Matches in DBpedia 2015-10 for { <http://dbpedia.org/resource/Sabatier_principle> ?p ?o }
Showing triples 1 to 39 of
39
with 100 triples per page.
- Sabatier_principle abstract "The Sabatier principle is a qualitative concept in chemical catalysis named after the French chemist Paul Sabatier. It states that the interactions between the catalyst and the substrate should be "just right"; that is, neither too strong nor too weak. If the interaction is too weak, the substrate will fail to bind to the catalyst and no reaction will take place. On the other hand, if the interaction is too strong, the catalyst gets blocked by substrate or product that fails to dissociate.The principle can be shown graphically by plotting the reaction rate against a property such as the heat of adsorption of the reactant by the catalyst. Such plots pass through a maximum, looking roughly like a triangle or an inverted parabola, and are called volcano plots because of their shape. Analogous three-dimensional plots can also be built against two different properties, such as the heats of adsorption of the two reactants for a two-component reaction. In that case the plot is generally shown as a contour plot and is called a volcano surface. Volcano plots were introduced by Balandin.The figure on the right shows a volcano plot for the decomposition of formic acid using different transition metals as catalysts. In this case, the heat of formation (ΔHf) of the metal formate salt was used for the x axis because studies showed that the reaction intermediate was a surface formate. For the y axis, the temperature at which the reaction reaches a specific rate was used (the y axis is plotted in reverse to preserve the conventional "volcano" shape). At low values of ΔHf, the reaction is slow (in other words, requires higher temperatures) because the rate of adsorption is slow and rate-limiting. At high values of ΔHf, desorption becomes the rate-limiting step. The maximum rate, which is observed for the platinum group metals in this case, requires intermediate values of ΔHf, with the rate being a combination of the rate of adsorption and the rate of desorption.".
- Sabatier_principle thumbnail Volcano_plot.png?width=300.
- Sabatier_principle wikiPageID "20168390".
- Sabatier_principle wikiPageLength "3598".
- Sabatier_principle wikiPageOutDegree "14".
- Sabatier_principle wikiPageRevisionID "630896280".
- Sabatier_principle wikiPageWikiLink Adsorption.
- Sabatier_principle wikiPageWikiLink Catalysis.
- Sabatier_principle wikiPageWikiLink Category:Catalysis.
- Sabatier_principle wikiPageWikiLink Contour_line.
- Sabatier_principle wikiPageWikiLink Contour_plot.
- Sabatier_principle wikiPageWikiLink Formic_acid.
- Sabatier_principle wikiPageWikiLink Heat_of_adsorption.
- Sabatier_principle wikiPageWikiLink Heat_of_formation.
- Sabatier_principle wikiPageWikiLink Paul_Sabatier_(chemist).
- Sabatier_principle wikiPageWikiLink Platinum_group.
- Sabatier_principle wikiPageWikiLink Rate-determining_step.
- Sabatier_principle wikiPageWikiLink Reaction_intermediate.
- Sabatier_principle wikiPageWikiLink Reaction_rate.
- Sabatier_principle wikiPageWikiLink Standard_enthalpy_of_formation.
- Sabatier_principle wikiPageWikiLink Substrate_(chemistry).
- Sabatier_principle wikiPageWikiLink Transition_metal.
- Sabatier_principle wikiPageWikiLink File:Volcano_plot.png.
- Sabatier_principle wikiPageWikiLinkText "Sabatier principle".
- Sabatier_principle hasPhotoCollection Sabatier_principle.
- Sabatier_principle wikiPageUsesTemplate Template:Reflist.
- Sabatier_principle subject Category:Catalysis.
- Sabatier_principle hypernym Concept.
- Sabatier_principle type Process.
- Sabatier_principle type Reaction.
- Sabatier_principle comment "The Sabatier principle is a qualitative concept in chemical catalysis named after the French chemist Paul Sabatier. It states that the interactions between the catalyst and the substrate should be "just right"; that is, neither too strong nor too weak. If the interaction is too weak, the substrate will fail to bind to the catalyst and no reaction will take place.".
- Sabatier_principle label "Sabatier principle".
- Sabatier_principle sameAs Vulkaanprincipe.
- Sabatier_principle sameAs m.04yfhl4.
- Sabatier_principle sameAs Q2247985.
- Sabatier_principle sameAs Q2247985.
- Sabatier_principle wasDerivedFrom Sabatier_principle?oldid=630896280.
- Sabatier_principle depiction Volcano_plot.png.
- Sabatier_principle isPrimaryTopicOf Sabatier_principle.