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- Evans–Saksena_reduction abstract "The Saksena–Evans reduction is a diastereoselective reduction of β-hydroxy ketones to the corresponding anti-dialcohols, employing the reagent tetramethylammonium triacetoxyborohydride (Me4NHB(OAc)3). The reaction was first described by Anil K. Saksena in 1983 and further developed by David A. Evans in 1987.The reaction is thought to proceed through the 6-membered ring transition state shown below. The intramolecular hydride delivery from the boron reducing agent forces the reduction to proceed from the opposite face of the chelating β-alcohol, thus determining the diastereoselectivity.This can be contrasted with the Narasaka–Prasad reduction which similarly employs a boron chelating agent but undergoes an intermolecular hydride delivery, favouring the corresponding syn-diol product.The Evans–Saksena reduction has since been used in the synthesis of several products, particularly the bryostatins.".
- Evans–Saksena_reduction wikiPageID "38067596".
- Evans–Saksena_reduction wikiPageLength "3034".
- Evans–Saksena_reduction wikiPageOutDegree "12".
- Evans–Saksena_reduction wikiPageRevisionID "591325721".
- Evans–Saksena_reduction wikiPageWikiLink Bryostatin.
- Evans–Saksena_reduction wikiPageWikiLink Category:Name_reactions.
- Evans–Saksena_reduction wikiPageWikiLink David_A._Evans.
- Evans–Saksena_reduction wikiPageWikiLink Diastereomer.
- Evans–Saksena_reduction wikiPageWikiLink Diastereoselectivity.
- Evans–Saksena_reduction wikiPageWikiLink Evans–Tishchenko_reaction.
- Evans–Saksena_reduction wikiPageWikiLink Intramolecular.
- Evans–Saksena_reduction wikiPageWikiLink Intramolecular_reaction.
- Evans–Saksena_reduction wikiPageWikiLink Ketone.
- Evans–Saksena_reduction wikiPageWikiLink Narasaka–Prasad_reduction.
- Evans–Saksena_reduction wikiPageWikiLink Redox.
- Evans–Saksena_reduction wikiPageWikiLink Reduction_(chemistry).
- Evans–Saksena_reduction wikiPageWikiLink Transition_state.
- Evans–Saksena_reduction wikiPageWikiLink File:Evans-Saksena.tif.
- Evans–Saksena_reduction wikiPageWikiLink File:Evans-Saksena_transition_state.tif.
- Evans–Saksena_reduction wikiPageWikiLinkText "Evans–Saksena reduction".
- Evans–Saksena_reduction wikiPageWikiLinkText "Evans–Saksena".
- Evans–Saksena_reduction hasPhotoCollection Evans–Saksena_reduction.
- Evans–Saksena_reduction wikiPageUsesTemplate Template:Reflist.
- Evans–Saksena_reduction subject Category:Name_reactions.
- Evans–Saksena_reduction comment "The Saksena–Evans reduction is a diastereoselective reduction of β-hydroxy ketones to the corresponding anti-dialcohols, employing the reagent tetramethylammonium triacetoxyborohydride (Me4NHB(OAc)3). The reaction was first described by Anil K. Saksena in 1983 and further developed by David A. Evans in 1987.The reaction is thought to proceed through the 6-membered ring transition state shown below.".
- Evans–Saksena_reduction label "Evans–Saksena reduction".
- Evans–Saksena_reduction sameAs m.0pcttqn.
- Evans–Saksena_reduction sameAs Q4371749.
- Evans–Saksena_reduction sameAs Q4371749.
- Evans–Saksena_reduction wasDerivedFrom Evans–Saksena_reduction?oldid=591325721.
- Evans–Saksena_reduction isPrimaryTopicOf Evans–Saksena_reduction.