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- Metal_bis(trimethylsilyl)amides abstract "Metal bis(trimethylsilyl)amides (often abbreviated as metal silylamides) are coordination complexes composed of a cationic metal with anionic bis(trimethylsilyl)amide ligands and are part of a broader category of metal amides.Metal bis(trimethylsilyl)amide complexes are lipophilic due to the ligand and hence are soluble in a range of nonpolar organic solvents, this often makes them more reactive than the corresponding metal halides, which can difficult to solubilise. The steric bulk of the ligands causes their complexes to be discrete and monomeric (with the exception of group 1 complexes). Having a built-in base, these compounds conveniently react with protic ligand precursors to give other metal complexes. The class of ligands and pioneering studies on their coordination compounds were described by Bürger and Wannagat.The ligands are often denoted hmds (e.g. M(N(SiMe3)2)3 = M(hmds)3) in reference to the hexamethyldisilazide from which they are prepared.".
- Metal_bis(trimethylsilyl)amides thumbnail Hmds_ligand.png?width=300.
- Metal_bis(trimethylsilyl)amides wikiPageID "32471219".
- Metal_bis(trimethylsilyl)amides wikiPageLength "26207".
- Metal_bis(trimethylsilyl)amides wikiPageOutDegree "24".
- Metal_bis(trimethylsilyl)amides wikiPageRevisionID "647995474".
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Air-free_technique.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Alkali_halide.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Alkali_metal_halide.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Bis(trimethylsilyl)amine.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Category:Bis(trimethylsilyl)amides.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Category:Coordination_compounds.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Coordination_complex.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Dimethoxyethane.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Improper_rotation.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink LiCl.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Lithium_aluminium_hydride.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Lithium_chloride.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Metal_amides.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink N-Butyllithium.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink N-butyllithium.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Non-nucleophilic_base.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Paramagnetic.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Paramagnetism.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Salt_metathesis_reaction.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Solvent.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Steric.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Steric_effects.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Sterically_hindered_bases.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Transmetalation.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Transmetallation.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink Trimethylamine.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink File:2_rotation.gif.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink File:Hmds_ligand.png.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLink File:Zinc_bis(trimethylsilyl)amide.jpg.
- Metal_bis(trimethylsilyl)amides wikiPageWikiLinkText "Metal bis(trimethylsilyl)amides".
- Metal_bis(trimethylsilyl)amides wikiPageWikiLinkText "metal bis(trimethylsilyl)amide".
- Metal_bis(trimethylsilyl)amides wikiPageWikiLinkText "metal bis(trimethylsilyl)amides".
- Metal_bis(trimethylsilyl)amides hasPhotoCollection Metal_bis(trimethylsilyl)amides.
- Metal_bis(trimethylsilyl)amides wikiPageUsesTemplate Template:Main.
- Metal_bis(trimethylsilyl)amides wikiPageUsesTemplate Template:Reflist.
- Metal_bis(trimethylsilyl)amides subject Category:Bis(trimethylsilyl)amides.
- Metal_bis(trimethylsilyl)amides subject Category:Coordination_compounds.
- Metal_bis(trimethylsilyl)amides hypernym Complexes.
- Metal_bis(trimethylsilyl)amides type AnatomicalStructure.
- Metal_bis(trimethylsilyl)amides comment "Metal bis(trimethylsilyl)amides (often abbreviated as metal silylamides) are coordination complexes composed of a cationic metal with anionic bis(trimethylsilyl)amide ligands and are part of a broader category of metal amides.Metal bis(trimethylsilyl)amide complexes are lipophilic due to the ligand and hence are soluble in a range of nonpolar organic solvents, this often makes them more reactive than the corresponding metal halides, which can difficult to solubilise.".
- Metal_bis(trimethylsilyl)amides label "Metal bis(trimethylsilyl)amides".
- Metal_bis(trimethylsilyl)amides sameAs m.0h1hw27.
- Metal_bis(trimethylsilyl)amides sameAs Q6822720.
- Metal_bis(trimethylsilyl)amides sameAs Q6822720.
- Metal_bis(trimethylsilyl)amides wasDerivedFrom Metal_bis(trimethylsilyl)amides?oldid=647995474.
- Metal_bis(trimethylsilyl)amides depiction Hmds_ligand.png.
- Metal_bis(trimethylsilyl)amides isPrimaryTopicOf Metal_bis(trimethylsilyl)amides.