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- Total_synthesis_of_morphine_and_related_alkaloids abstract "Synthesis of morphine-like alkaloids in chemistry describes the total synthesis of the natural morphinan class of alkaloids that includes codeine, morphine, oripavine, and thebaine and the closely related semisynthetic analogs buprenorphine, hydrocodone, isocodeine, naltrexone, naloxone, nalbuphine, and oxycodone.The structure of morphine is not particularly complex, however the electrostatic polarization of adjacent bonded atoms does not alternate uniformly throughout the structure. This "dissonant connectivity" makes bond formation more difficult and therefore significantly complicates any synthetic strategy that is applied to this family of molecules.The first morphine total synthesis, devised by Marshall D. Gates, Jr. in 1952 remains a widely used example of total synthesis. This synthesis took a total of 31 steps and proceeded in 0.06% over all yield. The dihydrocodeinone synthesis of Kenner C. Rice is one of the most efficient and proceeds in 30% overall yield in 14 steps.Several other syntheses were reported, notably by the research groups of Evans, Fuchs, Parker, Overman, Mulzer-Trauner, White, Taber, Trost, Fukuyama, Guillou, Stork, and Magnus.".
- Total_synthesis_of_morphine_and_related_alkaloids thumbnail Morphin_-_Morphine.svg?width=300.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageExternalLink gm-2006-01n31.pdf.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageExternalLink morphine.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageID "32519980".
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageLength "8402".
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageOutDegree "33".
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageRevisionID "676943386".
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Barry_Trost.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Biomimetic_synthesis.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Buprenorphine.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Category:Natural_opium_alkaloids.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Category:Total_synthesis.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Chemistry.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Codeine.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink David_A._Evans.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Diels-Alder_reaction.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Diels–Alder_reaction.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Dihydrocodeinone.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Gilbert_Stork.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Hydrocodone.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Isocodeine.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Johann_Mulzer.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Larry_E._Overman.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Marshall_D._Gates,_Jr..
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Morphinan.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Morphine.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Nalbuphine.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Naloxone.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Naltrexone.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Oripavine.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Oxycodone.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Reticuline.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Robert_Robinson_(organic_chemist).
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Semisynthesis.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Semisynthetic.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Thebaine.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Tohru_Fukuyama.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink Total_synthesis.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink File:Gates_synthesis.png.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink File:Kenner_Rice_morphine_synthesis.svg.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLink File:Morphin_-_Morphine.svg.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageWikiLinkText "Total synthesis of morphine and related alkaloids".
- Total_synthesis_of_morphine_and_related_alkaloids hasPhotoCollection Total_synthesis_of_morphine_and_related_alkaloids.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageUsesTemplate Template:Cite_web.
- Total_synthesis_of_morphine_and_related_alkaloids wikiPageUsesTemplate Template:Reflist.
- Total_synthesis_of_morphine_and_related_alkaloids subject Category:Natural_opium_alkaloids.
- Total_synthesis_of_morphine_and_related_alkaloids subject Category:Total_synthesis.
- Total_synthesis_of_morphine_and_related_alkaloids comment "Synthesis of morphine-like alkaloids in chemistry describes the total synthesis of the natural morphinan class of alkaloids that includes codeine, morphine, oripavine, and thebaine and the closely related semisynthetic analogs buprenorphine, hydrocodone, isocodeine, naltrexone, naloxone, nalbuphine, and oxycodone.The structure of morphine is not particularly complex, however the electrostatic polarization of adjacent bonded atoms does not alternate uniformly throughout the structure.".
- Total_synthesis_of_morphine_and_related_alkaloids label "Total synthesis of morphine and related alkaloids".
- Total_synthesis_of_morphine_and_related_alkaloids sameAs m.0h1hxbk.
- Total_synthesis_of_morphine_and_related_alkaloids sameAs Q10918457.
- Total_synthesis_of_morphine_and_related_alkaloids sameAs Q10918457.
- Total_synthesis_of_morphine_and_related_alkaloids sameAs 吗啡全合成.
- Total_synthesis_of_morphine_and_related_alkaloids wasDerivedFrom Total_synthesis_of_morphine_and_related_alkaloids?oldid=676943386.
- Total_synthesis_of_morphine_and_related_alkaloids depiction Morphin_-_Morphine.svg.
- Total_synthesis_of_morphine_and_related_alkaloids isPrimaryTopicOf Total_synthesis_of_morphine_and_related_alkaloids.