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- T-shaped_molecular_geometry abstract "In chemistry, T-shaped molecular geometry describes the structures of some molecules where a central atom has three ligands. Ordinarily, three-coordinated compounds adopt trigonal planar or pyramidal geometries. Examples of T-shaped molecules are the halogen trifluorides, such as ClF3.According to VSEPR theory, T-shaped geometry results when three ligands and two lone pairs of electrons are bonded to the central atom, written in AXE notation as AX3E2. The T-shaped geometry is related to the trigonal bipyramidal molecular geometry for AX5 molecules with three equatorial and two axial ligands. In an AX3E2 molecule, the two lone pairs occupy two equatorial positions, and the three ligand atoms occupy the two axial positions as well as one equatorial position. The three atoms bond at 90° angles on one side of the central atom, producing the T shape.The trifluoroxenate (II) anion, XeF3-, has been investigated as a possible first example of an AX3E3 molecule, which might be expected by VSEPR reasoning to have six electron pairs in an octahedral arrangement with both the three lone pairs and the three ligands in a mer or T-shaped orientations. Although this anion has been detected in the gas phase, attempts at synthesis in solution and experimental structure determination were unsuccessful. A computational chemistry study showed a distorted planar Y-shaped geometry with the smallest F-Xe-F bond angle equal to 69°, rather than 90° as in a T-shaped geometry.".
- T-shaped_molecular_geometry thumbnail T-shaped-3D-balls.png?width=300.
- T-shaped_molecular_geometry wikiPageExternalLink MolecularModeling1.htm.
- T-shaped_molecular_geometry wikiPageExternalLink 3BP.html.
- T-shaped_molecular_geometry wikiPageExternalLink 3D.
- T-shaped_molecular_geometry wikiPageExternalLink IUMSC.
- T-shaped_molecular_geometry wikiPageExternalLink Molecules_l3d.html.
- T-shaped_molecular_geometry wikiPageID "15296985".
- T-shaped_molecular_geometry wikiPageLength "3124".
- T-shaped_molecular_geometry wikiPageOutDegree "14".
- T-shaped_molecular_geometry wikiPageRevisionID "677367119".
- T-shaped_molecular_geometry wikiPageWikiLink AXE_method.
- T-shaped_molecular_geometry wikiPageWikiLink Category:Molecular_geometry.
- T-shaped_molecular_geometry wikiPageWikiLink Chlorine_trifluoride.
- T-shaped_molecular_geometry wikiPageWikiLink ClF3.
- T-shaped_molecular_geometry wikiPageWikiLink Computational_chemistry.
- T-shaped_molecular_geometry wikiPageWikiLink Coordination_complex.
- T-shaped_molecular_geometry wikiPageWikiLink Ligand.
- T-shaped_molecular_geometry wikiPageWikiLink Octahedral_molecular_geometry.
- T-shaped_molecular_geometry wikiPageWikiLink Trigonal_bipyramidal_molecular_geometry.
- T-shaped_molecular_geometry wikiPageWikiLink Trigonal_planar_molecular_geometry.
- T-shaped_molecular_geometry wikiPageWikiLink Trigonal_pyramidal_molecular_geometry.
- T-shaped_molecular_geometry wikiPageWikiLink VSEPR_theory.
- T-shaped_molecular_geometry wikiPageWikiLink File:Chlorine-trifluoride-3D-vdW.png.
- T-shaped_molecular_geometry wikiPageWikiLink File:T-shaped-3D-balls.png.
- T-shaped_molecular_geometry wikiPageWikiLinkText "T shaped intermediate".
- T-shaped_molecular_geometry wikiPageWikiLinkText "T-shaped molecular geometry".
- T-shaped_molecular_geometry wikiPageWikiLinkText "T-shaped".
- T-shaped_molecular_geometry wikiPageWikiLinkText "bent-T-shaped".
- T-shaped_molecular_geometry hasPhotoCollection T-shaped_molecular_geometry.
- T-shaped_molecular_geometry wikiPageUsesTemplate Template:MolecularGeometry.
- T-shaped_molecular_geometry subject Category:Molecular_geometry.
- T-shaped_molecular_geometry comment "In chemistry, T-shaped molecular geometry describes the structures of some molecules where a central atom has three ligands. Ordinarily, three-coordinated compounds adopt trigonal planar or pyramidal geometries. Examples of T-shaped molecules are the halogen trifluorides, such as ClF3.According to VSEPR theory, T-shaped geometry results when three ligands and two lone pairs of electrons are bonded to the central atom, written in AXE notation as AX3E2.".
- T-shaped_molecular_geometry label "T-shaped molecular geometry".
- T-shaped_molecular_geometry sameAs Geometría_molecular_en_forma_de_T.
- T-shaped_molecular_geometry sameAs T字形.
- T-shaped_molecular_geometry sameAs T-vormige_moleculaire_geometrie.
- T-shaped_molecular_geometry sameAs m.03hpfrf.
- T-shaped_molecular_geometry sameAs T-formad_geometri.
- T-shaped_molecular_geometry sameAs Q2668695.
- T-shaped_molecular_geometry sameAs Q2668695.
- T-shaped_molecular_geometry wasDerivedFrom T-shaped_molecular_geometry?oldid=677367119.
- T-shaped_molecular_geometry depiction T-shaped-3D-balls.png.
- T-shaped_molecular_geometry isPrimaryTopicOf T-shaped_molecular_geometry.
