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- Ether_cleavage abstract "Ether cleavage refers to chemical substitution reactions that lead to the cleavage of ethers. Due to the high chemical stability of ethers, ether cleavage is only possible under strongly acidic or extremely basic conditions.In organic chemistry, ether cleavage is an acid catalyzed nucleophilic substitution reaction. Depending on the specific ether, cleavage can follow either SN1 or SN2 mechanisms. Distinguishing between both mechanisms requires consideration of inductive and mesomeric effects that could stabilize or destabilize a potential carbocation in the SN1 pathway. Usage of Hydrohalic acids takes advantage of the fact that these agents are able to protonate the ether oxygen atom and also provide a halide anion as a suitable nucleophile. However, as ethers show similar basicity as alcohols (pKa of approximately 16), the equilibrium of protonation lies on the side of the unprotonated ether and cleavage is usually very slow at room temperature.In organometallic chemistry, ether cleavage refers to the decomposition of etheric solvents by extremely basic metallorganic agents. Cyclic ethers are especially susceptible to ether cleavage, but acyclic ethers can be cleaved as well.".
- Ether_cleavage thumbnail Etherspaltung_SN1_overview_V1-Seite001.svg?width=300.
- Ether_cleavage wikiPageID "42898403".
- Ether_cleavage wikiPageLength "5112".
- Ether_cleavage wikiPageOutDegree "49".
- Ether_cleavage wikiPageRevisionID "680988279".
- Ether_cleavage wikiPageWikiLink 1-Propanol.
- Ether_cleavage wikiPageWikiLink 1-propanol.
- Ether_cleavage wikiPageWikiLink Acid.
- Ether_cleavage wikiPageWikiLink Alcohol.
- Ether_cleavage wikiPageWikiLink Alcohols.
- Ether_cleavage wikiPageWikiLink Alkene.
- Ether_cleavage wikiPageWikiLink Alkoxide.
- Ether_cleavage wikiPageWikiLink Aryl.
- Ether_cleavage wikiPageWikiLink Base_(chemistry).
- Ether_cleavage wikiPageWikiLink Beta-Hydride_elimination.
- Ether_cleavage wikiPageWikiLink Bimolecular.
- Ether_cleavage wikiPageWikiLink Bromomethane.
- Ether_cleavage wikiPageWikiLink Carbocation.
- Ether_cleavage wikiPageWikiLink Carbon–carbon_bond.
- Ether_cleavage wikiPageWikiLink Category:Chemical_processes.
- Ether_cleavage wikiPageWikiLink Category:Substitution_reactions.
- Ether_cleavage wikiPageWikiLink Concerted_reaction.
- Ether_cleavage wikiPageWikiLink Concerted_reactions.
- Ether_cleavage wikiPageWikiLink Conjugate_acid.
- Ether_cleavage wikiPageWikiLink Conjugate_base.
- Ether_cleavage wikiPageWikiLink Cooling_bath.
- Ether_cleavage wikiPageWikiLink Ether.
- Ether_cleavage wikiPageWikiLink Ethers.
- Ether_cleavage wikiPageWikiLink Fluoride.
- Ether_cleavage wikiPageWikiLink Hydrobromic_acid.
- Ether_cleavage wikiPageWikiLink Hydrochloric_acid.
- Ether_cleavage wikiPageWikiLink Hydrofluoric_acid.
- Ether_cleavage wikiPageWikiLink Hydrogen_halide.
- Ether_cleavage wikiPageWikiLink Hydrogen_iodide.
- Ether_cleavage wikiPageWikiLink Hydrohalic_acids.
- Ether_cleavage wikiPageWikiLink Hydroiodic_acid.
- Ether_cleavage wikiPageWikiLink Inductive_effect.
- Ether_cleavage wikiPageWikiLink Mesomeric_effect.
- Ether_cleavage wikiPageWikiLink Methanol.
- Ether_cleavage wikiPageWikiLink Methyl.
- Ether_cleavage wikiPageWikiLink Methyl_bromide.
- Ether_cleavage wikiPageWikiLink Methyl_group.
- Ether_cleavage wikiPageWikiLink Methyl_tert-butyl_ether.
- Ether_cleavage wikiPageWikiLink Molecularity.
- Ether_cleavage wikiPageWikiLink Nucleophile.
- Ether_cleavage wikiPageWikiLink Nucleophilic_substitution.
- Ether_cleavage wikiPageWikiLink Nucleophilicity.
- Ether_cleavage wikiPageWikiLink Organic_chemistry.
- Ether_cleavage wikiPageWikiLink Organometallic_chemistry.
- Ether_cleavage wikiPageWikiLink Oxonium_ion.
- Ether_cleavage wikiPageWikiLink Primary_carbon.
- Ether_cleavage wikiPageWikiLink SN1_reaction.
- Ether_cleavage wikiPageWikiLink SN2_reaction.
- Ether_cleavage wikiPageWikiLink Tert-Butyl_bromide.
- Ether_cleavage wikiPageWikiLink Tetrahydrofuran.
- Ether_cleavage wikiPageWikiLink Tetrahydrofurane.
- Ether_cleavage wikiPageWikiLink Unimolecular.
- Ether_cleavage wikiPageWikiLink Vinyl.
- Ether_cleavage wikiPageWikiLink File:Etherspaltung_SN1_V1-Seite001.svg.
- Ether_cleavage wikiPageWikiLink File:Etherspaltung_SN1_overview_V1-Seite001.svg.
- Ether_cleavage wikiPageWikiLink File:Etherspaltung_SN2_V1a-Seite001.svg.
- Ether_cleavage wikiPageWikiLink File:Etherspaltung_SN2_overview_V1-Seite001.svg.
- Ether_cleavage wikiPageWikiLink File:THF_cleavage_by_RLi.svg.
- Ether_cleavage hasPhotoCollection Ether_cleavage.
- Ether_cleavage subject Category:Chemical_processes.
- Ether_cleavage subject Category:Substitution_reactions.
- Ether_cleavage comment "Ether cleavage refers to chemical substitution reactions that lead to the cleavage of ethers. Due to the high chemical stability of ethers, ether cleavage is only possible under strongly acidic or extremely basic conditions.In organic chemistry, ether cleavage is an acid catalyzed nucleophilic substitution reaction. Depending on the specific ether, cleavage can follow either SN1 or SN2 mechanisms.".
- Ether_cleavage label "Ether cleavage".
- Ether_cleavage sameAs m.010qk2ry.
- Ether_cleavage sameAs Q17067315.
- Ether_cleavage sameAs Q17067315.
- Ether_cleavage wasDerivedFrom Ether_cleavage?oldid=680988279.
- Ether_cleavage depiction Etherspaltung_SN1_overview_V1-Seite001.svg.
- Ether_cleavage isPrimaryTopicOf Ether_cleavage.