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- Inner_sphere_electron_transfer abstract "Inner sphere or bonded electron transfer is a redox chemical reaction that proceeds via a covalent linkage—a strong electronic interaction—between the oxidant and the reductant reactants. In Inner Sphere (IS) electron transfer (ET), a ligand bridges the two metal redox centers during the electron transfer event. Inner sphere reactions are inhibited by large ligands, which prevent the formation of the crucial bridged intermediate. Thus, IS ET is rare in biological systems, where redox sites are often shielded by bulky proteins. Inner sphere ET is usually used to describe reactions involving transition metal complexes and most of this article is written from this perspective. However, redox centers can consist of organic groups rather than metal centers. The bridging ligand could be virtually any entity that can convey electrons. Typically, such a ligand has more than one lone electron pair, such that it can serve as an electron donor to both the reductant and the oxidant. Common bridging ligands include the halides and the pseudohalides such as hydroxide and thiocyanate. More complex bridging ligands are also well known including oxalate, malonate, and pyrazine. Prior to ET, the bridged complex must form, and such processes are often highly reversible. Electron transfer occurs through the bridge once it is established. In some cases, the stable bridged structure may exist in the ground state; in other cases, the bridged structure may be a transiently-formed intermediate, or else as a transition state during the reaction.The alternative to inner sphere electron transfer is outer sphere electron transfer. In any transition metal redox process, the mechanism can be assumed to be outer sphere unless the conditions of the inner sphere are met. Inner sphere electron transfer is generally enthalpically more favorable than outer sphere electron transfer due to a larger degree of interaction between the metal centers involved, however, inner sphere electron transfer is usually entropically less favorable since the two sites involved must become more ordered (come together via a bridge) than in outer sphere electron transfer.".
- Inner_sphere_electron_transfer thumbnail Creutz-TaubeIon.png?width=300.
- Inner_sphere_electron_transfer wikiPageID "3418832".
- Inner_sphere_electron_transfer wikiPageLength "9005".
- Inner_sphere_electron_transfer wikiPageOutDegree "42".
- Inner_sphere_electron_transfer wikiPageRevisionID "629264269".
- Inner_sphere_electron_transfer wikiPageWikiLink Activation_energy.
- Inner_sphere_electron_transfer wikiPageWikiLink Antimony_tetroxide.
- Inner_sphere_electron_transfer wikiPageWikiLink Bridging_ligand.
- Inner_sphere_electron_transfer wikiPageWikiLink Category:Physical_chemistry.
- Inner_sphere_electron_transfer wikiPageWikiLink Chemical_element.
- Inner_sphere_electron_transfer wikiPageWikiLink Covalent.
- Inner_sphere_electron_transfer wikiPageWikiLink Covalent_bond.
- Inner_sphere_electron_transfer wikiPageWikiLink Creutz-Taube_complex.
- Inner_sphere_electron_transfer wikiPageWikiLink Creutz_Taube_complex.
- Inner_sphere_electron_transfer wikiPageWikiLink Creutz–Taube_complex.
- Inner_sphere_electron_transfer wikiPageWikiLink Cyanide.
- Inner_sphere_electron_transfer wikiPageWikiLink Enthalpy.
- Inner_sphere_electron_transfer wikiPageWikiLink Entropy.
- Inner_sphere_electron_transfer wikiPageWikiLink Halide.
- Inner_sphere_electron_transfer wikiPageWikiLink Halides.
- Inner_sphere_electron_transfer wikiPageWikiLink Henry_Taube.
- Inner_sphere_electron_transfer wikiPageWikiLink Hydroxide.
- Inner_sphere_electron_transfer wikiPageWikiLink Indium_chalcogenides.
- Inner_sphere_electron_transfer wikiPageWikiLink Inner_sphere_complex.
- Inner_sphere_electron_transfer wikiPageWikiLink Intervalence_charge_transfer.
- Inner_sphere_electron_transfer wikiPageWikiLink Lead(II,IV)_oxide.
- Inner_sphere_electron_transfer wikiPageWikiLink Ligand.
- Inner_sphere_electron_transfer wikiPageWikiLink Lone_electron_pair.
- Inner_sphere_electron_transfer wikiPageWikiLink Lone_pair.
- Inner_sphere_electron_transfer wikiPageWikiLink Malonate.
- Inner_sphere_electron_transfer wikiPageWikiLink Molybdenum_blue.
