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- Scholl_reaction abstract "The Scholl reaction is a coupling reaction between two arene compounds with the aid of a Lewis acid and a protic acid. It is named after its discoverer, Roland Scholl.In 1910 Scholl reported the synthesis of a quinone and of perylene from naphthalene both with aluminum chloride. Perylene was also synthesised from 1,1’-binaphthalene in 1913. The synthesis of Benzanthrone was reported in 1912.The protic acid in the Scholl reaction is often an impurity in the Lewis Acid and also formed in the course of a Scholl reaction. Reagents are iron(III) chloride in dichloromethane, copper(II) chloride, PIFA and boron trifluoride etherate in dichloromethane, Molybdenum(V) chloride and lead tetraacetate with BF3 in acetonitrile.Given the high reaction temperature and the requirement for strongly acidic catalysts the chemical yield often is low and the method is not a popular one. Intramolecular reactions fare better than the intermolecular ones, for instance in the organic synthesis of 9-phenylfluorene:Or the formation of the pyrene dibenzo-(a.1)-pyrene from the anthracene 1-phenylbenz(a)anthracene (66% yield).One study showed that the reaction lends itself to cascade reactions to form more complex polycyclic aromatic hydrocarbons In certain applications such as triphenylene synthesis this reaction is advocated as an alternative for the Suzuki reaction. A recurring problem is oligomerization of the product which can be prevented by blocking tert-butyl substituents:".
- Scholl_reaction thumbnail Scholl-reactie.png?width=300.
- Scholl_reaction wikiPageID "5533592".
- Scholl_reaction wikiPageLength "5584".
- Scholl_reaction wikiPageOutDegree "47".
- Scholl_reaction wikiPageRevisionID "683211202".
- Scholl_reaction wikiPageWikiLink (Bis(trifluoroacetoxy)iodo)benzene.
- Scholl_reaction wikiPageWikiLink Acetonitrile.
- Scholl_reaction wikiPageWikiLink Acid.
- Scholl_reaction wikiPageWikiLink Activating_group.
- Scholl_reaction wikiPageWikiLink Aluminium_chloride.
- Scholl_reaction wikiPageWikiLink Aluminum_chloride.
- Scholl_reaction wikiPageWikiLink Anthracene.
- Scholl_reaction wikiPageWikiLink Arene_compound.
- Scholl_reaction wikiPageWikiLink Arenium_ion.
- Scholl_reaction wikiPageWikiLink Aromatic_hydrocarbon.
- Scholl_reaction wikiPageWikiLink Benzanthrone.
- Scholl_reaction wikiPageWikiLink Boron_trifluoride.
- Scholl_reaction wikiPageWikiLink Butyl.
- Scholl_reaction wikiPageWikiLink Cascade_reaction.
- Scholl_reaction wikiPageWikiLink Catalysis.
- Scholl_reaction wikiPageWikiLink Catalyst.
- Scholl_reaction wikiPageWikiLink Category:Name_reactions.
- Scholl_reaction wikiPageWikiLink Category:Substitution_reactions.
- Scholl_reaction wikiPageWikiLink Chemical_yield.
- Scholl_reaction wikiPageWikiLink Copper(II)_chloride.
- Scholl_reaction wikiPageWikiLink Coupling_reaction.
- Scholl_reaction wikiPageWikiLink Dichloromethane.
- Scholl_reaction wikiPageWikiLink Electrophilic_aromatic_directing_groups.
- Scholl_reaction wikiPageWikiLink Electrophilic_aromatic_substitution.
- Scholl_reaction wikiPageWikiLink Fluorene.
- Scholl_reaction wikiPageWikiLink Friedel-Crafts_alkylation.
- Scholl_reaction wikiPageWikiLink Friedel–Crafts_reaction.
- Scholl_reaction wikiPageWikiLink Intramolecular.
- Scholl_reaction wikiPageWikiLink Intramolecular_reaction.
- Scholl_reaction wikiPageWikiLink Iron(III)_chloride.
