type Company.
- Allylic_strain comment "Allylic strain (also known as A1,3 strain, 1,3-allylic strain, or A-strain) in organic chemistry is a type of strain energy resulting from the interaction between a substituent on one end of an olefin with an allylic substituent on the other end. If the substituents (R and R') are large enough in size, they can sterically interfere with each other such that one conformer is greatly favored over the other. Allyic strain was first recognized in the literature in 1965 by Johnson and Malhotra.".
- Allylic_strain label "Allylic strain".
- Allylic_strain sameAs Q901195.
- Allylic_strain sameAs Allylspannung.
- Allylic_strain sameAs Tensión_alílica.
- Allylic_strain sameAs Terikan_alilik.
- Allylic_strain sameAs アリル歪み.
- Allylic_strain sameAs m.026n8f2.
- Allylic_strain sameAs Q901195.
- Allylic_strain sameAs 烯丙位张力.
- Allylic_strain wasDerivedFrom Allylic_strain?oldid=695108724.
- Allylic_strain depiction Generic_allylic_strain.png.
- Allylic_strain isPrimaryTopicOf Allylic_strain.