- Inner_sphere_electron_transfer wikiPageWikiLink Nobel_Prize_in_Chemistry.
- Inner_sphere_electron_transfer wikiPageWikiLink Organic_metal.
- Inner_sphere_electron_transfer wikiPageWikiLink Organic_semiconductor.
- Inner_sphere_electron_transfer wikiPageWikiLink Outer_sphere_electron_transfer.
- Inner_sphere_electron_transfer wikiPageWikiLink Oxalate.
- Inner_sphere_electron_transfer wikiPageWikiLink Oxidation_state.
- Inner_sphere_electron_transfer wikiPageWikiLink Prussian_blue.
- Inner_sphere_electron_transfer wikiPageWikiLink Pseudohalide.
- Inner_sphere_electron_transfer wikiPageWikiLink Pseudohalogen.
- Inner_sphere_electron_transfer wikiPageWikiLink Pyrazine.
- Inner_sphere_electron_transfer wikiPageWikiLink Red_lead.
- Inner_sphere_electron_transfer wikiPageWikiLink Redox.
- Inner_sphere_electron_transfer wikiPageWikiLink Spectroscopy.
- Inner_sphere_electron_transfer wikiPageWikiLink Tetrathiafulvalene.
- Inner_sphere_electron_transfer wikiPageWikiLink Thiocyanate.
- Inner_sphere_electron_transfer wikiPageWikiLink Turnbulls_blue.
- Inner_sphere_electron_transfer wikiPageWikiLink File:Creutz-TaubeIon.png.
- Inner_sphere_electron_transfer wikiPageWikiLinkText "Inner sphere electron transfer".
- Inner_sphere_electron_transfer wikiPageWikiLinkText "electron transfer reactions".
- Inner_sphere_electron_transfer wikiPageWikiLinkText "inner sphere electron transfer".
- Inner_sphere_electron_transfer wikiPageWikiLinkText "inner sphere or outer sphere".
- Inner_sphere_electron_transfer wikiPageWikiLinkText "inner sphere".
- Inner_sphere_electron_transfer wikiPageWikiLinkText "inner".
- Inner_sphere_electron_transfer wikiPageWikiLinkText "inner-sphere electron transfer".
- Inner_sphere_electron_transfer wikiPageWikiLinkText "mixed valence compound".
- Inner_sphere_electron_transfer hasPhotoCollection Inner_sphere_electron_transfer.
- Inner_sphere_electron_transfer wikiPageUsesTemplate Template:Chem.
- Inner_sphere_electron_transfer wikiPageUsesTemplate Template:Clarify.
- Inner_sphere_electron_transfer wikiPageUsesTemplate Template:Reflist.
- Inner_sphere_electron_transfer subject Category:Physical_chemistry.
- Inner_sphere_electron_transfer hypernym Reaction.
- Inner_sphere_electron_transfer type Article.
- Inner_sphere_electron_transfer type Disease.
- Inner_sphere_electron_transfer type Article.
- Inner_sphere_electron_transfer type Thing.
- Inner_sphere_electron_transfer comment "Inner sphere or bonded electron transfer is a redox chemical reaction that proceeds via a covalent linkage—a strong electronic interaction—between the oxidant and the reductant reactants. In Inner Sphere (IS) electron transfer (ET), a ligand bridges the two metal redox centers during the electron transfer event. Inner sphere reactions are inhibited by large ligands, which prevent the formation of the crucial bridged intermediate.".
- Inner_sphere_electron_transfer label "Inner sphere electron transfer".
- Inner_sphere_electron_transfer sameAs Compostos_de_valència_mixta.
- Inner_sphere_electron_transfer sameAs Intramolekularer_Elektronentransfer.
- Inner_sphere_electron_transfer sameAs Compuestos_de_valencia_mixta.
- Inner_sphere_electron_transfer sameAs 混合原子価化合物.
- Inner_sphere_electron_transfer sameAs m.09bh4r.
- Inner_sphere_electron_transfer sameAs Q1081009.
- Inner_sphere_electron_transfer sameAs Q1081009.
- Inner_sphere_electron_transfer sameAs 混合价态化合物.
- Inner_sphere_electron_transfer wasDerivedFrom Inner_sphere_electron_transfer?oldid=629264269.
- Inner_sphere_electron_transfer depiction Creutz-TaubeIon.png.
- Inner_sphere_electron_transfer isPrimaryTopicOf Inner_sphere_electron_transfer.