Matches in DBpedia 2015-10 for { <http://dbpedia.org/resource/Tsuji–Trost_reaction> ?p ?o }
- Tsuji–Trost_reaction abstract "The Tsuji–Trost reaction (also called the Trost allylic alkylation or allylic alkylation) is a palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This complex can then be attacked by a nucleophile, resulting in the substituted product.This work was first pioneered by Jiro Tsuji in 1965 and, later, adapted by Barry Trost in 1973 with the introduction of phosphine ligands. The scope of this reaction has been expanded to many different carbon, nitrogen, and oxygen-based nucleophiles, many different leaving groups, many different phosphorus, nitrogen, and sulfur-based ligands, and many different metals (although palladium is still preferred).The introduction of phosphine ligands led to improved reactivity and numerous asymmetric allylic alkylation strategies. Many of these strategies are driven by the advent of chiral ligands, which are often able to provide high enantioselectivity and high diastereoselectivity under mild conditions. This modification greatly expands the utility of this reaction for many different synthetic applications. The ability to form carbon-carbon, carbon-nitrogen, and carbon-oxygen bonds under these conditions, makes this reaction very appealing to the fields of both medicinal chemistry and natural product synthesis.".
- Tsuji–Trost_reaction thumbnail Tsuji-Trost_allylation.svg?width=300.
- Tsuji–Trost_reaction wikiPageExternalLink CV8P0009.pdf.
- Tsuji–Trost_reaction wikiPageExternalLink v86p0047.pdf.
- Tsuji–Trost_reaction wikiPageExternalLink concise_total_synthesis_of_Minfiensine.pdf.
- Tsuji–Trost_reaction wikiPageExternalLink spip.php?article332.
- Tsuji–Trost_reaction wikiPageID "31370522".
- Tsuji–Trost_reaction wikiPageLength "19515".
- Tsuji–Trost_reaction wikiPageOutDegree "99".
- Tsuji–Trost_reaction wikiPageRevisionID "646126653".
- Tsuji–Trost_reaction wikiPageWikiLink Achiral.
- Tsuji–Trost_reaction wikiPageWikiLink Acid_dissociation_constant.
- Tsuji–Trost_reaction wikiPageWikiLink Alkene.
- Tsuji–Trost_reaction wikiPageWikiLink Alkenes.
- Tsuji–Trost_reaction wikiPageWikiLink Alkoxide.
- Tsuji–Trost_reaction wikiPageWikiLink Alkoxides.
- Tsuji–Trost_reaction wikiPageWikiLink Alkylate.
- Tsuji–Trost_reaction wikiPageWikiLink Alkylation.
- Tsuji–Trost_reaction wikiPageWikiLink Allene.
- Tsuji–Trost_reaction wikiPageWikiLink Allyl.
- Tsuji–Trost_reaction wikiPageWikiLink Allylic.
- Tsuji–Trost_reaction wikiPageWikiLink Amine.
- Tsuji–Trost_reaction wikiPageWikiLink Amines.
- Tsuji–Trost_reaction wikiPageWikiLink Axial_chirality.
- Tsuji–Trost_reaction wikiPageWikiLink Azide.
- Tsuji–Trost_reaction wikiPageWikiLink Azides.
- Tsuji–Trost_reaction wikiPageWikiLink Barry_Trost.
- Tsuji–Trost_reaction wikiPageWikiLink Carbonate.
- Tsuji–Trost_reaction wikiPageWikiLink Carbonates.
- Tsuji–Trost_reaction wikiPageWikiLink Carbonyl.
- Tsuji–Trost_reaction wikiPageWikiLink Carboxylate.
- Tsuji–Trost_reaction wikiPageWikiLink Carboxylates.
- Tsuji–Trost_reaction wikiPageWikiLink Catalysed.
- Tsuji–Trost_reaction wikiPageWikiLink Catalysis.
- Tsuji–Trost_reaction wikiPageWikiLink Catalytic_cycle.
- Tsuji–Trost_reaction wikiPageWikiLink Category:Name_reactions.
- Tsuji–Trost_reaction wikiPageWikiLink Category:Organic_reactions.
- Tsuji–Trost_reaction wikiPageWikiLink Category:Palladium.
- Tsuji–Trost_reaction wikiPageWikiLink Category:Substitution_reactions.
- Tsuji–Trost_reaction wikiPageWikiLink Cell_(biology).
- Tsuji–Trost_reaction wikiPageWikiLink Chemical_yield.
- Tsuji–Trost_reaction wikiPageWikiLink Chiral.
- Tsuji–Trost_reaction wikiPageWikiLink Chirality.
- Tsuji–Trost_reaction wikiPageWikiLink Conjugate_acid.