- Scholl_reaction wikiPageWikiLink Lead(IV)_acetate.
- Scholl_reaction wikiPageWikiLink Lead_tetraacetate.
- Scholl_reaction wikiPageWikiLink Lewis_acid.
- Scholl_reaction wikiPageWikiLink Lewis_acids_and_bases.
- Scholl_reaction wikiPageWikiLink Methoxy.
- Scholl_reaction wikiPageWikiLink Molybdenum(V)_chloride.
- Scholl_reaction wikiPageWikiLink Naphthalene.
- Scholl_reaction wikiPageWikiLink Oligomer.
- Scholl_reaction wikiPageWikiLink Oligomerization.
- Scholl_reaction wikiPageWikiLink Organic_synthesis.
- Scholl_reaction wikiPageWikiLink Perylene.
- Scholl_reaction wikiPageWikiLink Phenyliodine_bis(trifluoroacetate).
- Scholl_reaction wikiPageWikiLink Polycyclic_aromatic_hydrocarbon.
- Scholl_reaction wikiPageWikiLink Protic_acid.
- Scholl_reaction wikiPageWikiLink Pyrene.
- Scholl_reaction wikiPageWikiLink Radical_cation.
- Scholl_reaction wikiPageWikiLink Radical_ion.
- Scholl_reaction wikiPageWikiLink Reaction_mechanism.
- Scholl_reaction wikiPageWikiLink Rearomatisation.
- Scholl_reaction wikiPageWikiLink Roland_Scholl.
- Scholl_reaction wikiPageWikiLink Suzuki_reaction.
- Scholl_reaction wikiPageWikiLink Tert-butyl.
- Scholl_reaction wikiPageWikiLink Triphenylene.
- Scholl_reaction wikiPageWikiLink Yield_(chemistry).
- Scholl_reaction wikiPageWikiLink File:Scholl-reactie.png.
- Scholl_reaction wikiPageWikiLink File:SchollReactionParadirectors.png.
- Scholl_reaction wikiPageWikiLink File:SchollreactionBlockingSubstituents.png.
- Scholl_reaction wikiPageWikiLink File:Schollvb.png.
- Scholl_reaction wikiPageWikiLink File:Schollvb2.png.
- Scholl_reaction wikiPageWikiLinkText "Scholl reaction".
- Scholl_reaction hasPhotoCollection Scholl_reaction.
- Scholl_reaction name "Scholl reaction".
- Scholl_reaction namedafter Roland_Scholl.
- Scholl_reaction type "Coupling reaction".
- Scholl_reaction wikiPageUsesTemplate Template:Reactionbox.
- Scholl_reaction wikiPageUsesTemplate Template:Reflist.
- Scholl_reaction subject Category:Name_reactions.
- Scholl_reaction subject Category:Substitution_reactions.
- Scholl_reaction hypernym Reaction.
- Scholl_reaction type Disease.
- Scholl_reaction type Eponym.
- Scholl_reaction type Reaction.
- Scholl_reaction comment "The Scholl reaction is a coupling reaction between two arene compounds with the aid of a Lewis acid and a protic acid. It is named after its discoverer, Roland Scholl.In 1910 Scholl reported the synthesis of a quinone and of perylene from naphthalene both with aluminum chloride. Perylene was also synthesised from 1,1’-binaphthalene in 1913.".
- Scholl_reaction label "Scholl reaction".
- Scholl_reaction sameAs Scholl-Reaktion.
- Scholl_reaction sameAs واکنش_شول.
- Scholl_reaction sameAs Scholl-reactie.
- Scholl_reaction sameAs m.0dr8zb.
- Scholl_reaction sameAs Schollova_reakcija.
- Scholl_reaction sameAs Q2453366.
- Scholl_reaction sameAs Q2453366.
- Scholl_reaction sameAs Scholl反应.
- Scholl_reaction wasDerivedFrom Scholl_reaction?oldid=683211202.
- Scholl_reaction depiction Scholl-reactie.png.
- Scholl_reaction isPrimaryTopicOf Scholl_reaction.