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- Renner–Teller_effect abstract "The Renner–Teller effect or Renner effect is an effect due to rovibronic coupling on the electronic spectra of three- (or more) atomic linear molecules in degenerate electronic (Π, Δ, ..., etc.) states.In its original formulation, the Renner–Teller effect was a vibronic coupling between the motions of the electrons and the nuclear vibrations in triatomic linear molecules. The article by R. Renner (1934) was the first that considered dynamic effects that go beyond the Born–Oppenheimer approximation, in which the nuclear and electronic motions in a molecule are uncoupled. This is a good approximation when the electronic energies are well separated. However, in linear molecules many of the electronic states are two-fold degenerate due to C∞v or D∞h symmetry, and the Born–Oppenheimer approximation breaks down. Since the best-known linear triatomic molecule (CO2) is electronically non-degenerate in its ground state, Renner chose the electronically excited two-fold degenerate Π-state of this well-known molecule as a model for his studies. The products of purely electronic and purely nuclear vibrational states served as the zeroth-order (no vibronic coupling) wave functions in Renner's study. The vibronic coupling acts as a perturbation. Because Renner is the only author of the 1934 paper that first described the effect, it was long called the Renner effect. However, as Herzberg's prestigious books refer to it as the Renner–Teller effect (after Edward Teller), it is now more common to use both names.While Renner's theoretical study concerned the linear triatomic molecule CO2, the first actual observation of the Renner–Teller effect was in the electronic absorption spectrum of NH2 and its isotopologue ND2. In 1959 Dressler and Ramsay found that the first electronically excited states of these triatomic molecules have a linear geometry and they observed in these excited states an unusual type of vibronic structure: the Renner–Teller effect. Much has been published about the Renner–Teller effect after its first experimental observation in 1959. At present, authors referring to it have usually broader physical phenomena and molecules larger than three-atoms in mind. Usually one considers now effects not only due to the coupling of electrons with vibrations, but also electronic couplings with rotations (rovibronic coupling).".
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- Renner–Teller_effect wikiPageRevisionID "563217504".
- Renner–Teller_effect wikiPageWikiLink Born–Oppenheimer_approximation.
- Renner–Teller_effect wikiPageWikiLink Carbon_Dioxide.
- Renner–Teller_effect wikiPageWikiLink Carbon_dioxide.
- Renner–Teller_effect wikiPageWikiLink Category:Edward_Teller.
- Renner–Teller_effect wikiPageWikiLink Category:Molecular_physics.
- Renner–Teller_effect wikiPageWikiLink Category:Spectroscopy.
- Renner–Teller_effect wikiPageWikiLink Edward_Teller.
- Renner–Teller_effect wikiPageWikiLink Electron.
- Renner–Teller_effect wikiPageWikiLink Gerhard_Herzberg.
- Renner–Teller_effect wikiPageWikiLink Isotopologue.
- Renner–Teller_effect wikiPageWikiLink Jahn–Teller_effect.
- Renner–Teller_effect wikiPageWikiLink Molecular_electronic_transition.
- Renner–Teller_effect wikiPageWikiLink Molecular_geometry.
- Renner–Teller_effect wikiPageWikiLink Molecular_vibration.
- Renner–Teller_effect wikiPageWikiLink Rovibronic_coupling.
- Renner–Teller_effect wikiPageWikiLink Vibronic_coupling.
- Renner–Teller_effect wikiPageWikiLinkText "Renner".
- Renner–Teller_effect wikiPageWikiLinkText "Renner–Teller effect".
- Renner–Teller_effect wikiPageWikiLinkText "Renner–Teller".
- Renner–Teller_effect hasPhotoCollection Renner–Teller_effect.
- Renner–Teller_effect subject Category:Edward_Teller.
- Renner–Teller_effect subject Category:Molecular_physics.
- Renner–Teller_effect subject Category:Spectroscopy.
- Renner–Teller_effect comment "The Renner–Teller effect or Renner effect is an effect due to rovibronic coupling on the electronic spectra of three- (or more) atomic linear molecules in degenerate electronic (Π, Δ, ..., etc.) states.In its original formulation, the Renner–Teller effect was a vibronic coupling between the motions of the electrons and the nuclear vibrations in triatomic linear molecules. The article by R.".
- Renner–Teller_effect label "Renner–Teller effect".
- Renner–Teller_effect sameAs m.026yv8k.
- Renner–Teller_effect sameAs Q7313322.
- Renner–Teller_effect sameAs Q7313322.
- Renner–Teller_effect wasDerivedFrom Renner–Teller_effect?oldid=563217504.
- Renner–Teller_effect isPrimaryTopicOf Renner–Teller_effect.