- Tsuji–Trost_reaction wikiPageWikiLink Deprotonation.
- Tsuji–Trost_reaction wikiPageWikiLink Dewar–Chatt–Duncanson_model.
- Tsuji–Trost_reaction wikiPageWikiLink Diastereomer.
- Tsuji–Trost_reaction wikiPageWikiLink Diastereoselectivity.
- Tsuji–Trost_reaction wikiPageWikiLink Dichloromethane.
- Tsuji–Trost_reaction wikiPageWikiLink Diethyl_malonate.
- Tsuji–Trost_reaction wikiPageWikiLink Dimer_(chemistry).
- Tsuji–Trost_reaction wikiPageWikiLink Drug.
- Tsuji–Trost_reaction wikiPageWikiLink Enantiomer.
- Tsuji–Trost_reaction wikiPageWikiLink Enantiomeric_excess.
- Tsuji–Trost_reaction wikiPageWikiLink Enantioselective_synthesis.
- Tsuji–Trost_reaction wikiPageWikiLink Enantioselectivity.
- Tsuji–Trost_reaction wikiPageWikiLink Enol.
- Tsuji–Trost_reaction wikiPageWikiLink Enolates.
- Tsuji–Trost_reaction wikiPageWikiLink Fluorescein.
- Tsuji–Trost_reaction wikiPageWikiLink Fluorescence.
- Tsuji–Trost_reaction wikiPageWikiLink Fluorescent.
- Tsuji–Trost_reaction wikiPageWikiLink Galantamine_total_synthesis.
- Tsuji–Trost_reaction wikiPageWikiLink Galanthamine_total_synthesis.
- Tsuji–Trost_reaction wikiPageWikiLink Halide.
- Tsuji–Trost_reaction wikiPageWikiLink Halides.
- Tsuji–Trost_reaction wikiPageWikiLink Hapticity.
- Tsuji–Trost_reaction wikiPageWikiLink High-throughput_screening.
- Tsuji–Trost_reaction wikiPageWikiLink Hydroxide.
- Tsuji–Trost_reaction wikiPageWikiLink Imide.
- Tsuji–Trost_reaction wikiPageWikiLink Imides.
- Tsuji–Trost_reaction wikiPageWikiLink In_situ.
- Tsuji–Trost_reaction wikiPageWikiLink Inversion_of_configuration.
- Tsuji–Trost_reaction wikiPageWikiLink Jiro_Tsuji.
- Tsuji–Trost_reaction wikiPageWikiLink Leaving_group.
- Tsuji–Trost_reaction wikiPageWikiLink Lewis_acids.
- Tsuji–Trost_reaction wikiPageWikiLink Lewis_acids_and_bases.
- Tsuji–Trost_reaction wikiPageWikiLink Ligand.
- Tsuji–Trost_reaction wikiPageWikiLink Ligands.
- Tsuji–Trost_reaction wikiPageWikiLink Living_cells.
- Tsuji–Trost_reaction wikiPageWikiLink Malonate.
- Tsuji–Trost_reaction wikiPageWikiLink Malonates.
- Tsuji–Trost_reaction wikiPageWikiLink Mole_Percentage.
- Tsuji–Trost_reaction wikiPageWikiLink Mole_fraction.
- Tsuji–Trost_reaction wikiPageWikiLink Morphine.
- Tsuji–Trost_reaction wikiPageWikiLink Nucleophile.
- Tsuji–Trost_reaction wikiPageWikiLink Ore.
- Tsuji–Trost_reaction wikiPageWikiLink Oxidation_state.
- Tsuji–Trost_reaction wikiPageWikiLink Oxidative_addition.
- Tsuji–Trost_reaction wikiPageWikiLink Palladium.
- Tsuji–Trost_reaction wikiPageWikiLink Palladium-catalyzed_coupling_reactions.
- Tsuji–Trost_reaction wikiPageWikiLink Palladium-catalyzed_reactions.
- Tsuji–Trost_reaction wikiPageWikiLink Pharmaceutical_products.
- Tsuji–Trost_reaction wikiPageWikiLink Phenols.
- Tsuji–Trost_reaction wikiPageWikiLink Phenoxides.
- Tsuji–Trost_reaction wikiPageWikiLink Phosphate.
- Tsuji–Trost_reaction wikiPageWikiLink Phosphates.
- Tsuji–Trost_reaction wikiPageWikiLink Phosphine.
- Tsuji–Trost_reaction wikiPageWikiLink Phosphinooxazolines.
- Tsuji–Trost_reaction wikiPageWikiLink Planar_chirality.
- Tsuji–Trost_reaction wikiPageWikiLink Reaction_intermediate.